After spending much of the 20th century languishing in development hell, electric cars have finally hit the roads in a big way. Automakers are working feverishly to improve range and recharge times to make vehicles more palatable to consumers.
With a strong base of sales and increased uncertainty about the future of fossil fuels, improvements are happening at a rapid pace. Oftentimes, change is gradual, but every so often, a brand new technology promises to bring a step change in performance. Silicon carbide (SiC) semiconductors are just such a technology, and have already begun to revolutionise the industry.
Mind The Bandgap
Traditionally, electric vehicles have relied on silicon power transistors in their construction. Having long been the most popular semiconductor material, new technological advances have opened it up to competition. Different semiconductor materials have varying properties that make them better suited for various applications, with silicon carbide being particularly attractive for high-power applications. It all comes down to the bandgap.
Electrons in a semiconductor can sit in one of two energy bands – the valence band, or the conducting band. To jump from the valence band to the conducting band, the electron needs to reach the energy level of the conducting band, jumping the band gap where no electrons can exist. In silicon, the bandgap is around 1-1.5 electron volts (eV), while in silicon carbide, the band gap of the material is on the order of 2.3-3.3 eV. This higher band gap makes the breakdown voltage of silicon carbide parts far higher, as a far stronger electric field is required to overcome the gap. Many contemporary electric cars operate with 400 V batteries, with Porsche equipping their Taycan with an 800 V system. The naturally high breakdown voltage of silicon carbide makes it highly suited to work in these applications.
We are normally told that microwave ovens are strictly for food only, and that anything else will cause all sorts of bad things to come our way. There can be few readers who haven’t at some time seen the shower of sparks when an inadvertent metallic object finds its way onto the turntable.
A particularly useful non-food application for a microwave oven comes in the form of the small kilns sold for glass fusing. These are ceramic cylinders coated internally with silicon carbide, and [ShakeTheFuture] shows us how to make your own.
Key to the process is ceramic fibre insulation, which is bonded both to itself and to the fused silicon carbide grit by a cured solution of waterglass, sodium silicate. The result can easily reach the required temperature for fusing glass, but also has an application in burning out surplus wax or PLA from a plaster mould. It’s particularly interesting to see the technique with the waterglass in action, and you can see a run-down of the whole thing in the video below the break.
The guesswork comes in finding the right piece of crystal. First [KOS] broke it into tiny pieces, then he started poking the chunks with electrified probes to see if he could get some light out of them. Once an active area was found he needed a base for the crystal. The image above shows the two nails which he used. This provides a large mounting area that also acts as a heat sink to make sure the LED won’t burn itself out. There’s a solder blob which he kept molten with his iron until the crystal could be pushed into place. That holds it securely as the pin which serves as the cathode is positioned.
The whole setup is soldered to some protoboard and is ready to use. This is the second time we remember seeing this technique used to fabricate LEDS. The first time was an accident.
[Grenadier] had a piece of silicon carbide sitting around that he planned to use when making a primitive diode called a Cat’sWhisker Diode. While probing he noticed that one of the crystals threw off a bit of light. He popped it off and used JB Weld to attach it to a brass plate. The peculiar thing is that it generates light when power is run through it both forward and reverse biased. So what’s going on here? According to an informed discussion on the phenomenon there’s actually a pair of diodes in series but with their polarity reversed.