Making A Copper-Oxide Photodetector From Scratch

Photodetectors come in a wide variety of constructions and materials, with the Cu2O-based photodetector that [Mad Scientist Creations] demonstrates in a recent video being a good example of a photodetector that can be created at home using nothing but some copper and a heat source.

Of the two copper elements in a salt water cell, one element is heated to the point where a copper oxide layer forms, specifically Cu2O, which acts as a semiconductor and provides the photosensitive layer. Even a fairly crude sensor created with a regular gas stove produces enough of a current that it can be used in a simple light detection circuit.

Although copper-oxide photodetectors may seem quaint, they are getting a lot of interest as they feature a very narrow bandgap at 1.2 eV. In a 2019 study by [Hyeon-Joo Song] et al. as published in Scientific Reports such a sensor is enhanced with an optimized grain structure that improves its performance, with much higher sensitivity and faster response times.

As demonstrated by [Andrzej Kwiatkowski] et al. in a 2024 paper in Solar Energy Materials and Solar Cells these copper-oxide sensors can also be used for gas detectors, though they used advanced gas deposition to produce the thin films instead of sticking a bit of copper tape into a natural gas flame.

Even if DIY copper-oxide sensors aren’t quite as exciting as what one can do with access to a well-equipped (semiconductor) lab, it’s still a pretty accessible material that lends itself for easy experimentation.

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Silicon Nanowires Create Flexible Photodetectors

Modern display and solar cell technologies are built with a material called Indium Tin Oxide (ITO). ITO has excellent optical transparency and electrical conductivity, and the material properties needed for integration in large-scale manufacturing. However, we’re not content with just merely “good enough” nowadays, and need better materials to build ever better devices. Graphene and carbon nanotubes have been considered as suitable replacements, but new research has identified a different possibility: nanowires.

Researchers from the Indian Association for the Cultivation of Science (IACS) and the Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN) in Ireland have demonstrated a seamless silicon nanowire junction that can be used for photodetector and display technology.

Before you get lost in the jargon, let’s take a step back. A nanowire is just a very narrow length of wire, on the order of 1 nanometer across. When silicon is used at this scale, electrical charges can become stuck (called “charge trapping”), which means that the holes and electrons are separated, allowing for transistors and photovoltaics. By controlling where these holes form in the nanowire, you can create a “seamless” junction without using any dopant materials to create impurities, as is done in modern CMOS transistors

These material properties allow the functionality of a junction, but it still needs to be easily and repeatably manufactured. To solve this problem, the team put the nanowire transistors on a flexible polymer, which should enable flexible nanowire applications, such as a roll-up screen.

The first step towards a display is a simple photodetector, just consisting of a basic P-N junction, but they hope this technology will eventually be useful in “smart windows” due to the junctions’ applicability to photodetectors and cameras. Moving to emitting light for displays or creating a solar cell using this technology will probably take some time.

Do you have any experience with different materials for creating junctions? What would you do with a small, transparent photodetector? We’ve featured homebrew solar cells before, as well as creating DIY semiconductors. We’ve also seen silver nanowires for wearable circuits.

[Via IEEE Spectrum]