Despite the reputation of polymers used with FDM 3D printing like nylon, ABS, and PLA as being generally indestructible, they do come with a whole range of moisture-related issues that can affect both the printing process as well as the final result. While the concept of ‘baking’ such 3D printing filaments prior to printing to remove absorbed moisture is well-established and with many commercial solutions available, the exact extent to which these different polymers are affected, and what these changes look like on a molecular level are generally less well-known.

Another question with such hygroscopic materials is whether the same issues of embrittlement, swelling, and long-term damage inflicted by moisture exposure that affects filaments prior to printing affects these materials post-printing, and how this affects the lifespan of FDM-printed items. In a 2022 paper by Adedotun D. Banjo and colleagues much of what we know today is summarized in addition to an examination of the molecular effects of moisture exposure on polylactic acid (PLA) and nylon 6.

The scientific literature on FDM filaments makes clear that beyond the glossy marketing there is a wonderful world of materials science to explore, one which can teach us a lot about how to get good FDM prints and how durable they will be long-term.

Continue reading “FDM Filament Troubles: Keeping Hygroscopic Materials From Degrading” →