A ZInc Air Battery You Can Make Yourself

Zinc air batteries have been a familiar sight for decades in the world of photography, where they provided an environmentally less dangerous alternative to mercury cells. They operate by the oxidation of metallic zinc using air, and the zinc comes in the form of a paste spread between two electrodes. Can their astounding energy density be harnessed for something useful? [ZollerLab] has designed a zinc air battery to find out, and is using it to power a rudimentary model car.

The video below is in German so you’ll have to enable translated subtitles if you’re an Anglophone, and it’s very long. But it goes into extreme detail on the chemistry, construction, and constraints of a zinc-air battery, and describes the system in this design. It’s a stack arrangement, in which the cells are held together on threaded rods, and pushed into each other with springs.

We think the car model is intended to demonstrate that this battery chemistry might one day be used in automotive applications. It’s not such a far-fetched idea given the low cost, relatively low environmental footprint, and high energy density, indeed we’ve heard of similar experiments with aluminium primary cells. But in this case we can see it provides the hacker with another route for their experiments, and that’s no bad thing.

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Zinc-Air, The Next Contender In Vehicle Batteries?

If you’ve got an interest in technology, it’s inevitable that your feed will feature a constant supply of stories with titles in the vein of “New battery breakthrough offers unlimited life and capacity!”. If we had a pound, dollar, or Euro for each one, we’d be millionaires by now. But while the real science behind the breathless headlines will undoubtedly have provided incremental battery improvements, we’re still waiting for the unlimited battery.

It’s not to say that they don’t conceal some interesting stories though, and there’s an announcement from Australia proving this point admirably. Scientists at ECU in Perth have created a new cathode compound for rechargeable zinc-air batteries, which it is hoped will make them much safer and cheaper competitors for lithium-ion cells.

Most of us think of zinc-air batteries as the tiny cells you’d put in a camera or a hearing aid, but these conceal a chemistry with significant potential that is held back by the difficulty of creating a reliable cathode. In these batteries the cathode is a porous support in which a reaction between zinc powder wet paste and oxygen in the air occurs, turning zinc into zinc oxide and releasing electrons which can be harvested as electricity. They have a very high power density, but previous cathode materials have quickly degraded performance when presented with significant load.

The new cathode support is a nano-composite material containing cobalt, nickel, and iron, and is claimed to offer much better performance without the degradation. Whether or not it can be mass-produced remains to be seen, but as a possible alternative to lithium-ion in portable and transport applications it’s of great interest.