Using A Potato As Photographic Recording Surface

Following in the tracks of unconventional science projects, [The Thought Emporium] seeks to answer the question of whether you can use a potato as a photograph recording medium. This is less crazy than it sounds, as ultimately analog photographs (and photograms) is about inducing a light-based change in some kind of medium, which raises the question of whether there is anything about potatoes that is light-sensitive enough to be used for capturing an image, or what we can add to make it suitable.

Unfortunately, a potato by itself cannot record light as it is just starch and salty water, so it needs a bit of help. Here [The Thought Emporium] takes us through the history of black and white photography, starting with a UV-sensitive mixture consisting out of turmeric and rubbing alcohol. After filtration and staining a sheet of paper with it, exposing only part of the paper to strong UV light creates a clear image, which can be intensified using a borax solution. Unfortunately this method fails to work on a potato slice.

The next attempt was to create a cyanotype, which involves covering a surface in a solution of 25 g ferric ammonium oxalate, 10 g of potassium ferricyanide and 100 mL water and exposing it to UV light. This creates the brilliant blue that gave us the term ‘blueprint’. As it turns out, this method works really well on potato slices too, with lots of detail, but the exposure process is very slow.

Speeding up cyanotype production is done by spraying the surface with an ammonium oxalate and oxalic acid solution to modify the pH, exposing the surface to UV, and then spraying it with a 10 g / 100 mL potassium ferricyanide solution, leading to fast exposure and good details.

This is still not as good on paper as an all-time favorite using silver-nitrate, however. These silver prints are the staple of black and white photography, with the silver halide reacting very quickly to light exposure, after which a fixer, like sodium thiosulfate, can make the changes permanent. When using cyanotype or silver-nitrate film like this in a 35 mm camera, it does work quite well too, but of course creates a negative image, that requires inverting, done digitally in the video, to tease out the recorded image.

Here the disappointment for potatoes hit, as using the developer with potatoes was a soggy no-go. Ideally a solution like that used with direct positive paper that uses a silver solution suspended in a gel, but creates a positive image unlike plain silver-nitrate. As for the idea of using the potato itself as the camera, this was also briefly attempted to by using a pinhole in a potato and a light-sensitive recording surface on the other side, but the result did indeed look like a potato was used to create the photograph.

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Growing Silver Nanoprisms With Light

Nanoparticles sound a bit like science fiction to minds of your average hacker — too esoteric and out of reach to be something we might get to work with in our own lairs — but [Ben Krasnow] of [Applied Science] over on YouTube has proven that they most definitely can be made by mere mortals, and importantly they can be tuned. With light. That’s right, nano particle growth appears to be affected very strongly by being illuminated with specific wavelengths, which locks-in their size, and thus defines their light-bending properties. This is the concept of photo mediated synthesis, which causes nanoparticles to clump together into different configurations depending on the wavelength. The idea is to start with a stock solution of Silver Nitrate, which is then reduced to form silver nanospheres which are then converted to larger silver nanoprisms, sized according to the wavelength of the illuminating source.

The process seems simple enough, with a solution of Silver Nitrate and Sodium Citrate being vacuum degassed to remove oxygen, and then purged by bubbling argon or nitrogen. Sodium Borohydride acts as a reducing agent, producing silver metal nanoparticles from the Silver Nitrate solution. The Sodium Citrate coats the silver nanoparticles, as they are produced, preventing them clumping together into a mushy precipitate. PVP (Polyvinylpyrrolidone) is added, acting as a colloiding agent preventing the coated nanoparticles from clumping together, and helping keep the solution stable long enough for the photo mediated synthesis process to complete. Finally, the pH is adjusted up to 11 using sodium hydroxide. The resulting silver nanoparticle stock solution has a pale yellow colour, and is ready for the final particle size selection using the light source.

The light source was custom made because [Ben] says he couldn’t find something suitable off the shelf. This is a simple design using a Teensy to drive an array of PAM2804 LED drivers, with each one of those driving its own medium power LED, one for each of the different wavelengths of interest. As [Ben] stresses, the naïve approach of trying to approximate a specific colour with an RGB LED setup would not work, as although the human eye perceives the colour, the actual wavelength peak will be totally wrong, and the reaction will not proceed as intended. The hardware design is available on MultiSpectLED GitHub for your viewing pleasure.

Nanoparticles have all kinds of weird and wonderful properties, such as making the unweldable, weldable, enabling aluminium to be 3D printed, and even enabling the production of one of our favourite liquid toys, ferrofluid.

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