The idea of making your own semiconductors from scratch would be more attractive if it weren’t for the expensive equipment and noxious chemicals required for silicon fabrication. But simple semiconductors can be cooked up at home without anything fancy, and they can actually yield pretty good results.
Granted, [Simplifier] has been working on the method detailed in the video below for about a year, and a look at his post on copper oxide thin-film solar cells reveals a meticulous approach to optimize everything. He started with regular window glass, heated over a propane burner and sprayed with a tin oxide solution to make it conductive while remaining transparent. The N-type layer was sprayed on next in the form of zinc oxide doped with magnesium. Copper oxide, the P-type layer, was electroplated on next, followed by a quick dip in copper sulfide to act as another transparent conductor. A conductive compound of sodium silicate and graphite was layered on the back to form the electrical contacts. The cell worked pretty well — 525 mV open circuit voltage and 6.5 mA short-circuit current. Not bad for home brewed.
If you want to replicate [Simplifier]’s methods, you’ll find his ample documentation of his site. Of course, if you yearn for DIY silicon semiconductors, there’s a fab for that, too.