A few years back, there were some studies on the chemical and particle emissions coming out of the hotends of 3D printers. Although they galvanized a lot of people in the community, the science wasn’t entirely conclusive — one paper made it sound like you needed a hazmat suit for 3D printing, and the other suggested that cooking a meal in a kitchen was worse for you. That’s because they were measuring different things.
This new research paper on the emissions of 3D printers covers all the bases. They examined a variety of different materials printed in different printers. They also measured both chemical emissions and Ultrafine Particles (UFP) which can be hazardous even when the material itself is not.
There was no significant variation across brands of 3D printers. (Duh?)
ABS and similar materials outgas styrene at levels you should probably be worrying about if you’re running your printer for a few hours a day in an unventilated office.
PLA emitted significantly less overall, and most of it was a non-hazardous chemical, lactide. PLA doesn’t look like a problem.
All of the materials resulted in increased UFP exposure. These levels are above normal household background levels, but lower than certain “microclimates” which (if you follow the references) include principals’ offices with carpet, automobiles, restaurants, and rooms with burning candles or running hair dryers. In short, the UFP exposure doesn’t look like it’s going to be a big deal unless you’re sitting right next to the printer and running it continually.
So what would we do? It now looks like it’s prudent to print ABS only in a well-ventilated room. Or enclose the printer in a box and vent whatever you can outside — which can also help prevent breezes cooling the piece down unevenly and adding to ABS’s warping problems. Or just stick to PLA. It looks essentially harmless.
This hack is a strange mixture of awesome and ghoulish. [Andrew Sink] created a 3D printed version of his brain. He received a CD from an MRI session that contained the data obtained by the scan. Not knowing what to do with it he created a model of his brain.
Out of a number of images, some missing various parts of his head, he selected the one that was most complete. This image he brought into OisriX, a Mac program for handling DICOM files. He worked on the image for an hour dissecting away his own eyes, skull, and skin. An STL file containing his brain was brought over to NetFabb to see how it looked. There was still more dissection needed so [Andrew] turned to Blender. More bits and pieces of his skull’s anatomy were dissected to pare it down to just the brain. But there were some lesions at the base of the brain that needed to be filled. With the help of [Cindy Raggio] these were filled in to complete the 3D image.
The usual steps sent it to the 3D printer to be produced at 0.2 mm resolution. It only took 49 hours to print at full-size. This brain was printed for fun, but we’ve seen other 3D printed brain hacks which were used to save lives. How many people do you know that have a spare brain sitting around?
Despite tuning my extruder steps perfectly, and getting good results instantly on larger prints. I was still having a ton of trouble with smaller parts. PLA is the favored printing material for its low odor, low warping, and decent material properties. It also has many downside, but it’s biggest, for the end user, lies in its large glass transition temperature range. Like all thermoplastics, it shrinks when it cools, but because of this large range, it stays expanded and, getting deep into my reserve of technical terms, bendy for a long time. If you don’t cool it, the plastic will pile up in its expanded state and deform.
I am working on a project that needs a tiny part, pictured above. The part on the left is what I was getting with my current cooling set-up and temperature settings. It had very little semblance with the CAD file that brought it into this world.
The bond between layers in a 3d print occurs when the plastic has freshly left the nozzle at its melting point. Almost immediately after that, the plastic crosses from the liquid state into a glass state, and like pressing two pieces of glass together, no further bonding occurs. This means that in order to get a strong bond between the print layers, the plastic has to have enough thermal mass to melt the plastic below it. Allowing the polymer chains to get cozy and hold hands. Nozzle geometry can help some, by providing a heat source to press and melt the two layer together, but for the most part, the fusing is done by the liquid plastic. This is why large diameter nozzles produce stronger parts.
What I’m getting at is that I like to run my nozzle temperature a little hotter than is exactly needed or even sensible. This tends to produce a better bond and sometimes helps prevent jamming (with a good extruder design). It also reduces accuracy and adds gloopiness. So, my first attempt to fix the problem was to perhaps consider the possibility that I was not 100% right in running my nozzle so hot, and I dropped the temperature as low as I could push it. This produced a more dimensionally accurate part, but a extraordinarily weak one. I experimented with a range of temperatures, but found that all but the lowest produced goopy parts.
After confirming that I could not get a significant return on quality by fine tuning my temperature, I reduced the speed of the nozzle by a large percentage. By reducing the speed I was able to produce the middle of the three printed parts shown in the opening image. Moving the nozzle very slowly gave the ambient air and my old cooling fan plenty of time to cool the part. However, what was previously a five minute part now took twenty minutes to print. A larger part would be a nightmare.
So, if I can’t adjust the temperature to get what I want, and I can adjust the speed; this tells me I just need to cool the part better. The glass state of the plastic is useless to me for two reasons. One, as stated before, no bonding occurs. Two, while the plastic remains expanded and bendy, the new layer being put down is being put down in the wrong place. When the plastic shrinks to its final dimension is when I want to place the next layer. Time to solve this the traditional way: overkill.
A while back my friend gifted me a little squirrel cage fan he had used with success on his 3d printer. Inspired by this, I had also scrounged a 12v, 1.7A fan from a broken Power Mac G5 power supply. When it spins up I have to be careful that it doesn’t throw itself off the table.
I printed out mounts for the fans. The big one got attached to the Z axis, and the little one rides behind the extruder. I fired up the gcode from before and started to print, only to find that my nozzle stopped extruding mid way. What? I soon discovered I had so much cooling that my nozzle was dropping below the 160C cold extrusion cut-off point and the firmware was stopping it from damaging itself. My heated bed also could no longer maintain a temperature higher than 59C. At this point I felt I was onto something.
I wrapped my extruder in fiberglass insulation and kapton tape, confidently turned the nozzle temperature up, set the speed to full, and clicked print. With the addition of the overkill cooling I was able to get the part shown to the right in my three example prints. This was full speed and achieved full bond. Not bad! Thus concludes this chapter in my adventures with cooling. I was really impressed by the results. Next I want to try cooling ABS as it prints. Some have reported horrible results, others pretty good ones, I’m interested. I also wonder about cooling the plastic with a liquid at a temperature just below the glass state as it is deposited. Thoughts?
I have an old Prusa i2 that, like an old car, has been getting some major part replacements lately after many many hours of service. Recently both the extruder and the extruder motor died. The extruder died of brass fill filament sintering to the inside of the nozzle (always flush your extruder of exotic filaments). The motor died at the wires of constant flexing. Regardless, I replaced the motors and found myself with an issue; the new motor and hotend (junk motor from the junk bin, and an E3D v6, which is fantastic) worked way better and was pushing out too much filament.
The hotend, driver gear, extruder mechanics, back pressure, motor, and plastic type all work together to set how much plastic you can push through the nozzle at once. Even the speed at which the plastic is going through the nozzle can change how much friction that plastic experiences. Most of these effects are somewhat negligible. The printer does, however, have a sort of baseline steps per mm of plastic you can set.
The goal is to have a steps per mm that is exactly matched to how much plastic the printer pushes out. If you say 10mm, 10mm of filament should be eaten by the extruder. This setting is the “steps per mm” in the firmware configuration. This number should be close to perfect. Once it is, you can tune it by setting the “extrusion multiplier” setting in most slicers when you switch materials, or have environmental differences to compensate for.
The problem comes in measuring the filament that is extruded. Filament comes off a spool and is pulled through an imprecisely held nozzle in an imprecisely made extruder assembly. On top of all that, the filament twists and curves. This makes it difficult to hold against a ruler or caliper and get a trustworthy measurement.
I have come up with a little measuring device you can make with some brass tubing, sandpaper, a saw (or pipe cutter), a pencil torch, solder, and some calipers. To start with, find two pieces of tubing. The first’s ID must fit closely with the filament size you use. The second tube must allow the inside tubing to slide inside of it closely. A close fit is essential.
Laser sintering works by laying down a thin layer of metal powder and then hitting it with a strong enough laser to sinter the particles together. (Sintering sticks the grains together without getting the metal hot enough to melt it.) The rapid local heating and cooling required to build up 3D objects expands and cools the metal, and can result in stresses inside the resulting object.
The Northwestern team still lays down layers of powder, but glues the layers together with a quick-drying polymer instead of fusing them with a laser. Once the full model is printed, they then sinter it in one piece in an oven.
The advantages of adding this extra step are higher printing speed — squirting the liquid out of syringe heads can be faster than fusing metal particles with a laser — and increased structural integrity because the whole model is heated and cooled at one time. A fringe benefit is that the model is still a bit flexible before firing, opening up possibilities for printing a flat model and then bending it into shape before sintering.
And if that weren’t enough, the team figured that they’d add a third step to the procedure to allow it to be used with rust (iron oxide) as the starting powder. They print the rust and polymer model, then un-rust the iron using hydrogen, and then fire it as before. Why rust? Do you know anything cheaper to use as a raw material?
What do you think? The basic idea may even be DIYable — glue metal particles together and heat them up enough to stick. Not in my microwave oven, though. We’d love to see a more energy-efficient 3D metal printer.
Even though the pewter is hot enough to melt the PLA, it doesn’t appear to be a major problem if you quench the piece fast enough. According to [bms.had], a slower quench will melt some PLA although that creates a smoother surface. You can see the 0.31 mm layer lines in the cast, though, although you can use any layer height you like to control that. Creating the mold is simple (the videos use Tinkercad, although anything suitable for creating 3D models would work). You essentially attach a funnel to your part and make the entire part a hole inside an enveloping shape.
The idea is simple. The team started with a printer that uses a liquid ink that is UV cured to produce solid layers. The printer has the ability to use multiple liquids, and [MacCurdy] uses hydraulic fluid (that does not UV cure) as one of the print materials. Just as you can use a 3D printer to build structures within other structures, printing the hydraulics allows for complex closed systems that use the UV-cured resin as mechanical parts that can transfer pressure to and from the hydraulic system.