Even if you aren’t a tube aficionado, you can’t help but be mesmerized by the blue glow inside a mercury vapor rectifier when it operates. It looks less like early 20th century tech and more like something that belongs on a Star Trek set. [Uniservo] acquired an 866 rectifier that was interesting due to the markings, which he explains in detail in the video below. Most people though will probably want to skip to closer to its end to see that distinctive blue glow. The exact hue depends on the mercury vapor pressure and usually contains a fair amount of ultraviolet light.
These tubes have an interesting history dating back to 1901, the year [Peter Cooper Hewitt] developed a mercury vapor light which was much more efficient than conventional bulbs. They had two main problems, they required some special process to get the mercury inside to vaporize when you turned them on, but worse still, the light was blue-green which isn’t really appropriate for home and office lighting. In 1902 though, [Hewitt] realized the tube would act as a rectifier. Electrons could readily flow out of the mercury vapor that was the cathode, while the carbon anodes didn’t give up electrons as readily. This was important because up until then, there wasn’t an easy way to convert AC to DC. The usual method was to use an AC motor coupled to a DC generator or a similar mechanical arrangement known as a rotary converter.
In later decades the mercury vapor lamp would wind up with a phosphor coating that converted the ultraviolet light to cool white light and became the fluorescent bulb, so while the rectifier mostly gave way to more efficient methods, [Hewitt’s] bulb has been in use for many years.