Etching PCBs with vinegar

When we hear about etching PCBs at home we assume that either Ferric Chloride or Cupric Chloride were used to eat away unmasked copper from the boards. But [Quinn Dunki] just wrote up her PCB etching guide and she doesn’t use either of those. Instead, she combines vinegar, hydrogen peroxide, and salt. It’s easier to find vinegar than muriatic acid (Cupric Chloride is made using this, peroxide, and adding the copper) so this is something to keep in mind if you’re in a pinch (or a Macgyver situation).

The rest of the process is what we’re used to. She’s using photoresistant boards which can be masked with a sheet of transparency instead of using the toner-transfer method. Once they take a bath in the developer solution she puts them in a shallow dish of vinegar and hydrogen peroxide along with a teaspoon of salt. She wipes the surface with a foam brush every minute or so, and inspects them every ten minutes to see if they’re done.

She does discuss disposal. Seems that she throws the solution in the garbage after each use. The liquid will contain copper salts which are bad for wildlife. We’ve heard that you should neutralize the acid and make a block of concrete using the liquid, then throw it in the garbage. Does anyone have a well-researched, ethical, and environmentally friendly way of getting rid of this stuff?

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