If you’ve been paying any attention to the renewable energy space, you’ll know that generation isn’t really the problem anymore. Solar panels are cheap, and wind turbines are everywhere. The problem is matching generation with demand—sometimes there’s too much wind and sun, and sometimes there’s not enough. Ideally, you could store that energy somewhere, and deploy it when you need it.
The answer everyone keeps reaching for is lithium-ion batteries, and they work just fine. However, there’s a competing technology that’s been quietly scaling up in the background—the vanadium flow battery. It has some unique advantages that could see it rise to prominence in the world of large-scale grid storage.
There’s folk wisdom in just about every culture that teaches about renewable energy — things like “make hay while the sun shines”. But as an industrial culture, we want to make hay 24/7 and not be at the whims of some capricious weather god! Alas, renewable energy puts a crimp in that. Once again, energy supplies are slowly becoming tied to the sun and the wind.
Since “Make compute while the wind blows” doesn’t have a great ring to it, clearly our civilization needs to come up with some grid-scale storage. Over in Sardinia they’re testing an idea that sounds like hot air, but isn’t — because the working gas is CO2.
The principle is simple: when power is available, carbon dioxide is compressed, cooled, and liquefied into pressure vessels as happens at millions of industrial facilities worldwide every day. When power is required, the compressed CO2 can be run through a turbine to generate sweet, sweet electricity. Since venting tonnes of CO2 into the atmosphere is kind of the thing we’re trying to avoid with this whole rigmarole, the greenhouse gas slash working fluid is stored in a giant bag. It sits, waiting for the next charge cycle, like the world’s heaviest and saddest dirigible. In the test project in Sardinia — backed by Google, amongst others — the gas bag holds 2000 tonnes and can produce 20 megawatts of power for up-to 10 hours.
These days just about any battery storage solution connected to PV solar or similar uses LiFePO4 (LFP) batteries. The reason for this is obvious: they have a very practical charge and discharge curve that chargers and inverters love, along with a great round trip efficiency. Meanwhile some are claiming that sodium-ion (Na+) batteries would be even better, but this is not borne out by the evidence, with [Will Prowse] testing and tearing down an Na+ battery to prove the point.
The OCV curve for LFP vs Na+ batteries.
The Hysincere brand battery that [Will] has on the test bench claims a nominal voltage of 12 V and a 100 Ah capacity, which all appears to be in place based on the cells found inside. The lower nominal voltage compared to LFP’s 12.8 V is only part of the picture, as can be seen in the OCV curve. Virtually all of LFP’s useful capacity is found in a very narrow voltage band, with only significant excursions when reaching around >98% or <10% of state of charge.
What this means is that with existing chargers and inverters, there is a whole chunk of the Na+ discharge curve that’s impossible to use, and chargers will refuse to charge Na+ batteries that are technically still healthy due to the low cell voltage. In numbers, this means that [Will] got a capacity of 82 Ah out of this particular 100 Ah battery, despite the battery costing twice that of a comparable LFP one.
Yet even after correcting for that, the internal resistance of these Na+ batteries appears to be significantly higher, giving a round trip efficiency of 60 – 92%, which is a far cry from the 95% to 99% of LFP. Until things change here, [Will] doesn’t see much of a future for Na+ beyond perhaps grid-level storage and as a starter battery for very cold climates.
For the cautious, a good piece of advice is to always wait to buy a new product until after the first model year, whether its cars or consumer electronics or any other major purchase. This gives the manufacturer a year to iron out the kinks and get everything ship shape the second time around. But not everyone is willing to wait on new tech. [Berto] has been interested in lithium capacitors, a fairly new type of super capacitor, and being unwilling to wait on support circuitry schematics to magically show up on the Internet he set about making his own.
The circuit he’s building here is a solar charger for the super capacitor. Being a fairly small device there’s not a lot of current, voltage, or energy, but these are different enough from other types of energy storage devices that it was worth taking a close look and designing something custom. An HT7533 is used for voltage regulation with a Schottky diode preventing return current to the solar cell, and a DW01 circuit is used to make sure that the capacitor doesn’t overcharge.
While the DW01 is made specifically for lithium ion batteries, [Berto] found that it was fairly suitable for this new type of capacitor as well. The capacitor itself is suited for many low-power, embedded applications where a battery might add complexity. Capacitors like this can charge much more rapidly and behave generally more linearly than their chemical cousins, and they aren’t limited to small applications either. For example, this RC plane was converted to run with super capacitors.
Although most people are probably familiar with the different energy levels that the electron shells of atoms can be in and how electrons shedding excess energy as they return to a lower state emit for example photons, the protons and neutrons in atomic nuclei can also occupy an excited state. This nuclear isomer (metastable) state is a big part of radioactive decay chains, but can also be induced externally. The trick lies in hitting the right excitation wavelength and being able to detect the nuclear transition, something which researchers at the Technical University of Wien have now demonstrated for thorium-229.
The findings by [J.Tiedau] and colleagues were published in Physical Review Letters, describing the use of a vacuum-ultraviolet (VUV) laser setup to excite Th-229 into an isomer state. This isotope was chosen for its low-energy isomeric state, with the atoms embedded in a CaF2 crystal lattice. By trying out various laser wavelengths and scanning for the signature of the decay event they eventually detected the signal, which raises the possibility of using this method for applications like new generations of much more precise atomic clocks. It also provides useful insights into nuclear isomers as it pertains to tantalizing applications like high-density energy storage.
Installing solar power at a home is a great way to reduce electricity bills, especially as the cost of solar panels and their associated electronics continue to plummet. Not every utility allows selling solar back to the grid, though, so if you’re like [Rogan] who lives in South Africa you’ll need to come up with some clever tricks to use the solar energy each day while it’s available to keep from wasting any. He’s devised this system for his water heater that takes care of some of this excess incoming energy.
A normal water heater, at least one based on electric resistive heaters, attempts to maintain a small range of temperatures within the insulated tank. If the temperature drops due to use or loss to the environment, the heaters turn on to bring the temperature back up. This automation system does essentially the same thing, but allows a much wider range of temperatures depending on the time of day. Essentially, it allows the water heater to get much hotter during times when solar energy is available, and lets it drop to lower values before running the heater on utility electricity during times when it isn’t. Using a combination ESP32 and ATtiny to both control the heater and report its temperature, all that’s left is to program Home Assistant to get the new system to interact with the solar system’s battery charge state and available incoming solar energy.
While it’s an elegantly simple system that also affords ample hot water for morning showers, large efficiency gains like this can be low-hanging fruit to even more home energy savings than solar alone provides on paper. Effectively the water heater becomes another type of battery in [Rogan]’s home, capable of storing energy at least for the day in the form of hot water. There are a few other ways of storing excess renewable energy as well, although they might require more resources than are typically available at home.
Researchers in Beijing have discovered a way to turn succulents into supercapacitors to help store energy. While previous research has found ways to store energy in plants, it often required implants or other modifications to the plant itself to function. These foreign components might be rejected by the plant or hamper its natural functions leading to its premature death.
This new method takes an aloe leaf, freeze dries it, heats it up, then uses the resulting components as an implant back into the aloe plant. Since it’s all aloe all the time, the plant stays happy (or at least alive) and becomes an electrolytic supercapacitor.
Using the natural electrolytes of the aloe juice, the supercapacitor can then be charged and discharged as needed. The researchers tested the concept by solar charging the capacitor and then using that to run LED lights.
This certainly proposes some interesting applications, although we think your HOA might not be a fan. We also wonder if there might be a way to use the photosynthetic process more directly to charge the plant? Maybe this could recharge a tiny robot that lands on the plants?
