Our metallurgical history is a little bit like a game of Rock, Paper, Scissors, only without the paper; we’re always looking for something hard enough to cut whatever the current hardest metal is. We started with copper, the first metal to be mined and refined. But then we needed something to cut copper, so we ended up with alloys like bronze, which demanded harder metals like iron, and eventually this arms race of cutting led us to steel, the king of metals.
But even a king needs someone to keep him in check, and while steel can be used to make tools hard enough to cut itself, there’s something even better for the job: tungsten, or more specifically tungsten carbide. We produced almost 120,000 tonnes of tungsten in 2022, much of which was directed to the manufacture of tungsten carbide tooling. Tungsten has the highest melting point known, 3,422 °C, and is an extremely dense, hard, and tough metal. Its properties make it an indispensible industrial metal, and it’s next up in our “Mining and Refining” series.
This week, Editor-in-Chief Elliot Williams and Assignments Editor Kristina Panos delighted in the aural qualities of Kristina’s brand new, real (read: XLR) microphone before embarking on creating a podcast highlighting the best of the previous week’s hacks.
This week in the news, NASA returned to the Moon with Artemis I, and this time, there are CubeSats involved. After that, it’s on to the What’s That Sound results show, marred by Kristina’s cheating scandal (listening ahead of time) and Elliot’s reading the filename aloud before we started recording. Finally, we move on to the hacks — they start with a trip to the 90s both sonically and visually, and end with a really nice alarm clock that’s decidedly 70s, and definitely Hackaday.
Check out the links below if you want to follow along, and as always, tell us what you think about this episode in the comments!
The story of humankind is largely a tale of conflict, often brought about by the uneven distribution of resources. For as long as we’ve been down out of the trees, and probably considerably before that too, our ancestors have been struggling to get what they need to survive, as often as not at the expense of another, more fortunate tribe. Food, water, land, it doesn’t matter; if They have it and We don’t, chances are good that there’s going to be a fight.
Few resources are as unevenly distributed across our planet as cobalt is. The metal makes up only a fraction of a percent of the Earth’s crust, and commercially significant concentrations are few and far between, enough so that those who have some often end up at odds with those who need it. And need it we do; what started in antiquity as mainly a rich blue pigment for glass and ceramics has become essential for important industrial alloys, high-power magnets, and the anodes of lithium batteries, among other uses.
Getting access to our limited supply of cobalt and refining it into a useful metal isn’t a trivial process, and unfortunately its outsized importance to technological society forces it into a geopolitical role that has done a lot to add to human misery. Luckily, market forces and new technology are making once-marginal sources viable, which just may help us get the cobalt we need without all the conflict.
I hope last week’s introduction to bulk material handling got you all thinking up amazing hacks, and we’ll soon be reporting on DIY Cap’n Crunch Robots galore. This week we’ll look at how to measure particle sizes, separate particles, and even grind them up when you need to.
Measuring Material Properties
Last week we talked about cohesive strength. Bulk material behaves somewhere between a solid and a liquid — if you’ve done your homework, it flows down the funnel just fine. But if you haven’t, it sticks together and holds up the rest of the material. Cohesive strength is the measure of how much weight the material at the bottom of the funnel can hold up.
You can get a rough measurement by packing material in a box with a square hole at the bottom. One side of the hole should have a retractable slide. Slowly withdraw the slide, making the hole rectangular. Material will bridge over, and then at some point a larger chunk will fall out. This is about the size of the minimum opening that will not arch, and a practical measure of the material’s cohesive strength.
Many materials cohere better when wet. Dry a sample in a microwave to determine the percent moisture by weighing it before and after.
Cohesive strength is closely allied to shear strength. If you want to measure shear strength, cut two 1 cm wide rings of 5 cm diameter PVC pipe, stack them, pack with material, put a disk atop the material and load it, then drag the top ring off the bottom with a spring scale. The force per unit area is the shear strength at that pressure. If it starts packing you’ll see it in the curve.
Packing factor is another useful measurement. Gently shake material to fill a rigid container and weigh it. Now empty the container and refill, packing the material as hard as you can with a length of 1” dowel. Reweigh, and the ratio of the two weights tells you how well the material packs.
Real bulk material is almost always made up of particles of varying sizes, shapes, and compositions. Dirt is particles of different kinds of mineral and organic matter varying from outright rocks to sub micron clay particles. If you’re having problems, getting a graph of material size distribution can be helpful.
For particles above about 75 μM, you can measure the sizes with sieves. If you want to be fancy, they sell nice sets of metal sieves with wire mesh in the bottom. Screen assortments are cheaper. Below 75 μM, you have to use a hydrometer. This is messy and takes a while, but does work.
The idea is to mix the material with soapy water and then use a hydrometer from the auto parts store to measure the density. The particles fall out by Stokes law, big ones first. Stokes law is just that the drag force on a sphere is proportional to the square of the radius. Mass will go up as cube of the radius, so large particles fall faster than small ones. As they fall out, the density of the fluid decreases. This page describes how to do it, and this page has a handy calculator for interpreting the results.
Grinding
You can also change the size of particles in your mix. If particles are too large, they can be crushed or ground. You can separate by size and only grind some of the sizes or discard some of the material. There’s a whole science to grinding. The finer you grind, the harder it gets to grind. Cosmetics and pharmaceutical companies are full of grinding experts.
In general, there are three ways to make something smaller – crush it, cut it, or hit it.
Crushing is straightforward. Use rollers or jaws, a rolling pin or a rock crusher. Don’t overlook the vise. A jaw crusher only crushes particles larger than the jaw space, useful to make a certain size. Rock crushers have a complex motion (video) that should nonetheless be easily imitated by a hacker project. Amateur/hobby gold prospectors have an accessible community.
Crushing action in rollers only works until the particle is small enough that the surface of the roller deforms instead of the particle. Stones have been used to crush grain into flour for most of history.
Cutting is best for soft things, like gummy worms, and tough things (video.). Make sure the cut material has an easy path out. Think of an old fashioned kitchen meat grinder. .
If you want small particles, you need an impact grinder. A coffee mill or blender works by striking the particle with a fast moving impactor. This can be a blade – useful if the material first needs to be cut up, as in a coffee mill – or blunt. Many industrial mills use two pivoting weights on a shaft, and this unit just uses chains (video).
Another impact mill is the ball mill. Rotate a drum on it’s side with steel balls and the material. The balls travel up the side, then fall back down, striking the material.
All these work by fracturing the material. What if you’re trying to powder something that doesn’t fracture, say rubber O rings? For that, there’s cryogenic grinding.
Many rubbery materials are really glasses — materials that are a gloppy liquid at a higher temperature, often brittle at a cool temperature, and soft in-between. The glass you’re probably thinking of is a brittle, breakable material at room temperature, but at high temperature is a liquid. The transition point is the ‘glass transition temperature’.
So what about our O rings? If they’re natural rubber their transition point is about -70° C. Below that temperature they’re brittle and can be ground up. Unfortunately, grinding is going to put heat back in. So consider grinding slowly – some labs grind biological materials like skin samples with a special mortar and pestle cooled beforehand with liquid nitrogen. Just be sure everything in contact with the material has been cooled, and use a thick walled container with lots of thermal mass.
Separating Wheat From Chaff
Sometimes you have a mix and need to separate it. Your roommate dumped all the gummy bears and all those weird ginger candies into a bowl or whatever. Last week we introduced particle segregation as a bad thing. But when you want to un-mix a mixture, it can be a good thing. Any of the techniques from last week can be an aid.
Sieves and screens work to separate by size. They clog unless the material keeps moving over them. One simple way to do this is to flow the material over sieves on a slanted board, finest sieve first. Another is to mechanically shake the screen. Paper filters are just fine screens, and do clog.
A trommel is a slowly turning cylinder with walls of different sized screens along it’s length. Material is fed into the fine screen end and slowly moves towards the other.
Stokes law provides another way to separate materials as we saw above. Make an upward air draft in a vertical pipe. Deliver the material into the pipe part way up. Materials with more drag than weight will go up, larger materials will go down. You can use the air speed to control the size of particle. An industrial machine called an air classifier does this with higher velocity air blowing material into the rim of a spinning set of blades.
It could be the air (or another gas) you want to remove. There are a couple ways to do it. The first is the cyclone familiar to wood shops. The second is even simpler – inject the air/material mix into the top of a tall, slender container with a tube that extends about halfway into the container. Let the air out from an outlet pipe in the roof. The air flow expands, slows down, and the material falls out.
You can just blow the material sideways – the age old system of threshing wheat works this way. Wheat comes from the plant with a husk, you beat it with a flail to loosen the husk, giving you wheat grains and chaff mixed. Put the mix on a blanket and have four peasants toss it repeatedly. The chaff blows away in the wind.
Inertial Separation
A very sensitive separation technique is inertial separation. Here’s a mix of gummy colas and jelly beans. We separated them by tilting and gently shaking the sheet. A material moves on a sheet by staying in place until the acceleration is more than some critical value. Then it rolls or slides.
If your material is dirt or such, run a magnet through it. There’s iron ore and bits of human generated iron in a lot of soil. It can get into motors and such. If you need it out run the material past magnets. An eddy current separator uses AC magnetic effects to do the same with nonferrous metals.
You can also segregate materials by dissolving them. A mixture of table salt and white sand would seem impossible, but if you stir it into water, then decant and boil off the water, the salt and sand can be recovered separately. But we think we’re veering into chemistry now, and we should stop.
Next time we’ll finish up by looking at controlling movement: building gates and contraptions that move your bulk material without clogging up.
Many years ago, I read an article about the new hotness: lithium batteries. The author opened with what he no doubt thought was a clever pop culture reference by saying that the mere mention of lithium would “strike fear in the hearts of Klingons.” It was a weak reference to the fictional “dilithium crystals” of Star Trek fame, and even then I found it a bit cheesy, but I guess he had to lead with something.
Decades later, a deeper understanding of the lore makes it clear that a Klingon’s only fear is death with dishonor, but there is a species here on earth that lives in dread of lithium: CEOs of electric vehicle manufacturing concerns. For them, it’s not the presence of lithium that strikes fear, but the relative absence of it; while it’s the 25th most abundant element in the Earth’s crust, and gigatons are dissolved into the oceans of the world, lithium is very reactive and thus tends to be diffuse, making it difficult to obtain concentrated in the quantities their businesses depend on.
As the electric vehicle and renewable energy markets continue to grow, the need for lithium to manufacture batteries will grow with it, potentially to the point where demand outstrips the mining industry’s production capability. To understand how that imbalance may be possible, we’ll take a look at how lithium is currently mined, as well as examine some new mining techniques that may help fill the coming lithium gap.
It’s hard to reckon exactly when in history humans became a technological species. Part of that is because the definition of technology is somewhat subjective; if you think making a stick pointy enough to grub roots from the dirt or to poke enough holes in an animal to convince it to let you eat it is technology, then our engineered world goes back a long, long way indeed.
But something about pointy sticks just doesn’t seem transformative enough, in the sense of fundamentally changing a naturally occurring material, to really count as a technological line in the sand. To cross that line, it really seems like the use of metals should be part of the package. Even if that’s the case, our technological history still goes pretty far back. And copper ends up being one of the metals that started it all, about 11,000 years ago, when our ancestors discovered natural deposits of the soft, reddish metal and began learning how to fashion it into the tools and implements that lifted us out of the Stone Age.
Our world literally cannot run without copper, forming as it does not only the electric-motor muscles of civilization, but also the wires and cables that form the power and data grids that stitch us together. Ironically, we are just as dependent on copper now as we were when it was the only metal we could make tools from, and perhaps more so. We’ll take a look at what’s involved in extracting and purifying copper, and see how the methods we today use are not entirely different from those developed over seven millennia ago.
A while back, I sat in the newish electric car that was the pride and joy of a friend of mine, and had what was at the time an odd experience. Instead of getting in, turning the key, and driving off, the car instead had to boot up.
The feeling was of a piece of software rather than a piece of hardware, and there was a tangible wait before the start button could be pressed. It was a miracle of technology that could travel smoothly and quietly for all but the longest journeys I could possibly throw at it on relative pennies-worth of electricity, but I hated it. As a technologist and car enthusiast, I should be all over these types of motor vehicles. I live for new technology and I lust after its latest incarnations in many fields including automobiles.
I want my next car to have an electric motor, I want it to push the boundaries of what is capable with a battery and I want it to be an automotive tour de force. The switch to electric cars represents an opportunity like no other to deliver a new type of car that doesn’t carry the baggage of what has gone before, but in that car I saw a future in which they were going badly astray.
I don’t want my next vehicle to be a car like my friend’s one, and to understand why that is the case it’s worth going back a few decades to the cars my parents drove back when when jumpers were goalposts, and the home computer was just a gleam in the eye of a few long-haired outsiders in California.
