hydrogen

50 Articles

Swiss Researchers May Have Solved Hydrogen Storage

September 1, 2024 by 102 Comments

If you follow the world of clean energy, you will probably have read all about the so-called hydrogen future and the hydrogen economy. The gas can easily be made from water by electrolysis from green solar electricity, contains a lot of stored energy which is clean to recover, and seems like the solution to many of our green energy woes. Sadly the reality doesn’t quite match up as hydrogen is difficult to store and transport, so thus far our hydrogen cars haven’t quite arrived. That hasn’t stopped researchers looking at hydrogen solutions though, and a team from ETH Zurich might just have found a solution to storing hydrogen. They’re using it to reduce iron oxide to iron, which can easily release the hydrogen by oxidation with water.

Their reactor is simplicity itself, a large stainless steel tank filled with powdered iron ore. Pump hydrogen into it and the iron oxide in the ore becomes water and iron which forms the storage medium, and retrieve the hydrogen later by piping steam through the mixture. Hydrogen generated in the summer using solar power can then be released in the winter months. Of course it’s not perfectly efficient, and a significant quantity of energy is lost in heat, but if the heat is recovered and used elsewhere that effect can be mitigated. The hope is that their university might be benefiting from a pilot plant in the coming years, and then perhaps elsewhere those hydrogen grids and cars might become a reality. We can hope.

Meanwhile, in the past we’ve looked at a not quite so green plan for a hydrogen grid.

Pulling Hydrogen Out Of The Water

August 20, 2024 by 23 Comments

In theory, water and electric current will cause electrolysis and produce oxygen and hydrogen as the water breaks apart. In practice, doing it well can be tricky. [Relic] shows an efficient way to produce an electrolysis cell using a few plastic peanut butter jars and some hardware.

The only tricky point is that you need hardware made of steel and not zinc or other materials. Well, that and the fact that the gasses you produce are relatively dangerous.

Continue reading “Pulling Hydrogen Out Of The Water” →

Hydrogen Generation With Seawater, Aluminum, And… Coffee?

August 12, 2024 by 56 Comments

A team at MIT led by [Professor Douglas Hart] has discovered a new, potentially revelatory method for the generation of hydrogen. Using seawater, pure aluminum, and components from coffee grounds, the team was able to generate hydrogen at a not insignificant rate, getting the vast majority of the theoretical yield of hydrogen from the seawater/aluminum mixture. Though the process does use indium and gallium, rare and expensive materials, the process is so far able to recover 90% of the indium-gallium used which can then be recycled into the next batch. Aluminum holds twice as much energy as diesel, and 40x that of Li-Ion batteries. So finding a way to harness that energy could have a huge impact on the amount of fossil fuels burned by humans!

Pure, unoxidized aluminum reacts directly with water to create hydrogen, as well as aluminum oxyhydroxide and aluminum hydroxide. However, any aluminum that has had contact with atmospheric air immediately gets a coating of hard, unreactive aluminum oxide, which does not react in the same way. Another issue is that seawater significantly slows the reaction with pure aluminum. The researchers found that the indium-gallium mix was able to not only allow the reaction to proceed by creating an interface for the water and pure aluminum to react but also coating the aluminum pellets to prevent further oxidization. This worked well, but the resulting reaction was very slow.

Apparently “on a lark” they added coffee grounds. Caffeine had already been known to act as a chelating agent for both aluminum and gallium, and the addition of coffee grounds increased the reaction rate by a huge margin, to the point where it matched the reaction rate of pure aluminum in deionized, pure water. Even with wildly varying concentrations of caffeine, the reaction rate stayed high, and the researchers wanted to find out specifically which part of the caffeine molecule was responsible. It turned out to be imidazole, which is a readily available organic compound. The issue was balancing the amount of caffeine or imidazole added versus the gallium-indium recovery rate — too much caffeine or imidazole would drastically reduce the recoverable amount of gallium-indium.

Continue reading “Hydrogen Generation With Seawater, Aluminum, And… Coffee?” →

POP! Goes The Hydrogen Howitzer

February 4, 2024 by 70 Comments

Military models are great 3D printing projects, even more so if they are somewhat functional. [Flasutie] took it a step further by engineering a 3D-printed howitzer that doesn’t just sit pretty—it launches shells with a hydrogen-powered bang.

This project’s secret sauce? Oxyhydrogen, aka HHO, the mix of hydrogen born when water endures the electric breakup of electrolysis. [Flasutie] wanted functional “high explosive” (HE) projectiles to pop without turning playtime into emergency room visit, and 30 mm was the magic size, allowing the thin-walled PLA projectile to rupture without causing injury, even when held in the hand. To set off the gaseous fireworks, [Flasutie] designed an impact fuze featuring piezoelectric spark mechanism nestled within a soft TPU tip for good impact sensitivity.

The howitzer itself is like something out of a miniaturized military fantasy—nearly entirely 3D printed. It boasts an interrupted thread breech-locking mechanism and recoil-absorbing mechanism inspired by the real thing. The breechblock isn’t just for show; it snaps open under spring power and ejects spent cartridges like hot brass.

Watch the video after the break for the build, satisfying loading sequence and of course cardboard-defeating “armor piercing” (AP) and HE shells knocking out targets.

Aqueous Battery Solves Lithium’s Problems

January 4, 2024 by 15 Comments

The demand for grid storage ramps up as more renewable energy sources comes online, but existing technology might not be up to the challenge. Lithium is the most popular option for battery storage right now, not just due to the physical properties of the batteries, but also because we’re manufacturing them at a massive scale already. Unfortunately they do have downsides, especially with performance in cold temperatures and a risk of fires, which has researchers looking for alternatives like aqueous batteries which mitigate these issues.

An aqueous battery uses a water-based electrolyte to move ions from one electrode to the other. Compared to lithium, which uses lithium salts for the electrolyte, this reduces energy density somewhat but improves safety since water is much less flammable. The one downside is that during overcharging or over-current situations, hydrogen gas can be produced by electrolysis of the water, which generally needs to be vented out of the battery. This doesn’t necessarily damage the battery but can cause other issues. To avoid this problem, researchers found that adding a manganese oxide to the battery and using palladium as a catalyst caused any hydrogen generated within the battery’s electrolyte to turn back into water and return to the electrolyte solution without issue.

Of course, these batteries likely won’t completely replace lithium ion batteries especially in things like EVs due to their lower energy density. It’s also not yet clear whether this technology, like others we’ve featured, will scale up enough to be used for large-scale applications either, but any solution that solves some of the problems of lithium, like the environmental cost or safety issues, while adding more storage to an increasingly renewable grid, is always welcome.

Renewable Energy: Beyond Electricity

December 18, 2023 by 72 Comments

Perhaps the most-cited downside of renewable energy is that wind or sunlight might not always be available when the electrical grid demands it. As they say in the industry, it’s not “dispatchable”. A large enough grid can mitigate this somewhat by moving energy long distances or by using various existing storage methods like pumped storage, but for the time being some amount of dispatchable power generation like nuclear, fossil, or hydro power is often needed to backstop the fundamental nature of nature. As prices for wind and solar drop precipitously, though, the economics of finding other grid storage solutions get better. While the current focus is almost exclusively dedicated to batteries, another way of solving these problems may be using renewables to generate hydrogen both as a fuel and as a means of grid storage. Continue reading “Renewable Energy: Beyond Electricity” →

Implant Fights Diabetes By Making Insulin And Oxygen

October 10, 2023 by 13 Comments

Type 1 diabetes remains a problem despite having an apparently simple solution: since T1D patients have lost the cells that produce insulin, it should be possible to transplant those cells into their bodies and restore normal function. Unfortunately, it’s not actually that simple, and it’s all thanks to the immune system, which would attack and destroy transplanted pancreas cells, whether from a donor or grown from the patient’s own stem cells.

That may be changing, though, at least if this implantable insulin-producing bioreactor proves successful.  The device comes from MIT’s Department of Chemical Engineering, and like earlier implants, it relies on encapsulating islet cells, which are the insulin-producing cells within the pancreas, inside a semipermeable membrane. This allows the insulin they produce to diffuse out into the blood, and for glucose, which controls insulin production in islet cells, to diffuse in. The problem with this arrangement is that the resource-intensive islet cells are starved of oxygen inside their capsule, which is obviously a problem for the viability of the implant.

The solution: electrolysis. The O2-Macrodevice, as the implant is called, uses a tiny power-harvesting circuit to generate oxygen for the islet cells directly from the patient’s own interstitial water. The circuit applies a current across a proton-exchange membrane, which breaks water molecules into molecular oxygen for the islet cells. The hydrogen is said to diffuse harmlessly away; it seems like that might cause an acid-base imbalance locally, but there are plenty of metabolic pathways to take care of that sort of thing.

The implant looks promising; it kept the blood glucose levels of diabetic mice under control, while mice who received an implant with the oxygen-generating cell disabled started getting hyperglycemic after two weeks. What’s really intriguing is that the study authors seem to be thinking ahead to commercial production, since they show various methods for mass production of the cell chamber from standard 150-mm silicon wafers using photolithography.

Type 1 diabetics have been down the “artificial pancreas” road before, so a wait-and-see approach is clearly wise here. But it looks like treating diabetes less like a medical problem and more like an engineering problem might just pay dividends.