You can make your own lithium-ion batteries if you have a source for individual cells and a control board to match your desired voltage levels. [Bill Porter] put together a quick tutorial where he makes a 14.4V 2.2 AH battery for about $10. He picked up a set of cable-modem backup batteries (used to make sure your bundled phone service doesn’t quit working when the power goes out) and tore out the cells. After reconfiguring the connections and swapping out the controller board the original 8V battery is now 14V. This doesn’t take into account any problems with battery life and charge leveling, but that’s a whole different tutorial waiting to happen.
If this type of battery hack is child’s play to you, take a look at a more involved lithium iron phosphate build.