Although the typical cliché for a mad scientist usually involves Bunsen burners, beakers, and retorts, most of us (with some exceptions, of course) aren’t really chemists. However, there are some electronic endeavors that require a bit of knowledge about chemistry or related fields like metallurgy. No place is this more apparent than producing your own PCBs. Unless you use a mill, you are probably using a chemical bath of some sort to strip copper from your boards.
The standard go-to solution is ferric chloride. It isn’t too tricky to use, but it does work better hot and with aeration, although neither are absolutely necessary. However, it does tend to stain just about everything it touches. In liquid form, it is more expensive to ship, although you can get it in dry form. Another common etchant is ammonium or sodium persulphate.
There’s also a variety of homemade etchants using things like muriatic acid and vinegar. Most of these use peroxide as an oxidizer. There’s lots of information about things like this on the Internet. However, like everything on the Internet, you can find good information and bad information.
When [w_k_fay] ran out of PCB etchant, he decided to make his own to replace it. He complained that he found a lot of vague and conflicting information on the Internet. He read that the vinegar solution was too slow and the cupric acid needs a heated tank, a way to oxygenate the solution, and strict pH controls. However, he did have successful experiments with the hydrochloric acid and peroxide. He also used the same materials (along with some others) to make ferric chloride successfully.
I’ve been soldering for a long time, and I take pride in my abilities. I won’t say that I’m the best solder-slinger around, but I’m pretty good at this essential shop skill — at least for through-hole and “traditional” soldering; I haven’t had much practice at SMD stuff yet. I’m confident that I could make a good, strong, stable joint that’s both electrically and mechanically sound in just about any kind of wire or conductor.
But like some many of us, I learned soldering as a practical skill; put solder and iron together, observe results, repeat the stuff that works and avoid the stuff that doesn’t. Seems like adding a little inside information might help me improve my skills, so I set about learning what’s going on mechanically and chemically inside a solder joint.
If you’ve ever tried to build a printed circuit board from home, you know how much of a pain it can be. There are buckets of acid to lug around, lots of waiting and frustration, and often times the quality of the circuits that can be made traditionally with a home setup isn’t that great in the end. Luckily, [Rich] has come up with a way that eliminates multiple prints and the acid needed for etching.
His process involves using a laser printer (as opposed to an inkjet printer, as is tradition) to get a layer of silver adhesive to stick to a piece of paper. The silver adheres to the toner like glitter sticks to Elmer’s glue, and allows a single pass of a laser printer to make a reliable circuit. From there, the paper can be fastened to something more solid, and components can be reflow soldered to it.
[Rich] does post several warnings about this method though. The silver is likely not healthy, so avoid contact with it, and when it’s applied to the toner an indeterminate brown smoke is released, which is also likely not healthy. Warnings aside, though, this is a great method for making home-made PCBs, especially if you don’t want tubs of acid lying around the house, however useful.
The 1970’s was the decade that illuminated the threat of acid rain to the citizens of the US. It had been known to exist several years before, but the sources of the problem did their best to suppress the information. It wasn’t until the environmental damage became significant enough to draw national attention that it would lead to the US enacting regulations to stop acid rain.
Truthfully, most of the public was probably still unaware of what acid rain actually was. The default mental image that comes to the mind of the non-chemist is large drops of battery acid raining down from the heavens and devouring everything. This is not quite the case, however. Pure water has a neutral pH of 7. Normal rain is actually slightly acidic as it picks up CO2 from the air, making carbonic acid. But when this “normal” rain mixes with the byproducts of industrial plants that pump out large amounts of SO2 (sulfuric dioxide) and NO (nitrogen oxide) into the atmosphere, it becomes even more acidic – down to a pH of 3. This “acid” rain has the acidity of citrus juice, so it’s not going to set the world on fire. But it will wreak havoc on local ecosystems.
The 1990’s brought with it tough government regulations on the output of SO2 and NO by large factories, pretty much eliminating acid rain in the US. The rise and fall of acid rain is a great example of why we should educate ourselves on the basic chemistries that define our lives, even though we might not be actual chemists. In this article, we’re going back to your first year of college and hash out just what defines an acid and base. And solidify our understanding of the pH scale. It is essential for the future biohacker to have this knowledge in their toolbox.
In this acid powered teardown, [Lindsay] decapped a USB isolator to take a look at how the isolation worked. The decapped part is an Analog Devices ADUM4160. Analog Devices explains that the device uses their iCoupler technology, which consists of on chip transformers.
[Lindsay] followed [Ben Krasnow]’s video tutorial on how to decap chips, but replaced the nitric acid with concentrated sulphuric acid, which is a bit easier to obtain. The process involves heating the chip while applying an acid. Over time, the packaging material is dissolved leaving just the silicon. Sure enough, one of the three dies consisted of five coils that make up the isolation transformers. Each transformer has 15 windings, and the traces are only 4μm thick.
After the break, you can watch a time lapse video of the chip being eaten by hot acid. For further reading, Analog Devices has a paper on how iCoupler works [PDF warning].
The title of our feature is a play on words. In this case, die refers to the silicone on which the IC has been etched. To protect it the hardware manufacturer first attaches the metal pins to the die, then encapsulates it in plastic. [Michail] removes that plastic case by heating sulfuric acid to about 300 degrees Celsius (that’s 572 Fahrenheit) then submerges the chips in the acid inside of a sealed container for about forty minutes. Some of the larger packages require multiple trips through the acid bath. After this he takes detailed pictures of the die and uses post processing to color enhance them.
Nearly everything at [HAD] is at least based on science in some way or another. If, however, you would like to do some actual scientific experiments with stuff around the house, [Observationsblog] might be for you.
The particular posts that [Ken] wrote in to tell us about were all about acids, bases, and natural indicators. In his first post he goes over some definitions of acids, bases, and what pH exactly means. A good refresher for those that have forgotten some of their high school (or college) chemistry classes.
The other two posts have to do with making your own natural acid/base indicators. The first is called Anthocyanin, and can be extracted from Red Cabbage. Quite specific directions can be found here. Similar directions can be found to turn the Indian spice of [Turmeric] into an indicator as well. Although these concepts probably won’t help build your next robot, they could easily be copied inspire young minds for a great science fair project!