During World War II a scientist named Georg Otto Erb developed the molten salt battery for use in military applications. The war ended before Erb’s batteries found any real use, but British Intelligence wrote a report about the technology and the United States adopted the technology for artillery fuses.
Molten salt batteries have two main advantages. First, you can store them for a long time (50 years or more) with no problems. Once the salt melts (usually from a pyrotechnic charge), the battery can produce a lot of energy for a relatively short period of time thanks to the high ionic conductivity of the electrolyte (about three times that of sulfuric acid).
[OrbitalDesigns] couldn’t find a DIY version of a molten salt battery so he decided to make one himself. Although he didn’t get the amount of power you’d find in a commercial design, it did provide 1.6V and enough power to light an LED.
The electrolyte was a mixture of potassium chloride and lithium chloride and melts at about 350 to 400 degrees Celsius. He used nickel and magnesium for electrodes. Potassium chloride is used as a salt substitute, so it isn’t dangerous to handle (at least, no more dangerous than anything else heated to 400 degrees Celsius). The lithium compound, however, is slightly toxic (even though it was briefly sold as a salt substitute, also). If you try to replicate the battery, be sure you read the MSDS for all the materials.