Reinforcing Plastic Polymers With Cellulose And Other Natural Fibers

September 9, 2024 by Maya Posch 10 Comments

While plastics are very useful on their own, they can be much stronger when reinforced and mixed with a range of fibers. Not surprisingly, this includes the thermoplastic polymers which are commonly used with FDM 3D printing, such as polylactic acid (PLA) and polyamide (PA, also known as nylon). Although the most well-known fibers used for this purpose are probably glass fiber (GF) and carbon fiber (CF), these come with a range of issues, including their high abrasiveness when printing and potential carcinogenic properties in the case of carbon fiber.

So what other reinforcing fiber options are there? As it turns out, cellulose is one of these, along with basalt. The former has received a lot of attention currently, as the addition of cellulose and similar elements to thermopolymers such as PLA can create so-called biocomposites that create plastics without the brittleness of PLA, while also being made fully out of plant-based materials.

Regardless of the chosen composite, the goal is to enhance the properties of the base polymer matrix with the reinforcement material. Is cellulose the best material here?

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Instant Filament Drying Satisfies An Immediate Need

July 2, 2024 by Bob Baddeley 33 Comments

Most 3D printer filament soaks up water from the air, and when it does, the water passing through the extruder nozzle can expand, bubble, and pop, causing all kinds of mayhem and unwanted effects in the print. This is why reels come vacuum sealed. Some people 3D print so much that they consume a full roll before it can soak up water and start to display these effects. Others live in dry climates and don’t have to worry about humidity. But the rest of us require a solution. To date, that solution has been filament dryers, which are heated elements in a small reel-sized box, or for the adventurous an oven put at a very specific temperature until the reel melts and coats the inside of the oven. The downside to this method is that it’s a broad stroke that takes many hours to accomplish, and it’s inefficient because one may not use the whole roll before it gets soaked again.

In much the same way that instant water heaters exist to eliminate the need for a water heater, [3DPI67] has a solution to this problem, and it involves passing the filament through a small chamber with a heating element and fan circulating air. The length of the chamber is important, as is the printing speed, since the filament needs to have enough time in the improvised sauna to sweat out all its water weight. The temperature of the chamber can’t get above the glass transition temperature of the filament, either, which is another limiting factor for the dryer. [3DPI67] wrote up a small article on his improvised instant filament heater in addition to the video.

So far, only TPU has been tested with this method, but it looks promising. Some have suggested a larger chamber with loops of filament so that more can be exposed for longer. There’s lots of room for innovation, and it seems some math might be in order to determine the limits and optimizations of this method, but we’re excited to see the results.

A man in a red plaid shirt draped over an olive t-shirt holds sandpaper in one hand an an aluminum tube filled with white beads in the other over a wooden table.

Activated Alumina For Desiccating Your Filament

June 27, 2024 by Navarre Bartz 22 Comments

When you first unwrap a shiny new roll of filament for your FDM printer, it typically has a bag of silica gel inside. While great for keeping costs low on the manufacturing side, is silica gel the best solution to keep your filament dry at home?

Frustrated with the consumable nature and fussy handling of silica gel beads, [Build It Make It] sought a more permanent way to keep his filament dry. Already familiar with activated alumina beads, he crafted a desiccant cylinder that can be popped into the oven all at once instead of all that tedious mucking about with emptying and refilling plastic capsules.

A length of aluminum intake pipe, some high temperature epoxy, and aluminum mesh are all combined to make a simple, sealed cylinder. During the process, he found that using a syringe filled with the epoxy led to a much more precise application to the aluminum cylinder, so he recommends starting out that way if you make these for yourself.

We suspect something with a less permanent attachment at one end would let you periodically swap out the beads if you wanted to try this hack with the silica beads you already had. Perhaps some kind of threaded pipe fitting? If you want a more active dryer, try making one with a Peltier. If you want to know just how dry your filament is getting, you could also put in a sensor. You might also wonder, do you really need to dry filament at all?

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On The Merits Of A Solid-State Dehumidifier Filament Dry Box

March 2, 2024 by Maya Posch 42 Comments

How good are ion membrane dehumidifiers for keeping FDM filament dry and ready for printing? This is the question which [Stefan] at CNC Kitchen sought to answer in a recent video. Like many of us, he was inspired by a video which [Big Clive] made a while ago in which said dehumidifiers were demonstrated for keeping an enclosure free from moisture. Yet would they be able to tackle the much bigger drying job of one or more spools of filament? Thanks to some free samples sent by Rosahl, [Stefan] was able to start answering this question.

Performance of desiccants and dehumidifier element. (Credit CNC Kitchen)

In the experiments, he used the smaller RS1 (€36.25 a piece) for a single spool container, and the larger MDL-3 (€169) with a Bambu Lab AMS multi-spool unit. Normally such an AMS has three big containers with silica desiccant in it that have to be regularly swapped out, but he modified one AMS to only have the big MDL-3 membrane to dehumidify. A second AMS was left with older silica in its containers, and a third got fresh silica, allowing for some benchmarking between the three units.

The results say a lot, with the initial empty AMS test showing the older silica desiccants topping out quickly and leaving the fresh silica and the membrane dehumidifier to go neck to neck. This is not the usual scenario in which you’d use these dehumidification methods of course, and the small-scale test with the RS1 showed that with a full filament spool in the box, humidity inside the container would only drop very gradually as more and more moisture replaced what was removed from the air. In particular the cardboard element of the spool being used was suspected of being one of the biggest sources of moisture.

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3D Printing With Plastic Cutlery

December 25, 2023 by Al Williams 18 Comments

How many plastic spoons, knives, and forks do you think we throw away daily? [Stefan] noted that the compostable type is made from PLA, so why shouldn’t you be able to recycle it into 3D printing stock? How did it work? Check it out in the video below.

[Stefan] already has a nice setup for extruding filament. However, unsurprisingly, it won’t accept spoons and forks directly. A blender didn’t help, so he used an industrial plastic shredder. It reduced the utensils to what looked like coarse dust, which he then dried out. After running it through the extruder, the resulting filament was thin and brittle. [Stefan] speculates the plastic was set up for injection molding, but it at least showed the concept had merit.

In a second attempt, he cut the ground-up utensils with fresh PLA in equal measures. That is, 50% of the mix was recycled, and half was not. That made much more usable filament. So did a different brand of compostable plasticware.

The real test was to take dirty plasticware. This time, he soaked utensils in tomato sauce overnight. He cleaned, dried, and shredded the plastic. This time, he used 20% new PLA and some pigment, as well. We aren’t sure this is worth the effort simply on economics, but if you are committed to recycling, this might be worth your while.

It always seems like it should be easy to extrude filament. Until you try to do it, of course. Recycling plastic bottles is especially popular.

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Four images in as many panes. Top left is a fuchsia bottle with a QR code that only shows up on the smartphone screen held above it. Top right image is A person holding a smartphone over a red wristband. The phone displays a QR code on its screen that it sees but is invisible in the visible wavelengths. Bottom left is a closeup of the red wristband in visible light and the bottom right image is the wristband in IR showing the three QR codes embedded in the object.

Fluorescent Filament Makes Object Identification Easier

August 17, 2023 by Navarre Bartz 14 Comments

QR codes are a handy way to embed information, but they aren’t exactly pretty. New work from MIT’s Computer Science and Artificial Intelligence Laboratory (CSAIL) have a new way to produce high contrast QR codes that are invisible. [PDF]

If this sounds familiar, you may remember CSAILs previous project embedding QR codes into 3D prints via IR-transparent filament. This followup to that research increases the detection of the objects by using an IR-fluorescent filament. Another benefit of this new approach is that while the InfraredTags could be any color you wanted as long as it was black, BrightMarkers can be embedded in objects of any color since the important IR component is embedded in traditional filament instead of the other way around.

One of the more interesting applications is privacy-preserving object detection since the computer vision system only “sees” the fluorescent objects. The example given is marking a box of valuables in a home to be detected by interior cameras without recording the movements of the home’s occupants, but the possibilities certainly don’t end there, especially given the other stated application of tactile interfaces for VR or AR systems.

We’re interested to see if the researchers can figure out how to tune the filament to fluoresce in more colors to increase the information density of the codes. Now, go forth and 3D print a snake with snake in a QR code inside!

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The Effect Of Filament Color On Print Strength And More

February 5, 2023 by Maya Posch 16 Comments

What is an FDM filament coloring’s purpose but to be an aesthetic choice? As it turns out, the additives that create these changes in coloring and transparency also affect the base properties of the polymer, whether it’s PLA, PETG, or another material. This is where a recent video by [CNC Kitchen] is rather illustrative, using a collection of colored PLA filaments from a single filament manufacturer.

[CNC Kitchen] ran a range of tests including tensile strength, ductility, layer adhesion, impact resistance, and annealing performance. The results showed no clear overall winner between plain PLA polymer and any specific color. Perhaps most fascinating was just how much these color additives change the material’s response to annealing. Baking the PLA at 100°C for 30 minutes generally improves material properties, but also can cause warping and shrinking. The effective warping and shrinking differed wildly between the filament.

The general conclusion would seem to be that the natural polymer isn’t necessarily the optimal choice, but that you should test and pick the filament from a specific manufacturer to fit your project’s needs.

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