Why Sodium-Ion Batteries Are Terrible For Solar Storage

October 30, 2025 by Maya Posch 82 Comments

These days just about any battery storage solution connected to PV solar or similar uses LiFePO4 (LFP) batteries. The reason for this is obvious: they have a very practical charge and discharge curve that chargers and inverters love, along with a great round trip efficiency. Meanwhile some are claiming that sodium-ion (Na+) batteries would be even better, but this is not borne out by the evidence, with [Will Prowse] testing and tearing down an Na+ battery to prove the point.

The Hysincere brand battery that [Will] has on the test bench claims a nominal voltage of 12 V and a 100 Ah capacity, which all appears to be in place based on the cells found inside. The lower nominal voltage compared to LFP’s 12.8 V is only part of the picture, as can be seen in the OCV curve. Virtually all of LFP’s useful capacity is found in a very narrow voltage band, with only significant excursions when reaching around >98% or <10% of state of charge.

What this means is that with existing chargers and inverters, there is a whole chunk of the Na+ discharge curve that’s impossible to use, and chargers will refuse to charge Na+ batteries that are technically still healthy due to the low cell voltage. In numbers, this means that [Will] got a capacity of 82 Ah out of this particular 100 Ah battery, despite the battery costing twice that of a comparable LFP one.

Yet even after correcting for that, the internal resistance of these Na+ batteries appears to be significantly higher, giving a round trip efficiency of 60 – 92%, which is a far cry from the 95% to 99% of LFP. Until things change here, [Will] doesn’t see much of a future for Na+ beyond perhaps grid-level storage and as a starter battery for very cold climates.

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The Slow March Of Sodium-Ion Batteries To Compete With Lithium-Ion

November 26, 2023 by Maya Posch 56 Comments

The process of creating new battery chemistries that work better than existing types is a slow and arduous one. Not only does it know more failures than successes, it’s rare that a once successful type gets completely phased out, which is why today we’re using lead-acid, NiMH, alkaline, lithium, zinc-air, lithium-ion and a host of other battery types alongside each other. For one of the up-and-coming types in the form of sodium (Na)-based batteries the same struggles are true as it attempts to hit the right balance between anode, cathode and electrolyte properties. A pragmatic solution here involves Prussian Blue for the cathode and hard carbon for the anode, as is the case with Swedish Northvolt’s newly announced sodium-ion battery (SIB) which is sampling next year.

Commercialization of different SIB battery chemistries by various companies. (Credit: Yadav et al. 2022) — Commercialization of different SIB battery chemistries by various companies. (Credit: Yadav et al., 2022)

The story of SIBs goes back well over a decade, with a recent review article by Poonam Yadav and colleagues in Oxford Open Materials Science providing a good overview of the many types of anodes, cathodes and electrolytes which have been attempted and the results. One of the issues that prevents an SIB from directly using the carbon-based anodes employed with today’s lithium-ion batteries (LIB) is its much larger ionic radius that prevents intercalation without altering the carbon material to accept Na+ ions.

This is essentially where the hard carbon (HC) anode used by a number of SIB-producing companies comes into play, which has a far looser structure that does accept these ions and thus can be used with SIBs. The remaining challenges lie then with the electrolyte – which is where an organic form is the most successful – and the material for the sodium-containing cathode.

Although oxide forms and even sodium vanadium fluorophosphate (NVPF) are also being used, Prussian Blue analogs (PBAs) are attractive for being very low-cost and effective as cathode material once processed. An efficient way to process PB into fully sodiated and reduced Prussian White was demonstrated a few years ago, followed by successive studies backing up this assessment.

Although SIBs are seeing limited commercial use at this point, signs are that if it can be commercialized for the consumer market, it would have similar capacity as current LIBs, albeit with the potential to be cheaper, more durable and easier to recycle.

Prototype Sodium Ion Batteries In 18650 Cells

December 2, 2015 by Al Williams 70 Comments

French researchers have announced a prototype of an 18650 sodium-ion battery. If you’ve bought a powerful LED flashlight, a rechargeable battery pack, or a–ahem–stronger than usual LASER pointer, you’ve probably run into 18650 batteries. You often find these inside laptop batteries and –famously– the Tesla electric vehicle runs on a few thousand of these cells. The number might seem like a strange choice, but it maps to the cell size (18 mm in diameter and 65 mm long).

The batteries usually use lithium-ion technology. However, lithium isn’t the only possible choice for rechargeable cells. Lithium has a lot of advantages. It has a high working voltage, and it is lightweight. It does, however, have one major disadvantage: it is a relatively rare element. It is possible to make sodium-ion batteries, although there are some design tradeoffs. But sodium is much more abundant than lithium, which makes up about 0.06% of the Earth’s crust compared to sodium’s 2.6%). Better still, sea water is full of sodium chloride (which we call salt) that you can use to create sodium.

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