How To Refrigerate With Urine

January 9, 2024 by Maya Posch 13 Comments

It’s often said that the best science experiments are the ones which do not require any special devices or ingredients, which makes the use of what naturally comes out of one’s body clearly one of the winners. It’s also the beginning of yet another [Hyperspace Pirate] chemistry video that’s both fascinating and unforgettable — this time introducing a considerable collection of urine, and the many uses of the urea in it, including its use for refrigeration.

The respective cooling effect of a variety of compounds in solution. (Credit: Hyperspace Pirate)

As icky as this may sound, it doesn’t even rank in the top ten of quaint things people have historically done with urine, so extracting urea from it is rather benign. This is performed by adding sodium hydroxide to the starting component after heating, which creates gaseous ammonia (NH₃) which was then condensed into its liquid (dissolved) form. In order to create the target compound – being ammonium nitrate – nitric acid (HNO₃) had to be created first.

For this the older, but cheaper and easier Birkeland-Eyde process was used. This uses high-voltage electrical arcs to break down the nitrogen and oxygen in the air and cause the formation of nitric oxide (NO), that subsequently reacts with atmospheric oxygen to form nitrogen dioxide (NO₂). Running the NO₂ through water then creates the desired HNO₃, which can be combined with the ammonia solution to create ammonium nitrate. The resulting solution was then evaporated into solid ammonium nitrate, to use it in an aluminium cooling cylinder, with freshly added water.

This is the simplest way to use the cooling effect of such solutions (pictured), but the benefit of ammonium nitrate over the original urea seems minimal. The low efficiency of this cooling approach means that the next use of urine will involve a much more efficient vapor-absorption cycle, which we’re sure everyone is squeezing their legs together for in anticipation.

We’ve been covering the refrigeration experiments [Hyperspace Pirate] has been conducting for some time now. If you’re into the science of making things cold check out how seashells can be turned into dry ice, or what goes into building a home cryocooler.

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Japan Wants To Decarbonize With The Help Of Ammonia

September 27, 2022 by Lewin Day 59 Comments

With climate change concerns front of mind, the world is desperate to get to net-zero carbon output as soon as possible. While direct electrification is becoming popular for regular passenger cars, it’s not yet practical for more energy-intensive applications like aircraft or intercontinental shipping. Thus, the hunt has been on for cleaner replacements for conventional fossil fuels.

Hydrogen is the most commonly cited, desirable for the fact that it burns very cleanly. Its only main combustion product is water, though its combustion can generate some nitrogen oxides when burned with air. However, hydrogen is yet to catch on en-masse, due largely to issues around transport, storage, and production.

This could all change, however, with the help of one garden-variety chemical: ammonia. Ammonia is now coming to the fore as an alternative solution. It’s often been cited as a potential way to store and transport hydrogen in an alternative chemical form, since its formula consists of one nitrogen atom and three hydrogen atoms.However, more recently, ammonia is being considered as a fuel in its own right.

Let’s take a look at how this common cleaning product could be part of a new energy revolution.

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A Fascinating Plot Twist As Researchers Recreate Classic “Primordial Soup” Experiment

October 31, 2021 by Dan Maloney 46 Comments

Science is built on reproducibility; if someone else can replicate your results, chances are pretty good that you’re looking at the truth. And there’s no statute of limitations on reproducibility; even experiments from 70 years ago are fair game for a fresh look. A great example is this recent reboot of the 1952 Miller-Urey “primordial soup” experiment which ended up with some fascinating results.

At the heart of the Miller-Urey experiment was a classic chicken-and-the-egg paradox: complex organic molecules like amino acids and nucleic acids are the necessary building blocks of life, but how did they arise on Earth before there was life? To answer that, Stanley Miller, who in 1952 was a graduate student of Harold Urey, devised an experiment to see if complex molecules could be formed from simpler substances under conditions assumed to have been present early in the planet’s life. Miller assembled a complicated glass apparatus, filled it with water vapor and gasses such as ammonia, hydrogen, and methane, and zapped it with an electric arc to simulate lightning. He found that a rich broth of amino acids accumulated in the reaction vessel; when analyzed, the sludge was found to contain five of the 20 amino acids.

The Miller-Urey experiment has been repeated over and over again with similar results, but a recent reboot took a different tack and looked at how the laboratory apparatus itself may have influenced the results. Joaquin Criado-Reyes and colleagues found that when run in a Teflon flask, the experiment produced far fewer organic compounds. Interestingly, adding chips of borosilicate glass to the Teflon reaction chamber restored the richness of the resulting broth, suggesting that the silicates in the glassware may have played a catalytic role in creating the organic soup. They also hypothesize that the highly alkaline reaction conditions could create microscopic pits in the walls of the glassware, which would serve as reaction centers to speed up the formation of organics.

This is a great example of a finding that seems to knock a hole in a theory but actually ends up supporting it. On the face of it, one could argue that Miller and Urey were wrong since they only produced organics thanks to contamination from their glassware. And it appears to be true that silicates are necessary for the abiotic generation of organic molecules. But if there was one thing that the early Earth was rich in, it was silicates, in the form of clay, silt, sand, rocks, and dust. So this experiment lends support to the abiotic origin of organic molecules on Earth, and perhaps on other rocky worlds as well.

[Featured image credit: Roger Ressmeyer/CORBIS, via Science History Institute]

Researchers monitor calves as they use the MooLoo, a special pen for urination.

Toilet-Training Cows Is No Bull

September 21, 2021 by Kristina Panos 28 Comments

Human activity may be the main cause of climate change, but all these cows milling and mooing about don’t help, either. Everyone knows that cows produce methane-laden flatulence, but there’s another problem — their urine contains ammonia. The nitrogen leeches into the soil and turns into nitrous oxide, which is no laughing matter. So what’s the answer, giant diapers? No, just train them to use a toilet instead of the soil-let.

A pair of researchers from the University of Auckland traveled to a research institute’s farm in Germany with the hope of training a group of 16 calves to do their business in a special pen. The “MooLoo” is painted bright green and carpeted with artificial turf so it’s less weird for the cows. First they left the calves in the pen until they peed, and then gave it a reward of sugar water. From there, they started extended the animals’ distance from the MooLoo. Whenever the calves thought outside the box, they would be sprayed with water for three seconds. The results are kind of surprising: within an average of 15-20 urination sessions, 11 of the 16 cows had been trained successfully and were using the MooLoo 75% of the time. Watch a calf earn some sugar water after the break.

German cows mostly live in barns, but millions of other cows spend much of their time outside. So, how would that work? The researchers believe that cows could be trained to go when they gather for milking time. Makes sense to us, but how do you train cows on a large scale? Maybe with bovine VR?

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Fueling With Ammonia

March 3, 2021 by Al Williams 68 Comments

There’s a major push now to find energy sources with smaller carbon footprints. The maritime shipping industry, according to IEEE Spectrum, is going towards ammonia. Burning ammonia produces no CO₂ and it isn’t hard to make. It doesn’t require special storage techniques as hydrogen does and it has ten times the energy density of a modern lithium-ion battery.

You can burn ammonia for internal combustion or use it in a fuel cell. However, there are two problems. First, no ships are currently using the fuel and second most ammonia today is made using a very carbon-intensive process. However it is possible to create “green” ammonia, and projects in Finland, Germany, and Norway are on schedule to start using ammonia-powered ships over the next couple of years.

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Mutant Corn Could Be The Future Of Agriculture

October 16, 2020 by Kristina Panos 103 Comments

In America, corn syrup is king, and real sugar hovers somewhere around prince status. We’re addicted to corn, and corn, in turn, is addicted to nitrogen. A long time ago, people figured out that by rotating crops, the soil will stay nutrient-rich, which helps to an extent by retaining nitrogen. Then we figured out how to make nitrogen fertilizer, and through its use we essentially doubled the average crop yield over the last hundred years or so.

The aerial roots of the Sierra Mixe corn stalk help the plant produce its own nitrogen. Image via Wikimedia Commons

Not all plants need extra nitrogen. Legumes like beans and soybeans are able to make their own. But corn definitely needs nitrogen. In the 1980s, the now-chief of agriculture for Mars, Inc. Howard-Yana Shapiro went to Mexico, corn capital of the world, looking for new kinds of corn. He found one in southern Mexico, in the Mixes District of Oaxaca. Not only was this corn taller than American corn by several feet, it somehow grew to these dizzying heights in terrible soil.

Shapiro thought the corn’s success might have something to do with the aerial, finger-like roots protruding from the cornstalk. Decades later, it turns out he was right. Researchers at UC Davis have proven that those aerial roots allow the plant to grab nitrogen out of the air through a symbiotic relationship with bacteria in that clear, syrupy mucus. The process is called nitrogen fixation.

Nitrogen Fixing is a Bit Broken

So if we already have nitrogen fertilizer, why even look for plants that do it themselves? The Haber-Bosch fertilizer-making process, which is an artificial form of nitrogen fixation, does make barren soil less of a factor. But that extra nitrogen in ammonia-based fertilizer tends to run off into nearby streams and lakes, making its use an environmental hazard. And the process of creating ammonia for fertilizer involves fossil fuels, uses a lot of energy, and produces greenhouse gases to boot. All in all, it’s a horrible thing to do to the environment for the sake of agriculture. But with so many people to feed, what else is there to do?

The Haber-Bosch process illustrated. Image via Wikimedia Commons

Over the last decade, the UC Davis researchers use DNA sequencing to determine that the mucus on the Sierra Mixe variety of the plant provides microbes to the corn, which give it both sugars to eat and a layer of protection from oxygen. They believe that the plants get 30-80% of their nitrogen this way. The researchers also proved that the microbes do in fact belong to nitrogen-fixing families and are similar to those found in legumes. Most impressively, they were able to transplant Sierra Mixe corn to both Davis, California and Madison, Wisconsin, and have it grow successfully, proving that the nitrogen-fixing trick isn’t limited to the corn’s home turf. Now they are working to identify the genes that produce the aerial roots.

One Step in a Longer Journey of Progress

We probably won’t be switching over to Sierra Mixe corn anytime soon, however. It takes eight months to mature, which is much too slow for American appetites used to a three-month maturation period. If we can figure out how to make other plants do their own nitrogen fixation, who knows how far we could go? It seems likely that more people would accept a superpower grafted from a corn cousin instead of trying to use CRISPR to grant self-nitrogen fixation, as studies have shown a distrust of genetically modified foods.

The issue of intellectual property rights could be a problem, but the researchers started on the right foot with the Mexican government by putting legal agreements in place that ensure the Sierra Mixe community benefits from research and possible commercialization. We can’t wait to see what they’re able to do. If they’re unable to transplant the power of self-fixation to other plants, then perhaps there’s hope for improving the Haber-Bosch process.

First Light: The Story Of The Laser

January 8, 2018 by Dan Maloney 36 Comments

Lasers are such a fundamental piece of technology today that we hardly notice them. So cheap that they can be given away as toys and so versatile that they make everything from DVD players to corneal surgery a reality, lasers are one of the building blocks of the modern world. Yet lasers were once the exclusive province of physicists, laboring over expansive and expensive experimental setups that seemed more the stuff of science fiction than workhouse tool of communications and so many other fields. The laser has been wildly successful, and the story of its development is an intriguing tale of observation, perseverance, and the importance of keeping good notes.

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