[Cody] Builds a Chlorine Machine

In his continuing bid to have his YouTube channel demonetized, [Cody] has decided to share how he makes chlorine gas in his lab. Because nothing could go wrong with something that uses five pounds of liquid mercury and electricity to make chlorine, hydrogen, and lye.

We’ll be the first to admit that we don’t fully understand how the Chlorine Machine works. The electrochemistry end of it is pretty straightforward – it uses electrolysis to liberate the chlorine from a brine solution. One side of the electrochemical cell generates chlorine, and one side gives off hydrogen as a byproduct. We even get the purpose of the mercury cathode, which captures the sodium metal as an amalgam. What baffles us is how [Cody] is pumping the five pounds of mercury between the two halves of the cell. Moving such a dense liquid would seem challenging, and after toying with more traditional approaches like a peristaltic pump, [Cody] leveraged the conductivity of mercury to pump it using a couple of neodymium magnets. He doesn’t really explain the idea other than describing it as a “rail-gun for mercury,” but it appears to work well enough to gently circulate the mercury. Check out the video below for the build, which was able to produce enough chlorine to dissolve gold and to bleach cloth.

We need to offer the usual warnings about how playing with corrosive, reactive, and toxic materials is probably not for everyone. His past videos, from turning urine into gunpowder to mining platinum from the side of the road, show that [Cody] is clearly very knowledgeable in the ways of chemistry and that he takes to proper precautions. So if you’ve got a jug of mercury and you want to try this out, just be careful.

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Potassium Chlorate from household products

To the upper right we have very pure potassium chlorate, so much so that it bursts into flames when mixed with sugar and catalyzed with some sulfuric acid. [Mr. Home Scientist] produced the KClO3 using household chemicals and some rudimentary equipment sourced on eBay.

The experiment started off with concentrated bleach containing 8.25% sodium hypochlorite. He needed sodium chlorate so a hot plate was used to boil the bleach until crystals started to form. A more efficient way to achieve this reaction would be using electrolysis (check out the HHO generator we saw recently for a homemade rig). The next step is to add potassium chloride, which is sourced from the grocery store as a sodium-free salt alternative. After mixing with the filtered remains of the bleach reaction the two are combined. There is no precipitate from this — an indication that not everything is as it should be. But an overnight stay in the refrigerator results in the potassium chlorate crystals seen above.

Fiery testing (seen below) lets him know the experiment worked. From here the product can be used for things like making solid rocket engines.

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