silica

4 Articles

A Homebrew Gas Chromatograph That Won’t Bust Your Budget

October 13, 2024 by 17 Comments

Chances are good that most of us will go through life without ever having to perform gas chromatography, and if we do have the occasion to do so, it’ll likely be on a professional basis using a somewhat expensive commercial instrument. That doesn’t mean you can’t roll your own gas chromatograph, though, and if you make a few compromises, it’s not even all that expensive.

At its heart, gas chromatography is pretty simple; it’s just selectively retarding the movement of a gas phase using a solid matrix and measuring the physical or chemical properties of the separated components of the gas as they pass through the system. That’s exactly what [Markus Bindhammer] has accomplished here, in about the simplest way possible. Gas chromatographs generally use a carrier gas such as helium to move the sample through the system. However, since that’s expensive stuff, [Markus] decided to use room air as the carrier.

The column itself is just a meter or so of silicone tubing packed with chromatography-grade silica gel, which is probably the most expensive thing on the BOM. It also includes an injection port homebrewed from brass compression fittings and some machined acrylic blocks. Those hold the detectors, an MQ-2 gas sensor module, and a thermal conductivity sensor fashioned from the filament of a grain-of-wheat incandescent lamp. To read the sensors and control the air pump, [Markus] employs an Arduino Uno, which unfortunately doesn’t have great resolution on its analog-to-digital converter. To fix that, he used the ubiquitous HX7111 load cell amplifier to read the output from the thermal conductivity sensor.

After purging the column and warming up the sensors, [Markus] injected a sample of lighter fuel and exported the data to Excel. The MQ-2 clearly shows two fractions coming off the column, which makes sense for the mix of propane and butane in the lighter fuel. You can also see two peaks in the thermal conductivity data from a different fuel containing only butane, corresponding to the two different isomers of the four-carbon alkane.

[Markus] has been on a bit of a tear lately; just last week, we featured his photochromic memristor and, before that, his all-in-one electrochemistry lab.

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A White-Light Laser, On The Cheap

January 4, 2023 by 51 Comments

Lasers are known for the monochromatic nature of their light, so much so that you might never have thought there could be such a thing as a white laser. But in the weird world of physics, a lot of things that seem impossible aren’t really, as demonstrated by this dirt-cheap supercontinuum laser.

Of course, we’re not experts on lasers, and certainly not on non-linear optics, so we’ll rely on [Les Wright]’s video below to explain what’s going on here. Basically, a “supercontinuum” is just the conversion of a monochromatic source to a broader spectral bandwidth. It’s a non-linear optical process that’s usually accomplished with expensive bits of kit, like photonic crystal fibers, which are optical fibers with an array of tiny air-filled holes running down their lengths. Blast a high-intensity monochromatic laser down one end, and white light comes out the other end.

Such fibers are obviously fantastically expensive, so [Les] looked back in the literature and found that a simple silica glass single-mode fiber could be used to produce a supercontinuum. As luck would have it, he had been experimenting with telecom fibers recently, so along with a nitrogen laser he recovered from a Dumpster, he had pretty much everything he needed. The final setup uses the UV laser to pump a stilbene dye laser, which shoots a powerful pulse of 426 nanometer light into about 200 meters of fiber, and produces a gorgeous supercontinuum containing light from 430 nm to 670 nm — pretty much the entire visible spectrum.

It’s great to see projects like this that leverage low-cost, easy-to-source equipment to explore esoteric physics concepts.

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Injection-Molded Glass Breakthrough Shatters Ceiling Of Work Methods

June 10, 2021 by 36 Comments

Glass is one of humanity’s oldest materials, and it is still used widely for everything from drinking vessels and packaging to optics and communications. Unfortunately, the methods for working with glass are stuck in the past. Most methods require a lot of high heat in the range of 1500 °C to 2000 °C, and they’re all limited in the complexity of shapes that can be made.

As far as making shapes goes, glass can be blown and molten glass pressed into molds. Glass can also be ground, etched, or cast in a kiln. Glass would be fantastic for many applications if it weren’t for the whole limited geometry thing. Because of the limitations of forming glass, some optic lenses are made with polymers, even though glass has better optical characteristics.

Ideally, glass could be injection molded like plastic. The benefits of this would be twofold: more intricate shapes would be possible, and they would have a much faster manufacturing time. Well, the wait is over. Researchers at Germany’s University of Freiburg have figured out a way to apply injection molding to glass. And it’s not just any glass — they’ve made highly-quality, transparent fused quartz glass, and they did it at lower temperatures than traditional methods. The team used x-ray diffraction to verify that the glass is amorphous and free of crystals, and were able to confirm its optical transparency three ways — light microscopy, UV-visible, and infrared measurements. All it revealed was a tiny bit of dust, which is to be expected outside of a clean room.

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Store Digital Files For Eons In Silica-Encased DNA

February 21, 2015 by 58 Comments

If there’s one downside to digital storage, it’s the short lifespan.  Despite technology’s best efforts, digital storage beyond 50 years is extremely difficult. [Robert Grass, et al.], researchers from the Swiss Federal Institute of Technology in Zurich, decided to address the issue with DNA.  The same stuff that makes you “You” can also be used to store your entire library, and then some.

As the existence of cancer shows, DNA is not always replicated perfectly. A single mismatch, addition, or omission of a base pair can wreak havoc on an organism. [Grass, et al.] realized that for long-term storage capability, error-correction was necessary. They decided to use Reed-Solomon codes, which have been utilized in error-correction for many storage formats from CDs to QR codes to satellite communication. Starting with uncompressed digital text files of the Swiss Federal Charter from 1291 and the English translation of the Archimedes Palimpsest, they mapped every two bytes to three elements in a Galois field. Each element was then encoded to a specific codon, a triplet of nucleotides. In addition, two levels of redundancy were employed, creating outer- and inner- codes for error recovery. Since long DNA is very difficult to synthesize (and pricier), the final product was 4991 DNA segments of 158 nucleotides each (39 codons plus primers).

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