A red, cuboid electrochemical cell is in the center of the picture, with a few wires protruding from the front. Tubes run from each side of the cell to a peristaltic pump and tank on each side. The frame holding the pumps and tanks is white 3D printed plastic.

An Open Source Flow Battery

The flow battery is one of the more interesting ideas for grid energy storage – after all, how many batteries combine electron current with fluid current? If you’re interested in trying your hand at building one of these, the scientists behind the Flow Battery Research Collective just released the design and build instructions for a small zinc-iodide flow battery.

The battery consists of a central electrochemical cell, divided into two separated halves, with a reservoir and peristaltic pump on each side to push electrolyte through the cell. The cell uses brass-backed grafoil (compressed graphite sheets) as the current collectors, graphite felt as porous electrodes, and matte photo paper as the separator membrane between the electrolyte chambers. The cell frame itself and the reservoir tanks are 3D printed out of polypropylene for increased chemical resistance, while the supporting frame for the rest of the cell can be printed from any rigid filament.

The cell uses an open source potentiostat to control charge and discharge cycles, and an Arduino to control the peristaltic pumps. The electrolyte itself uses zinc chloride and potassium iodide as the main ingredients. During charge, zinc deposits on the cathode, while iodine and polyhalogen ions form in the anode compartment. During discharge, zinc redissolves in what is now the anode compartment, while the iodine and polyhalogen ions are reduced back to iodides and chlorides. Considering the stains that iodide ions can leave, the researchers do advise testing the cell for leaks with distilled water before filling it with electrolyte.

If you decide to try one of these builds, there’s a forum available to document your progress or ask for advice. This may have the clearest instructions, but it isn’t the only homemade flow cell out there. It’s also possible to make these with very high energy densities.

Bath County Pumped Storage Station (Credit: CHA)

Grid-Level Energy Storage And The Challenge Of Storing Energy Efficiently

Although every electrical grid begins with the production of electricity, there are times when storing this power in some form instead of using it immediately is highly convenient. Today’s battery-powered gadgets are an obvious example of such time-shifting, but energy storage plays a major role on the grid itself, too, whether in electrochemical, mechanical or in some other form.

Utility-level energy storage is essential for not only stabilizing the grid, but also to time-shift excess energy and provide a way to deal with sudden spikes in demand (peak-shaving) plus demand drops by absorbing the excess energy. The health of the grid can essentially be regarded as a function of its alternating current (AC) frequency, with strong deviations potentially leading to a collapse of the grid.

Naturally, such energy storage is not free, and the benefits of adding it to the grid have to be considered against the expense, as well as potential alternatives. With the rapid increase of highly volatile electrical generators on the grid in the form of non-dispatchable variable renewable energy, e.g. wind turbines and PV solar, there has been a push to store more excess power rather than curtailing it, in addition to using energy storage for general grid health.

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