Making Smoke That Really Performs

Smoke is a useful thing, whether you want to hide from enemy combatants or just make a big scene at a local sporting match. Smoke devices have lots of applications, many of which will likely cause a nuisance to somebody, somewhere. With that said, they can also be really cool, and [Tech Ingredients] is here to tell you how to make them.

Far from a simple tutorial, the video guide is loaded with detail. It begins with an explanation of the basic chemistry involved, using potassium nitrate and sugar. This is the basis of rocket candy, a popular method for making solid rocket motors at home. However, it’s then explained how the formula is altered to suit a smoke-making, rather than a thrust-making device. The trick is the addition of paraffin to moderate the reaction.

The tips don’t stop there. The guide explains how to use a coffee grinder to make the coarse ingredients finer, which increases the surface area and allows the powder constituents to blend with the wax more easily. Enclosures are also discussed, with a cardboard tube and bentonite clay favored for its heat resistance and stability.

Overall, it’s an excellent guide which takes the time to explain the rationale behind each step in the process. It’s great to see the underlying concepts explained with the practical execution, giving a strong understanding of not just how to do it, but why. Video after the break.

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Anyone Need A Little Fuming Nitric Acid?

If there’s a chemical with a cooler name than “fuming nitric acid,” we can’t think of it. Nearly pure nitric acid is useful stuff, especially if you’re in the business of making rocket fuels and explosives. But the low-end nitric acid commonly available tops out at about 68% pure, so if you want the good stuff, you’ll have to synthesize fuming nitric acid yourself. (And by “good stuff”, we mean be very careful with the resulting product.)

Fuming nitric acid comes in two colors – red fuming nitric acid (RFNA), which is about 90% pure and has some dissolved nitrogen oxides, giving it its reddish-brown color. White fuming nitric acid (WFNA) is the good stuff — more than 99% pure. Either one is rough stuff to work with — you don’t want to wear latex or nitrile gloves while using it. It’s not clear what [BarsMonster] needs the WFNA for, although he does mention etching some ICs. The synthesis is pretty straightforward, if a bit dangerous. An excess of sulfuric acid is added to potassium nitrate, and more or less pure nitric acid is distilled away from the resulting potassium sulfate. Careful temperature control is important, and [BarsMonster] seems to have gotten a good yield despite running out of ice.

We don’t feature too many straight chemistry hacks around here, but this one seemed gnarly enough to be interesting. We did have a Hackaday Prize entry a while back on improvements to the Haber process for producing ammonia, which curiously is the feedstock for commercial nitric acid production processes.

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Eco Friendly Space-Fuel

If you’d like to risk blowing your fingers off for a good cause this week, look no further than [M. Bindhammer]’s search for an eco-friendly rocket fuel. [M. Bindhammer] predicts the increasing use of solid rocket boosters in the future. We’re into that. For now, rocket launches are so few and far between that the pollution doesn’t add up, but when we’re shipping consumer electronics to the moon and back twice a day, we might have a problem.

The most common solid rocket fuel emits chlorine gas into the atmosphere when burned. [Bindhammer] is exploring safe ways to manufacture a eutectically balanced and stabilized fuel compromised of sugar or sugar-alcohol, and potassium nitrate. If you watch home chemistry videos for fun on the weekend like us, [Bindhammer] goes through all his thinking, and even spells out the process for duplicating his fuel safely in a lab.

He’s done a lot of work. The resulting fuel is stable, can be liquid or solid. It has a high ignition temperature, but as you can see in the video after the break. Once ignited. It goes off like rocket fuel.

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Chocolate As Rocket Fuel

[Adric Menning] has an unfortunate allergy. He’s allergic to chocolate. Instead of eating the stuff, he’s using it to build model rocket engines. The project stems from the Quelab Hackerspace’s chocolate hacking challenge which spawned a number of interesting hacks. [Adric’s] doesn’t use pure chocolate (an experiment with a Hershey’s bar was a bust) but manages to ignite using a Milky Way bar.

This is not as unorthodox as you might think. Sugar and potassium nitrate have long been used to create solid rocket propellant. The chocolate version is swapping out plain old sugar for the candy bar. It was chopped into 10 gram chunks to make proportion calculations easier later on. The chunks go into the freezer to make them easier to grind using a mortar and pestle. Once it’s a somewhat chunk-free powder he mixes it with the potassium nitrate which previously had its own trip through the grinder. After being packed into a chunk of PVC pipe and fitted with an exhaust nozzle the engine is ready to go.

You can check out the test-fire video after the break. There’s a burn restriction in his area due to drought so this is just an engine test and not an actual rocket launch.

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Homemade Solid Propellant Rocket Motors

[KoD] and [Navic] are building solid propellant motors using sugar and potassium nitrate. They cook up the two ingredients along with water and a bonding agent. They find that corn syrup is particularly good for bonding and that cooking the strange brew is more of an artform than science. Either way, the video after the break is proof of the dangers involved in this hobby. Testing the engine thrust with a bathroom scale ends badly for the scale.

There is something satisfying about the ingenuity that goes into the materials. For a casing they’re using PVC pipe, and forming a cone to focus the thrust by using a what amounts to plumber’s epoxy putty. The capping agent for the finished motor is ground up kitty litter.

This is an interesting read, but for now we’re going to stick to water rockets.

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