green hydrogen

3 Articles

Hydrogen Generation With Seawater, Aluminum, And… Coffee?

August 12, 2024 by 56 Comments

A team at MIT led by [Professor Douglas Hart] has discovered a new, potentially revelatory method for the generation of hydrogen. Using seawater, pure aluminum, and components from coffee grounds, the team was able to generate hydrogen at a not insignificant rate, getting the vast majority of the theoretical yield of hydrogen from the seawater/aluminum mixture. Though the process does use indium and gallium, rare and expensive materials, the process is so far able to recover 90% of the indium-gallium used which can then be recycled into the next batch. Aluminum holds twice as much energy as diesel, and 40x that of Li-Ion batteries. So finding a way to harness that energy could have a huge impact on the amount of fossil fuels burned by humans!

Pure, unoxidized aluminum reacts directly with water to create hydrogen, as well as aluminum oxyhydroxide and aluminum hydroxide. However, any aluminum that has had contact with atmospheric air immediately gets a coating of hard, unreactive aluminum oxide, which does not react in the same way. Another issue is that seawater significantly slows the reaction with pure aluminum. The researchers found that the indium-gallium mix was able to not only allow the reaction to proceed by creating an interface for the water and pure aluminum to react but also coating the aluminum pellets to prevent further oxidization. This worked well, but the resulting reaction was very slow.

Apparently “on a lark” they added coffee grounds. Caffeine had already been known to act as a chelating agent for both aluminum and gallium, and the addition of coffee grounds increased the reaction rate by a huge margin, to the point where it matched the reaction rate of pure aluminum in deionized, pure water. Even with wildly varying concentrations of caffeine, the reaction rate stayed high, and the researchers wanted to find out specifically which part of the caffeine molecule was responsible. It turned out to be imidazole, which is a readily available organic compound. The issue was balancing the amount of caffeine or imidazole added versus the gallium-indium recovery rate — too much caffeine or imidazole would drastically reduce the recoverable amount of gallium-indium.

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Renewable Energy: Beyond Electricity

December 18, 2023 by 72 Comments

Perhaps the most-cited downside of renewable energy is that wind or sunlight might not always be available when the electrical grid demands it. As they say in the industry, it’s not “dispatchable”. A large enough grid can mitigate this somewhat by moving energy long distances or by using various existing storage methods like pumped storage, but for the time being some amount of dispatchable power generation like nuclear, fossil, or hydro power is often needed to backstop the fundamental nature of nature. As prices for wind and solar drop precipitously, though, the economics of finding other grid storage solutions get better. While the current focus is almost exclusively dedicated to batteries, another way of solving these problems may be using renewables to generate hydrogen both as a fuel and as a means of grid storage. Continue reading “Renewable Energy: Beyond Electricity” →

Making Hydrogen With Solar Energy, With Oxygen And Heat A Bonus

April 27, 2023 by 66 Comments

Hydrogen is a useful gas. Whether you want to float an airship, fuel a truck, or heat an industrial process, hydrogen can do the job. However, producing it is currently a fraught issue. While it can be produced cleanly using renewable energy, it’s often much cheaper to split it out of hydrocarbon fuels using processes that generate significant pollution.

There are methods to generate hydrogen more efficiently, though, in a clean and sustainable process. that also produces useful heat and oxygen as byproducts. The key to the process? Concentrated sunshine.
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