Busting The Myth That Plastics Are Chemically Inert In Water

One of the often made claims about plastics is that they are chemically inert under most conditions, such as when exposed to water. This long-held belief has also challenged the notion that micro- and nanoplastics (MNPs) are dangerous to organisms such as us human animals. A hitherto unknown mechanism between common plastics as investigated by [Naixin Qian] et al. and published in Nature serves to generate highly reactive hydroxyl radicals when exposed to water.

Hydroxyl radicals (HO•) are the neutral form of the hydroxide ion (OH–). It’s a free radical that tends to be extremely short-lived due to its reactivity, much like the singular oxygen molecule that is freed at the plastic-water interface. The energy provided for this reactivity comes from the electrostatic effect, itself highly correlated with many plastics, with the six types of microplastics used in the experiment showing varying levels of free radicals, particularly for the more hydrophobic types.

This high reactivity of free radicals is a well-known problem in cellular biology, with evolution having developed many tools over the years to deal with capturing these radicals as well as repair the (DNA) damage that they can cause. The effect of these microplastics and their generated free radicals was thus studied as well.

Of note here is that the electrostatic effect itself already serves to draw charged biomolecules to it, before the impact of free radicals is considered. By using mouse red blood cells and exposing them to polystyrene (PS) microplastics fatal damage was observed to the red blood cells.

This indicates that there are at least three possible ways in which MNPs can be harmful to organisms. It also provides another clue to how this may affect the ageing of plastics, among other implications.

Currently there is still ongoing debate on whether MNPs are truly harmful and just how prevalent they may be in e.g. our bodies. Reliably detecting them in e.g. biological tissues remains a challenge, which this new study may also be helpful with, since one of our biggest blind spots is that we lack solid knowledge of how MNPs may behave inside an organism.

An exploded view of an electrostatic motor from manufacturer C-Motive. There is a silvery cylinder on the left, two half silver and half golden disks on either side and two thinner gold disks in the center. A square mountin plate is on the right hand side next to one of the silver/gold disks.

Electrostatic Motors Are Making A Comeback

Electrostatic motors are now common in MEMS applications, but researchers at the University of Wisconsin and spinoff C-Motive Technologies have brought macroscale electrostatic motors back. [via MSN/WSJ]

While the first real application of an electric motor was Ben Franklin’s electrostatically-driven turkey rotisserie, electromagnetic type motors largely supplanted the technology due to the types of materials available to engineers of the time. Newer dielectric fluids and power electronics now allow electrostatic motors to be better at some applications than their electromagnetic peers.

The main advantage of electrostatic motors is their reduced critical materials use. In particular, electrostatic motors don’t require copper windings or any rare earth magnets which are getting more expensive as demand grows for electrically-powered machines. C-Motive is initially targeting direct drive industrial applications, and the “voltage driven nature of an electrostatic machine” means they require less cooling than an electromagnetic motor. They also don’t use much if any power when stalled.

Would you like a refresher on how to make static electricity or a deeper dive on how these motors work?

Static Electricity And The Machines That Make It

Static electricity often just seems like an everyday annoyance when a wool sweater crackles as you pull it off, or when a doorknob delivers an unexpected zap. Regardless, the phenomenon is much more fascinating and complex than these simple examples suggest. In fact, static electricity is direct observable evidence of the actions of subatomic particles and the charges they carry.

While zaps from a fuzzy carpet or playground slide are funny, humanity has learned how to harness this naturally occurring force in far more deliberate and intriguing ways. In this article, we’ll dive into some of the most iconic machines that generate static electricity and explore how they work.

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A modern recreation of von Guericke's electrostatic generator

Electrostatic Generator Project Starts With Molten Sulfur

Although the basic concept of electrostatic attraction has been known since ancient times, it was only in the 17th century that scientists began to systematically investigate electrostatics. One of the first to explore this new field was Otto von Guericke, who constructed an electrostatic generator to help with his experiments. [Markus Bindhammer] has reconstructed this machine, which formed the basis for later work by the likes of Wimshurst and Van de Graaff. [Markus] kept his machine in an almost period-correct fashion.

Von Guericke’s machine consists of a sulfur ball mounted on a spindle that allows it to be rotated and rubbed against a piece of cloth. By doing so, the ball gains a charge that can be used to attract small pieces of material. [Markus] built a neat wooden frame with faux-antique carved legs and installed a handle, a spindle, and a belt-drive system to rotate whatever’s mounted on the spindle at high speed.

A round-bottom flask containing sulfur being heated in an oil bathAll of this is beautifully documented in [Markus]’s video, but by far the most interesting part of his project is the process of manufacturing the sulfur ball. If you’ve always wanted one, here’s how to make one: first, melt some pieces of pure sulfur in a round-bottom flask using an oil bath. Then, turn on your vacuum pump to remove any air or water vapor trapped inside the liquid. Once the liquid is nice and clear, let it cool down and solidify very slowly; the sulfur ball can then be released from its container by breaking the glass with a hammer.

While it sounds simple, we can imagine it took a bit of experimenting to get all those steps just right. The end result is a simple but useful machine to demonstrate basic electrostatics, which [Markus] is planning to use in science lectures. There are lots of interesting experiments you can do with static electricity, including building a basic motor.

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