Silicon Carbide May Replace Zirconium Alloys For Nuclear Fuel Rod Cladding

Since the construction of the first commercial light water nuclear power plants (LWR) the design of their fuel rods hasn’t changed significantly. Mechanically robust and corrosion-resistant zirconium alloy (zircalloy) tubes are filled with ceramic fuel pellets, which get assembled into fuel assemblies for loading into the reactor.

A 12' SiGa fuel assembly, demonstrating the ability to scale to full-sized fuel rods. (Credit: DoE)
A 12′ SiGa fuel assembly, demonstrating the ability to scale to full-sized fuel rods. (Credit: DoE)

Now it seems that silicon carbide (SiC) may soon replace the traditional zirconium alloy with General Atomics’ SiGa fuel cladding, which has been tested over the past 120 days in the Advanced Test Reactor at Idaho National Laboratory (INL). This completes the first of a series of tests before SiGa is approved for commercial use.

One of the main advantages of SiC over zircalloy is better resistance to high temperatures — during testing with temperatures well above those experienced with normal operating conditions, the zircalloy rods would burst while the SiC ones remained intact (as in the embedded video). Although normally SiC is quite brittle and unsuitable for such structures, SiGa uses a SiC fiber composite, which allows it to be used in this structural fashion.

Although this development is primarily part of the Department of Energy’s Accident Tolerant Fuel Program and its focus on melt-down proof fuel, the switch to SiC could also solve a major issue with zirconium, being its use as a catalyst with hydrogen formation when exposed to steam. Although with e.g. Fukushima Daiichi’s triple meltdown the zircalloy fuel rods were partially destroyed, it was the formation of hydrogen gas inside the reactor vessels and the hydrogen explosions during venting which worsened what should have been a simple meltdown into something significantly worse.

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The Intricacies Of Creating Fuel For Nuclear Reactors

All nuclear fission power reactors run on fuel containing uranium and other isotopes, but fueling a nuclear reactor is a lot more complicated than driving up to them with a dump truck filled with uranium ore and filling ‘er up. Although nuclear fission is simple enough that it can occur without human intervention as happened for example at the Oklo natural fission reactors, within a commercial reactor the goal is to create a nuclear chain reaction that targets a high burn-up (fission rate), with an as constant as possible release of energy.

Each different fission reactor design makes a number of assumptions about the fuel rods that are inserted into it. These assumptions can be about the enrichment ratio of the fissile isotopes like U-235, the density of individual fuel pellets, the spacing between the fuel rods containing these pellets, the configuration of said fuel rods along with any control, moderator and other elements. and so on.

Today’s light water reactors, heavy water reactors, fast neutron reactors, high temperature reactors and kin all have their own fuel preferences as a result, with high-assay low-enriched (HALEU) fuel being the new hot thing for new reactor designs. Let’s take a look at what goes into these fuel recipes.

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