If you use the Arduino IDE to program the ESP32, you might be interested in [Andreas Spiess’] latest video (see below). In it, he shows an example of using all three ESP32 UARTs from an Arduino program. He calls the third port “secret” although that’s really a misnomer. However, it does require a quick patch to the Arduino library to make it work.
Just gaining access to the additional UARTs isn’t hard. You simply use one of the additional serial port objects available. However, enabling UART 1 causes the ESP32 to crash! The reason is that by default, UART 1 uses the same pins as the ESP32 flash memory.
Luckily, the chip has a matrix switch that can put nearly any logical I/O pin on any physical I/O pin. [Andreas] shows how to modify the code, so that UART 1 maps to unused pins, which makes everything work. it is a simple change, replacing two parameters to a call that — among other things — maps the I/O pins. You could use the technique to relocate the UARTs to other places if you choose.