Disposing Of PLA And Why Composting Is Not An Option

The ‘biofriendly’ nature of poly(lactic acid) (PLA) filament often gets touted as one of its main advantages over alternatives like PETG, but even a modicum of research ought to inform a person that the biodegrading feature of PLA is only true for pure PLA without additives and at temperatures at or above its glass transition temperature (Tg). Thus the results of a year-long experiment by [I built a thing] shouldn’t be too surprising.

After burying said PLA in the garden like any self-respecting person does who tries to dispose of some evidence, the PLA suffered through a European winter and very hot, dry summer, before being dug up again recently for inspection and testing. Although not the first time that someone has tested this, it’s a good reminder considering just how much PLA filament is used each year.

In total three sample sets were used, one being the control, the other two buried in soil and compost respectively. A visual inspection showed no major difference, and a tensile strength test also showed no statistically significant change among all three sample sets. The experiment could have been concluded here, but instead calorimetry was used in a laboratory setting to see whether exposure to microbes as commonly found in soil does anything significant.

This isothermal microcalorimetry test was performed at the University of Basel, effectively to answer the question whether there’s anything in the PLA samples that can feed said microbes. As it turns out, the answer is a resounding ‘no’, with microbial activity within the presence of PLA dropping off even quicker presumably due to there being less volume available for nutrients.

When [I built a thing] contacted a large number of commercial biodegrading facilities in Switzerland, Germany and the USA, many would happily take PLA, but none of them would accepted 3D-printed PLA parts, which says a lot. The primary reason for this appears to be that even under industrial composting conditions it simply takes too long for these facilities to consider these to be economical to compost.

With PLA primarily degrading via hydrolysis, it needs to be exposed to the right conditions for this process to not take an eternity. You can of course use something like PHA instead, which doesn’t require this hydrolysis step to be biodegradable. Overall PLA is quite a crummy material, with it also suffering from embrittlement due to crystallization that will happily turn a spool of PLA into lots of sad fragments. This makes PETG into a very common and very attractive alternative to PLA.

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Art of 3D printer in the middle of printing a Hackaday Jolly Wrencher logo

3D Printering: Why Is My PLA So Brittle?

Over the years poly(lactic acid) (PLA) – also known as polylactide – has become a popular thermoplastic for a variety of reasons. One of these reasons is that it’s easily produced from a renewable resource, i.e. lactic acid, with the resulting polymer even being compostable if you assume that your compost pile hits a steady 65°C or more, well above the polymer’s glass transition temperature (Tg).

That said, PLA by itself is a pretty crummy material, being exceedingly brittle and inferior to common alternatives like PET(G) in many metrics. Over the decades much research has gone into figuring out this material, its amorphous and crystalline states, as well as how to use plasticizers, copolymers, mechanical manipulation and PLLA/PDLA blends to produce more useful variants of PLA.

Today’s spools of thermoplastic filament that gets marketed as ‘PLA’ are the result of such engineering, though with plenty of remaining issues, as anyone who has struggled through a spool of brittle PLA filament can attest to. Although you can find plenty of tips online about how you should ‘just’ toss said spool into an filament dryer, oven or similar to bake it – with accusing fingers pointed at moisture intrusion, hydrolysis and kin – it helps to understand the fundamentals of how PLA works, and how it degrades.

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Co-Extrusion Carbon Fiber FDM Filament Investigated

After previously putting carbon fiber-reinforced PLA filament under the (electron) microscope, the [I built a thing] bloke is back with a new video involving PLA-CF, this time involving co-extrusion rather than regular dispersed chopped CF. This features a continuous CF core that is enveloped by PLA, with a sample filament spool sent over by BIQU in the form of their CarbonCore25 filament.

In the previous video chopped CF in PLA turned out to be essentially a contaminant, creating voids and with no integration of the CF into the polymer matrix. Having the CF covered by PLA makes the filament less abrasive to print, which is a definitely advantage, but does it help with the final print’s properties? Of note is that this is still chopped CF, just with a longer fiber length (0.3-0.5 mm).

Samples of the BIQU filament were printed on a Bambu Lab H2D printer with AMS. In order to create a clean fracture surface, a sample was frozen in liquid nitrogen to make it easy to snap. After this it was coated with gold using a gold sputtering system to prepare it for the SEM.

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Why Chopped Carbon Fiber In FDM Prints Is A Contaminant

A lot of claims have been made about the purported benefits of adding chopped carbon fiber to FDM filaments, but how many of these claims are actually true? In the case of PLA at least, the [I built a thing] channel on YouTube makes a convincing case that for PLA filament, the presence of chopped CF can be considered a contaminant that weakens the part.

Using the facilities of the University of Basel for its advanced imaging gear, the PLA-CF parts were subjected to both scanning electron microscope (SEM) and Micro CT imaging. The SEM images were performed on the fracture surfaces of parts that were snapped to see what this revealed about the internal structure. From this, it becomes apparent that the chopped fibers distribute themselves both inside and between the layers, with no significant adherence between the PLA polymer and the CF. There is also evidence for voids created by the presence of the CF.

To confirm this, an intact PLA-CF print was scanned using a Micro CT scanner over 13 hours. This confirmed the SEM findings, in that the voids were clearly visible, as was the lack of integration of the CF into the polymer. This latter point shouldn’t be surprising, as the thermal coefficient of PLA is much higher than that of the roughly zero-to-negative of CF. This translates into a cooling PLA part shrinking around the CF, thus creating the voids.

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Bambu Lab’s PLA Tough+ Filament: Mostly A Tough Sell

Beyond the simple world of basic PLA filaments there is a whole wild world of additives that can change this humble material for better or worse. The most common additives here are primarily to add color, but other additives seek to specifically improve certain properties of PLA. For example Bambu Lab’s new PLA Tough+ filament series that [Dr. Igor Gaspar] over at the My Tech Fun YouTube channel had over for reviewing purposes.

According to Bambu Lab’s claims for the filament, it’s supposed to have ‘up to’ double the layer adhesion strength as their basic PLA, while being much more robust when it comes to flexing and ‘taking a beating’. Yet as [Igor] goes through his battery of tests – comparing PLA Tough+ against the basic PLA – the supposedly tough filament is significantly worse in every count. That sad streak lasts until the impact tests, which is where we see a curious set of results – as shown above – as well as [Igor]’s new set of impact testing toys being put through their paces.

Of note is that although the Tough+ variants tested are consistently less brittle than their basic PLA counterparts, the Silver basic PLA variant makes an unexpectedly impressive showing. This is a good example of how color additives can have very positive impacts on a basic polymer like PLA, as well as a good indication that at least Bambu Lab’s Basic PLA in its Silver variant is basically better than Tough+ filaments. Not only does it not require higher printing temperatures, it also doesn’t produce more smelly VOCs, while being overall more robust.

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Elegoo Rapid PETG Vs PETG Pro: Same Price, Similar Specs, Which To Buy?

Even within a single type of FDM filament there is an overwhelming amount of choice. Take for example Elegoo’s PETG filament offerings, which include such varieties like ‘Pro’ and ‘Rapid’. Both cost the same, but is there a reason to prefer one over the other, perhaps even just for specific applications? To test this, [Dr. Igor Gaspar] over at the My Tech Fun YouTube channel bought some spools of these two filaments and subjected both to a series of tests.

Obviously, the Rapid filament is rated for higher extrusion speeds – <270 vs <600 mm/s – while the website claims a higher required nozzle temperature that confusingly does not match those listed on the spool. There are quite a few differences in the listed specifications, including the physical and mechanical properties, which make it hard to draw any immediate conclusions. Could you perhaps just use Rapid PETG and forget about the Pro version?

Test objects were printed with a Bambu Lab P1P with an AMS unit. After calibrating the ideal temperature for each filament, a tensile break test gave a win to the Rapid PETG, followed by a layer adhesion test win. This pattern continued across further tests, with Rapid PETG either matching or beating the Pro PETG.

There are only two advantages of the Pro version that can be seen here, which are less moisture sensitivity and  stringing risk, and you of course get the luxury cardboard spool with the closed edges. Whether that’s enough to make you go ‘Pro’ remains to be seen, of course.

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Introducing PooLA Filament: Grass Fiber-Reinforced PLA

We’re probably all familiar with adding wood dust, hemp and carbon fibers to PLA filament, but there are so many other fillers one could add. During the completely unrelated recent heatwave in Germany, [Stefan] from CNCKitchen decided to give a new type of biodegradable filler type a shot by scooping some freshly dried cow patties off the very picturesque grazing fields near his place. In the resulting video a number of questions are answered about this ‘PooLA’ that nobody was asking, such as whether it makes for a good filler, and whether it smells bad while printing.

Perhaps unsurprisingly to those who have spent any amount of time around large herbivores like cows, cow dung doesn’t smell bad since it’s mostly composed of the grass fibers that are left over after the cow’s multiple stomachs and repeated chewing have done their thing. As [Stefan] and his colleagues thus found out was that printing with PooLA smells like printing with grass.

As for the practical benefits of PooLA, it adds a nice coloring, but like other ‘reinforced’ PLA filaments seems to trade flexibility for stiffness, so that at ratios of cow dung powder between 5 to 20% added to the PLA powder the test parts would break faster. Creating the filament was also a bit of a chore, for reasons that [Stefan] still has to figure out.

That said, aside from the technically unneeded bacterial corpses and other detritus in cow patties, using grass fibers in FDM filament isn’t a crazy idea, and might fit right in there with other fibers.

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