Promethean Matches: The Ancestor To Modern Matches

December 25, 2023 by Maya Posch 7 Comments

The history of making fire at will is a long and storied one, stretching back to the days when we’d rub wooden sticks together, or use flint and steel to ignite tinder. An easier, albeit vastly more expensive and dangerous alternative came in the 19th century when chemists discovered auto-ignition using a potassium chlorate mixture and sulfuric acid. This method was refined and later patented by Samuel Jones in 1828 as the ‘promethean match’ after the God of Fire, Prometheus, which is the topic of a recent [NurdRage] chemistry video.

Using practically the same recipe of potassium chlorate and sugar as in the 19th century, [NurdRage] uses paper straws to contain this powder. Glue is used to section the paper straw into two compartments and seal in the components, with the smaller compartment used for a glass capsule containing sulfuric acid. This vial was produced from the tip of a glass pipette, using a hot flame to first seal the tip, then detach and seal the other end of the tip, resulting in the sulfuric acid capsule, ready to be added to the second compartment.

The moment this glass capsule is crushed, the sulfuric acid will soak into the paper, reaching the large compartment with the potassium chlorate and sugar mixture, causing a strongly exothermic reaction that ignites the paper. Yet as simple as this sounds, [NurdRage] found the three matches he made to be rather fickle, with one igniting beautifully after crushing the capsule with pliers, while one did nothing and the remaining match decided to violently explode rather than burn.

Considering the immense manual labor involved in making these matches, they never were very popular, and were quickly replaced by strike-anywhere matches, followed by safety matches, none of which require you to carry fragile glass capsules containing sulfuric acid with you. As a chemistry experiment, it is however a total blast that will set any boring chemistry class on fire.

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Scaled-Up Matches Are Hilarious And Moderately Effective

September 20, 2023 by Lewin Day 22 Comments

Regular matches are fine for lighting candles and the like, but they’re a bit small and fiddly to use. After seeing some giant prop matches used in a stage play, [Handy Bear] decided to see if they could build some functional extra-large matches at home.

The build starts with a square wooden dowel, cut into lengths to serve as the main body of the matches. Regular tiny matches were then harvested for their flammable matchheads, made of potassium chlorate. Sourcing the material this way is far simpler than attempting a chemical synthesis from raw materials. Once roughly ground, the material was glued on to the end of the wooden rod to finish the match. [Handy Bear] then whipped up a giant matchbox to suit, using the ignition strips from multiple smaller matchboxes in the process.

Impressively, the monster matches work, and work well. They readily ignite when struck, and are able to keep a strong flame burning for some time. However they’re not quite potent enough to fully ignite the wood, so they don’t burn down like the real thing. We could see these being a great way to light a campfire with less hassle than regular matches, even if they are a bulky solution to the problem.

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