Molybdenene whiskers. (Credit: Sahu et al., 2023)

Introducing Molybdenene As Graphene’s New Dirac Matter Companion

November 12, 2023 by Maya Posch 9 Comments

Amidst all the (well-deserved) hype around graphene, it’s important to remember that its properties are not unique to carbon. More atoms can be coaxed into stable 2-dimensional configuration, with molybdenene previously theoretically possible. This is now demonstrated by Tumesh Kumar Sahu and colleagues in a recent Nature Nanotechnology article, through the manufacturing of a 2D molybdenum-based material which they showed to be indeed molybdenene. Essentially, this is a 2D lattice of molybdenum atoms, a configuration in which it qualifies as Dirac matter, just like graphene. For those of us unfamiliar with Dirac materials, this gentle introduction by Jérôme Cayssol in Comptes Rendus Physique might be of use.

Manufacturing process of molybdenene. (Credit: Sahu et al., 2023)

In order to create molybdenene, the researchers started with molybdenum disulfide (MoS₂), which using a microwave-assisted field underwent electrochemical transformation into whiskers that when examined turned out to consist out of monolayers of Mo. The sulfur atoms were separated using a graphene sheet. As is typical, molybdenene sheets were exfoliated using Scotch tape, in a process reminiscent of the early days of graphene research.

Much like graphene and other Dirac materials, molybdenene has many potential uses as a catalyst, as cantilever in scanning electron microscope (SEM) tips, and more. If the past decades of research into graphene has demonstrated anything, it is that what once seemed more of a novelty, suddenly turned out to have endless potential in fields nobody had considered previously. One of these being as coatings for hard disk platters, for example, which has become feasible due to increasingly more efficient ways to produce graphene in large quantities.

$1 Graphene Sensor Identifies Safe Water

August 29, 2023 by Al Williams 15 Comments

If you live in a place where you can buy Arduinos and Raspberry Pis locally, you probably don’t spend much time worrying about your water supply. But in some parts of the world, it is nothing to take for granted, bad water accounts for as many as 500,000 deaths worldwide every year. Scientists have reported a graphene sensor they say costs a buck and can detect dangerous bacteria and heavy metals in drinking water.

The sensor uses a GFET — a graphene-based field effect transistor to detect lead, mercury, and E. coli bacteria. Interestingly, the FETs transfer characteristic changes based on what is is exposed to. We were, frankly, a bit surprised that this is repeatable enough to give you useful data. But apparently, it is especially when you use a neural network to interpret the results.

What’s more, there is the possibility the device could find other contaminants like pesticides. While the materials in the sensor might have cost a dollar, it sounds like you’d need a big equipment budget to reproduce these. There are silicon wafers, spin coating, oxygen plasma, and lithography. Not something you’ll whip up in the garage this weekend.

Still, it is interesting to see a FET used this way and a cheap way to monitor water quality would be welcome. Using machine learning with water sensors isn’t a new idea. Of course, the sensor is one part of the equation. Monitoring is the other.

Easy Graphene Production With A Laser Engraver

May 20, 2023 by Al Williams 13 Comments

Graphene isn’t easy to produce at scale. But making small batches of graphene is doable in a few ways. [Robert Murray-Smith] decided to try producing “flash graphene.” This requires a big capacitor bank that is moderately expensive, so he decided to explain a different technique he read about using an ordinary laser cutter. Check it out in the video below.

We were a little disappointed that he didn’t actually make any graphene this time. He has, however, used other methods in other videos to create some type of graphene. In fact, he has many similar videos going back quite a ways as well as applications with concrete, capacitors, and more. We understand that this method doesn’t produce monolayer graphene, but actually creates a graphene “foam” with interesting properties. [Robert] talks about recent papers that show you can grow graphene on things other than Kapton tape using this method.

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Noninvasive Sensors For Brain–Machine Interfaces Based On Micropatterned Epitaxial Graphene

April 15, 2023 by Maya Posch 4 Comments

As fun as brain-computer interfaces (BCI) are, for the best results they tend to come with the major asterisk of requiring the cutting and lifting of a section of the skull in order to implant a Utah array or similar electrode system. A non-invasive alternative consists out of electrodes which are placed on the skin, yet at a reduced resolution. These electrodes are the subject of a recent experiment by [Shaikh Nayeem Faisal] and colleagues in ACS Applied NanoMaterials employing graphene-coated electrodes in an attempt to optimize their performance.

Impedance values of eight-channel FEG and eight-channel HPEG sensor systems placed on the occipital area of the head. (Faisal et al., 2023)

Although external electrodes can be acceptable for basic tasks, such as registering a response to a specific (visual) impulse or for EEG recordings, they can be impractical in general use. Much of this is due to the disadvantages of the ‘wet’ and ‘dry’ varieties, which as the name suggests involve an electrically conductive gel with the former.

This gel ensures solid contact and a resistance of no more than 5 – 30 kΩ at 50 Hz, whereas dry sensors perform rather poorly at >200 kΩ at 50 Hz with worse signal-to-noise characteristics, even before adding in issues such as using the sensor on a hairy scalp, as tends to be the case for most human subjects.

In this study, they created electrode arrays in a number of configurations, each of which used graphene as the interface material. The goal was to get a signal even through human hair — such as on the back of the head near the visual cortex — that would be on-par with wet electrodes. The researchers got very promising results with hex-patterned epitaxial graphene (HEPG) sensors, and even in this early prototype stage, the technique could offer an alternative where wet electrodes are not an option.

While the subject is complex, brain-computer interfaces don’t have to be the sole domain of research laboratories. We recently covered an open hardware Raspberry Pi add-on that can let you experiment with detecting and filtering biosignals from the comfort of your own home.

Hackaday Podcast 214: Jet Engine Hair Dryer, Comic Sans Type Balls, And Belief In Graphene

April 14, 2023 by Kristina Panos 4 Comments

This week, Editor-in-Chief Elliot Williams and Contributor Emeritus Kristina Panos gushed about all the best hacks of the previous week. But first, a contest! That’s right — hot on the heels of the Low Power Challenge comes the Op Amp Challenge, sponsored by Digi-Key. You have between now and June 6th to dip your toes into the warm waters of analog and show us what you’ve got. Will it be a musical hack? Will you seek high analog precision? We can’t wait to see.

Kristina definitely did not get What’s That Sound this week, which honestly reminded her of a cartoon character getting a piano dropped on them, except the sounds were in reverse order. Then it’s on to the hacks, beginning with a way to make an IBM Selectric typewriter use Comic Sans, a project that’s sure to make you a believer in graphene, and a miniature MNT for every (cargo) pocket.

From there we take a look at a really cool indicator from a 1960s RAF aeroplane and investigate why your multimeter might be lying to you. Finally, we discuss the gargantuan task of building an AR system to rival Google Glass, and the merits of taking a lot of pictures as you go about your hacks.

Check out the links below if you want to follow along, and as always, tell us what you think about this episode in the comments!

Download and savor at your leisure.

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The Challenges Of Producing Graphene In Quantity

April 12, 2023 by Maya Posch 26 Comments

We’ve all heard the incredible claims made about graphene and its many promising applications, but so far the wonder-material has been held back by the difficulty of producing it in large quantities. Although small-scale production was demonstrated many years ago using basic Scotch tape, producing grams or even kilograms of it in a scalable industrial process seemed like a pipedream — until recently. As [Tech Ingredients] demonstrates in a new video, the technique of flash Joule heating of carbon may enable industrial graphene production.

The production of this flash graphene (FG) was first demonstrated by Duy X. Luong and colleagues in a 2020 paper in Nature, which describes a fairly straightforward process. In the [Tech Ingredients] demonstration it becomes obvious how easy graphene manufacturing is using this method, requiring nothing more than carbon black as ingredient, along with a capacitor bank, vacuum chamber and a number of reasonably affordable items.

Perhaps best of all is that no refinement or other complicated processes are required to separate the produced graphene from the left-over carbon black and other non-graphene products. Using multiple of these carbon black-filled tubes in parallel, producing graphene could conceivably be scaled up to industrial levels. This would make producing a few kilograms of graphene significantly easier than coating hard drive platters with the substance.

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Graphene And Copper Nanowire Thermal Interface With Low Thermal Resistance

March 5, 2023 by Maya Posch 8 Comments

With the increasing waste heat production by today’s electronics in ever smaller spaces, drawing this heat away quickly enough to prevent thermal throttling or damage is a major concern. This is where research by Lin Jing and colleagues from Carnegie Mellon University’s Department of Mechanical Engineering demonstrates a thermal interface material (TIM) that should provide a significant boost here. In the article, published in ACS Nano (paywalled; open access preprint alternative) the construction of this copper and graphene ‘sandwich’ TIM is described, along with tests.

The general idea is to use pillars between the two surfaces that can quickly carry the heat from the hot surface to the cool one. Although pure copper versions exist and do work, they suffer from the complications of having to build up these copper pillars in place, and subsequent oxidation reducing the effectiveness. While graphene and similar materials have shown superior heat-transfer capabilities, interfacing these materials with copper and other metals has proven problematic.

What Lin Jing et al. demonstrate in this study is to use essentially the pure copper approach, but to combine it with earlier research by Raghav Garg et al. (2017), who demonstrated how to grow 3-dimensional graphene structures. By cladding the copper pillars with graphene, this material improves heat transfer by 60%, while preventing oxidation of the metal. While the challenge is obviously to transfer these findings to something that can be mass-produced for consumer devices, it demonstrates how much potential there is in the use of graphene, which is a relatively new material for such applications due to how hard it was to produce until recently.