PoX: Super-Fast Graphene-Based Flash Memory

Recently a team at Fudan University claimed to have developed a picosecond-level Flash memory device (called ‘PoX’) that has an access time of a mere 400 picoseconds. This is significantly faster than the millisecond level access times of NAND Flash memory, and more in the ballpark of DRAM, while still being non-volatile. Details on the device technology were published in Nature.

In the paper by [Yutong Xing] et al. they describe the memory device as using a two-dimensional Dirac graphene-channel Flash memory structure, with hot carrier injection for both electron and hole injection, meaning that it is capable of both writing and erasing. Dirac graphene refers to the unusual electron transport properties of typical monolayer graphene sheets.

Demonstrated was a write speed of 400 picoseconds, non-volatile storage and a 5.5 × 106 cycle endurance with a programming voltage of 5 V. It are the unique properties of a Dirac material like graphene that allow these writes to occur significantly faster than in a typical silicon transistor device.

What is still unknown is how well this technology scales, its power usage, durability and manufacturability.

Graphene Tattoos: The Future Of Continuous Health Monitoring?

In the near future, imagine a world where your health is continuously monitored, not through bulky devices but through an invisible graphene tattoo. Developed at the University of Massachusetts Amherst, these tattoos could soon detect a range of health metrics, including blood pressure, stress levels, and even biomarkers of diseases like diabetes. This technology, though still in its infancy, promises to revolutionize how we monitor health, making it possible to track our bodies’ responses to everything from exercise to environmental exposure in real-time.

Graphene, a single layer of carbon atoms, is key to the development of these tattoos. They are flexible, transparent, and conductive, making them ideal for bioelectronics. The tattoos are so thin and pliable that users won’t even feel them on their skin. In early tests, graphene electronic tattoos (GETs) have been used to measure bioimpedance, which correlates with blood pressure and other vital signs. The real breakthrough here, however, is the continuous, non-invasive monitoring that could enable early detection of conditions that usually go unnoticed until it’s too late.

While still requiring refinement, this technology is advancing rapidly. Graphene still amazes us, but it’s no longer just science fiction. Soon, these tattoos could be a part of everyday life, helping individuals track their health and enabling better preventative care. Since we’re hackers out here –  but this is a far fetch – combining this knowledge on graphene production, and this article on tattooing with a 3D printer, could get you on track. Let us know, what would you use graphene biosensors for?

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Who’d Have Guessed? Graphene Is Strange!

Graphene always sounds exciting, although we aren’t sure what we want to do with it. One of the most promising features of the monolayer carbon structure is that under the right conditions, it can superconduct, and some research into how that works could have big impacts on practical superconductor technology.

Past experiments have shown that very cold stacks of graphene (two or three sheets) can superconduct if the sheets are at very particular angles, but no one really understands why. A researcher at Northeaster and another at Harvard realized they were both confused about the possible mechanism. Together, they have started progressing toward a better description of superconductivity in graphene.

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Brain Implant Uses Graphene Instead Of Metal Probes

Implantable electrodes for the (human) brain have been around for a many decades in the form of Utah arrays and kin, but these tend to be made out of metal, which can cause issues when stimulating the surrounding neurons with an induced current. This is due to faradaic processes between the metal probe and an electrolyte (i.e. the cerebrospinal fluid). Over time this can result in insulating deposits forming on the probe’s surface, reducing their effectiveness.

Graphene-based, high-resolution cortical brain interface (Credit: Inbrain Neuroelectronics)
Graphene-based, high-resolution cortical brain interface (Credit: Inbrain Neuroelectronics)

Now a company called InBrain claims to have cracked making electrodes out of graphene, following a series of tests on non-human test subjects. Unlike metal probes, these carbon-based probes should be significantly more biocompatible even when used for brain stimulation as with the target goal of treating the symptoms associated with Alzheimer’s.

During the upcoming first phase human subjects would have these implants installed where they would monitor brain activity in Alzheimer’s patients, to gauge how well their medication is helping with the symptoms like tremors. Later these devices would provide deep-brain stimulation, purportedly more efficiently than similar therapies in use today. The FDA was impressed enough at least to give it the ‘breakthrough device’ designation, though it is hard to wade through the marketing hype to get a clear picture of the technology in question.

In their most recently published paper (preprint) in Nature Nanotechnology, [Calia] and colleagues describe flexible graphene depth neural probes (gDNP) which appear to be what is being talked about. These gDNP are used in the experiment to simultaneously record infraslow (<0.1 Hz) and higher frequencies, a feat which metal microelectrodes are claimed to struggle with.

Although few details are available right now, we welcome any brain microelectrode array improvements, as they are incredibly important for many types of medical therapies and research.

Molybdenene whiskers. (Credit: Sahu et al., 2023)

Introducing Molybdenene As Graphene’s New Dirac Matter Companion

Amidst all the (well-deserved) hype around graphene, it’s important to remember that its properties are not unique to carbon. More atoms can be coaxed into stable 2-dimensional configuration, with molybdenene previously theoretically possible. This is now demonstrated by Tumesh Kumar Sahu and colleagues in a recent Nature Nanotechnology article, through the manufacturing of a 2D molybdenum-based material which they showed to be indeed molybdenene. Essentially, this is a 2D lattice of molybdenum atoms, a configuration in which it qualifies as Dirac matter, just like graphene. For those of us unfamiliar with Dirac materials, this gentle introduction by Jérôme Cayssol in Comptes Rendus Physique might be of use.

Manufacturing process of molybdenene. (Credit: Sahu et al., 2023)
Manufacturing process of molybdenene. (Credit: Sahu et al., 2023)

In order to create molybdenene, the researchers started with molybdenum disulfide (MoS2), which using a microwave-assisted field underwent electrochemical transformation into whiskers that when examined turned out to consist out of monolayers of Mo. The sulfur atoms were separated using a graphene sheet. As is typical, molybdenene sheets were exfoliated using Scotch tape, in a process reminiscent of the early days of graphene research.

Much like graphene and other Dirac materials, molybdenene has many potential uses as a catalyst, as cantilever in scanning electron microscope (SEM) tips, and more. If the past decades of research into graphene has demonstrated anything, it is that what once seemed more of a novelty, suddenly turned out to have endless potential in fields nobody had considered previously. One of these being as coatings for hard disk platters, for example, which has become feasible due to increasingly more efficient ways to produce graphene in large quantities.

$1 Graphene Sensor Identifies Safe Water

If you live in a place where you can buy Arduinos and Raspberry Pis locally, you probably don’t spend much time worrying about your water supply. But in some parts of the world, it is nothing to take for granted, bad water accounts for as many as 500,000 deaths worldwide every year. Scientists have reported a graphene sensor they say costs a buck and can detect dangerous bacteria and heavy metals in drinking water.

The sensor uses a GFET — a graphene-based field effect transistor to detect lead, mercury, and E. coli bacteria. Interestingly, the FETs transfer characteristic changes based on what is is exposed to. We were, frankly, a bit surprised that this is repeatable enough to give you useful data. But apparently, it is especially when you use a neural network to interpret the results.

What’s more, there is the possibility the device could find other contaminants like pesticides. While the materials in the sensor might have cost a dollar, it sounds like you’d need a big equipment budget to reproduce these. There are silicon wafers, spin coating, oxygen plasma, and lithography. Not something you’ll whip up in the garage this weekend.

Still, it is interesting to see a FET used this way and a cheap way to monitor water quality would be welcome. Using machine learning with water sensors isn’t a new idea. Of course, the sensor is one part of the equation. Monitoring is the other.

Easy Graphene Production With A Laser Engraver

Graphene isn’t easy to produce at scale. But making small batches of graphene is doable in a few ways. [Robert Murray-Smith] decided to try producing “flash graphene.” This requires a big capacitor bank that is moderately expensive, so he decided to explain a different technique he read about using an ordinary laser cutter. Check it out in the video below.

We were a little disappointed that he didn’t actually make any graphene this time. He has, however, used other methods in other videos to create some type of graphene. In fact, he has many similar videos going back quite a ways as well as applications with concrete, capacitors, and more. We understand that this method doesn’t produce monolayer graphene, but actually creates a graphene “foam” with interesting properties. [Robert] talks about recent papers that show you can grow graphene on things other than Kapton tape using this method.

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