Two guys — Stern and Gerlach — did an experiment in 1922. They wanted to measure magnetism caused by electron orbits. At the time, they didn’t know about particles having angular momentum due to spin. So — as explained by [The Science Asylum] in the video below — they clearly showed quantum spin, they just didn’t know it and Physics didn’t catch on for many years.

The experiment was fairly simple. They heated a piece of silver foil to cause atoms to stream out through a tiny pinhole. The choice of silver was because it was a simple material that had a single electron in its outer shell. An external magnet then pulls silver atoms into a different position before it hits some film and that position depends on its magnetic field.

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