perovskite

5 Articles

First Tentative Sales Of Tandem Perovskite-Silicon PV Panels

September 29, 2024 by 18 Comments

To anyone who has spent some time in photovoltaic (PV) power circles, the word ‘perovskite’ probably sounds familiar. Offering arguably better bandgap properties than traditional silicon cells, perovskite-based PV panels also promise to be cheaper and (literally) more flexible, but commercialization has been elusive. This is something which Oxford PV seeks to change, with the claim that they will be shipping the first hybrid perovskite-silicon panels to a US customer.

Although Oxford PV prefers to keep the details of their technology classified, there have been decades of research on pure perovskite PV cells as well as tandem perovskite-silicon versions. The reason for the tandem (i.e. stacked) construction is to use more of the solar rays’ spectrum and total energy to increase output. The obvious disadvantage of this approach is that you need to find ways to make each layer integrate in a stable fashion, with ideally the connecting electrodes being transparent. A good primer on the topic is found in this 2021 review article by [Yuanhang Cheng] and [Liming Ding].

The primary disadvantage of perovskites has always been their lack of longevity, with humidity, UV irradiation, temperature and other environmental factors conspiring against their continued existence. In a 2022 study by [Jiang Liu] et al. in Science it was reported that a perovskite-silicon tandem solar cell lost about 5% of its initial performance after 1,000 hours. A 2024 study by [Yongbin Jin] et al. in Advanced Materials measured a loss of 2% after approximately the same timespan. At a loss of 2%/1,000 hours, the perovskite layer would be at 50% of its initial output after 25,000 hours, or a hair over 2.85 years.

A quick glance through the Oxford PV website didn’t reveal any datasheets or other technical information which might elucidate the true loss rate, so it would seem that we’ll have to wait a while longer on real data to see whether this plucky little startup has truly cracked the perovskite stability issue.

Top image: Summary of tandem perovskite-silicon solar cell workings. (Credit: Yuanhang Cheng, Liming Ding, SusMat, 2021)

PeLEDs: Using Perovskites To Create LEDs Which Also Sense Light

July 7, 2024 by 12 Comments

With both of the dominant display technologies today – LCD and OLED – being far from perfect, there is still plenty of room in the market for the Next Big Thing. One of the technologies being worked on is called PeLED, for Perovskite LED. As a semiconductor material, it can both be induced to emit photons as well as respond rather strongly to incoming photons. That is a trick that today’s displays haven’t managed without integrating additional sensors. This technology could be used to create e.g. touch screens without additional hardware, as recently demonstrated by [Chunxiong Bao] and colleagues at Linköping University in Sweden and Nanjing University in China.

Their paper in Nature Electronics describes the construction of photo-responsive metal halide perovskite pixels, covering the typical red (CsPbI3−xBrx), green (FAPbBr3), and blue (CsPbBr3−xClx) wavelengths. The article also describes the display’s photo-sensing ability to determine where a finger is placed on the display. In addition, it can work as an ambient light sensor, a scanner, and a solar cell to charge a capacitor. In related research by [Yun Gao] et al. in Nature Electronics, PeLEDs are demonstrated with 1 microsecond response time.

As usual with perovskites, their lack of stability remains their primary obstacle. In the article by [Chunxiong Bao] et al. the manufactured device with red pixels was reduced to 80% of initial brightness after 18.5 hours. While protecting the perovskites from oxygen, moisture, etc. helps, this inherent instability may prevent PeLEDs from ever becoming commercialized in display technology. Sounds like a great challenge for the next Hackaday Prize!

Stacking Solar Cells Is A Neat Trick To Maximise Efficiency

March 7, 2024 by 51 Comments

Solar power is already cheap and effective, and it’s taking on a larger role in supplying energy needs all over the world. The thing about humanity, though, is that we always want more! Too much, you say? It’s never enough!

The problem is that the sun only outputs so much energy per unit of area on Earth, and solar cells can only be so efficient thanks to some fundamental physical limits. However, there’s a way to get around that—with the magic of tandem solar cells!

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Overall design of retina-inspired NB perovskite PD for panchromatic imaging. (Credit: Yuchen Hou et al., 2023)

Perovskite Sensor Array Emulates Human Retina For Panchromatic Imaging

June 2, 2023 by 13 Comments

The mammalian retina is a complex system consisting out of cones (for color) and rods (for peripheral monochrome) that provide the raw image data which is then processed into successive layers of neurons before this preprocessed data is sent via the optical nerve to the brain’s visual cortex. In order to emulate this system as closely as possible, researchers at Penn State University have created a system that uses perovskite (methylammonium lead bromide, MAPbX3) RGB photodetectors and a neuromorphic processing algorithm that performs similar processing as the biological retina.

Panchromatic imaging is defined as being ‘sensitive to light of all colors in the visible spectrum’, which in imaging means enhancing the monochromatic (e.g. RGB) channels using panchromatic (intensity, not frequency) data. For the retina this means that the incoming light is not merely used to determine the separate colors, but also the intensity, which is what underlies the wide dynamic range of the Mark I eyeball. In this experiment, layers of these MAPbX3 (X being Cl, Br, I or combination thereof) perovskites formed stacked RGB sensors.

The output of these sensor layers was then processed in a pretrained convolutional neural network, to generate the final, panchromatic image which could then be used for a wide range of purposes. Some applications noted by the researchers include new types of digital cameras, as well as artificial retinas, limited mostly by how well the perovskite layers scale in resolution, and their longevity, which is a long-standing issue with perovskites. Another possibility raised is that of powering at least part of the system using the energy collected by the perovskite layers, akin to proposed perovskite-based solar panels.

(Heading: Overall design of retina-inspired NB perovskite PD for panchromatic imaging. (Credit: Yuchen Hou et al., 2023) )

Perovskite Solar: Coming Soon?

July 15, 2016 by 35 Comments

Making solar cells out of silicon is difficult. There’s plenty of manufacturing steps, many of them at very high temperatures, and you need a high vacuum and a clean room. However, perovskite solar cells–cells made with hybrid organic-inorganic materials in a perovskite crystal structure–are relatively easy to make using wet chemistry involving solvents or vapor deposition.

In theory, silicon solar cells could be 30% efficient, but in reality, 25% seems to be a practical limit with commercial cells typically topping out at 20%. Perovskite cells are nearly that high now, and could be higher by stacking thin layers, each sensitive to different wavelengths of light.

A recent development at the Lawrence Berkeley National Laboratory may lead to even more efficient perovskite cells. Researchers found that certain crystal structures had a much higher efficiency than other structures. The problem now is figuring out how to produce the crystals to increase the prevalence of that structure.

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