Fully Submerge This Modernized PH Sensor

November 29, 2024 by Bryan Cockfield 18 Comments

There’s a school of thought that says you shouldn’t mess around with a solution that’s already working, but that’s never seemed to stop anyone in this community. When [Skye] was looking at the current state of connected pH meters they realized there was incredible room for improvement.

Called the Nectar Monitor, this pH meter is a more modern take on what is currently offered in this space. Open source and based on the ESP32, it’s accessible to most people with a soldering iron, fits into a standard project box, and includes other modern features like USB and WiFi connectivity. It can even measure conductivity and temperature. But the main improvement here is that unlike other monitors that can only be submerged temporarily, this one is designed to be under water for long time periods thanks to a specially designed probe and electrical isolation.

This design makes it an appealing choice for people with aquariums, hydroponic farms, or any other situation where constant monitoring of pH is extremely important to maintaining a balanced system. We’ve seen some unique takes on hydroponics before especially, including this build that moves the plants instead of the nutrient solution and this fully automated indoor garden.

Boss Byproducts: Corium Is Man-Made Lava

November 27, 2024 by Kristina Panos 20 Comments

So now we’ve talked about all kinds of byproducts, including man-made (Fordite), nature-made (fulgurites), and one that’s a little of both (calthemites). Each of these is beautiful in its own way, but I’m not sure about the beauty and merit of corium — that which is created in a nuclear reactor core during a meltdown.

A necklace made to look like corium. Image via OSS-OSS

Corium has the consistency of lava and is made up of many things, including nuclear fuel, the products of fission, control rods, any structural parts of the reactor that were affected, and products of those parts’ reaction with the surrounding air, water, and steam.

If the reactor vessel itself is breached, corium can include molten concrete from the floor underneath. That said, if corium is hot enough, it can melt any concrete it comes in contact with.

So, I had to ask, is there corium jewelry? Not quite. Corium is dangerous and hard to come by. But that doesn’t stop artisans from imitating the substance with other materials.

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Boss Byproducts: Calthemites Are Man-Made Cave Dwellers

November 20, 2024 by Kristina Panos 6 Comments

Some lovely orange calthemite flowstone colored so by iron oxide from rusting steel reinforcing. Image via Wikipedia

At this point, we’ve learned about man-made byproducts and nature-made byproducts. But how about one that’s a little of both? I’m talking about calthemites, which are secondary deposits that form in those man-made caves such as parking garages, mines, and tunnels.

Calthemites grow both on and under these structures in forms that mimic natural cave speleothems like stalactites, stalagmites, flowstone, and so on. They are often the result of an hyperalkalinic solution of pH 9-14 seeping through a concrete structure to the point of coming into contact with the air on the underside. Here, carbon dioxide in the air facilitates the necessary reactions to secondarily deposit calcium carbonate.

These calcium carbonate deposits are usually white, but can be colored red, orange, or yellow thanks to iron oxide. If copper pipes are around, copper oxide can cause calthemites to be blue or green. As pretty as all that sounds, I didn’t find any evidence of these parking garage growths having been turned into jewelry. So there’s your million-dollar idea.

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Homebrew PH Meter Uses Antimony Electrode

November 15, 2024 by Dan Maloney 11 Comments

Understanding the nature of pH has bedeviled beginning (and not-so-beginning) chemistry students for nearly as long as chemistry has had students. It all seems so arbitrary, being the base-10 log of the inverse of hydrogen ion concentration and with a measurement range of 0 to 14. Add to that the electrochemical reactions needed to measure pH electronically, and it’s enough to make your head spin.

Difficulties aside, [Markus Bindhammer] decided to tackle the topic and came up with this interesting digital pH meter as a result. Measuring pH electronically is all about the electrode, or rather a pair of electrodes, one of which is a reference electrode. The potential difference between the electrodes when dipped into the solution under test correlates to the pH of the solution. [Markus] created his electrode by drawing molten antimony into a length of borosilicate glass tubing containing a solid copper wire as a terminal. The reference electrode was made from another piece of glass tubing, also with a copper terminal but filled with a saturated solution of copper(II) sulfate and plugged with a wooden skewer soaked in potassium nitrate.

In theory, this electrode system should result in a linear correlation between the pH of the test solution and the potential difference between the electrodes, easily measured with a multimeter. [Marb]’s results were a little different, though, leading him to use a microcontroller to scale the electrode output and display the pH on an OLED.

The relaxing video below shows the build process and more detail on the electrochemistry involved. It might be worth getting your head around this, since liquid metal batteries based on antimony are becoming a thing.

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Desert Island Acetylene From Seashells And Driftwood

November 15, 2024 by Dan Maloney 35 Comments

[MacGyver] would be proud of [Hyperspace Pirate]’s rough and ready method of producing acetylene gas from seashells and driftwood.

Acetylene, made by decomposing calcium carbide with water, is a vitally important industrial gas. Not only as a precursor in many chemical processes, but also as the fuel for the famous “blue wrench,” a tool without which auto mechanics working in the Rust Belt would be reduced to tears. To avoid this, [Hyperspace Pirate] started by beachcombing for the raw materials: shells to make calcium oxide and wood to make charcoal. Charcoal is pretty easy; you just cook chunks of wood in a reducing environment to drive off everything but the carbon. Making calcium oxide from the calcium carbonate in the shells isn’t much harder, with ground seashells heated in a propane-fired furnace to release carbon dioxide.

With the raw ingredients in hand, things get a little tricky. Making calcium carbide requires a lot of heat, far more than a simple propane burner can provide. [Hyperspace Pirate] decided to go with an electric arc furnace, to which end he cannibalized a 120 V to 240 V step-up converter for its toroidal transformer, which with a few extra windings provided the needed current to run an arc through carbon electrodes. This generated the needed heat, and then some, as the ceramic firebrick he was using to contain the inferno melted. After rewinding the melted secondary windings on his makeshift transformer and switching to a stainless steel crucible, he was able to make enough calcium carbide to generate an impressive amount of acetylene. The video below documents the process and the sooty results, as well as details a little of the excitement that metal acetylides offer.

For more about acetylene and its many uses, [This Old Tony] has you covered.

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A Tiny Chemistry Lab

November 8, 2024 by Bryan Cockfield 12 Comments

While advances in modern technology have allowed average people access to tremendous computing power as well as novel tools like 3D printers and laser cutters for a bare minimum cost, around here we tend to overlook some of the areas that have taken advantage of these trends as well. Specifically in the area of chemistry, the accessibility of these things have opened up a wide range of possibilities for those immersed in this world, and [Marb’s Lab] shows us how to build a glucose-detection lab in an incredibly small form factor.

The key to the build is a set of three laser-cut acrylic sheets, which when sandwiched together provide a path for the fluid to flow as well as a chamber that will be monitored by electronic optical sensors. The fluid is pumped through the circuit by a custom-built syringe pump driven by a linear actuator, and when the chamber is filled the reaction can begin. In this case, if the fluid contains glucose it will turn blue, which is detected by the microcontroller’s sensors. The color value is then displayed on a small screen mounted to the PCB, allowing the experimenter to take quick readings.

Chemistry labs like this aren’t limited to one specific reaction, though. The acrylic plates are straightforward to laser cut, so other forms can be made quickly. [Marb’s Lab] also made the syringe pump a standalone system, so it can be quickly moved or duplicated for use in other experiments as well. If you want to take your chemistry lab to the extreme, you can even build your own mass spectrometer.

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Boss Byproducts: Fulgurites Are Fossilized Lightning

October 29, 2024 by Kristina Panos 28 Comments

So far in this series, we’ve talked about man-made byproducts — Fordite, which is built-up layers of cured car enamel, and Trinitite, which was created during the first nuclear bomb test.

A fulgurite pendant. — A lovely fulgurite pendant. Image via Etsy

But not all byproducts are man-made, and not all of them are basically untouchable. Some are created by Mother Nature, but are nonetheless dangerous. I’m talking about fulgurites, which can form whenever lightning discharges into the Earth.

It’s likely that even if you’ve seen a fulgurite, you likely had no idea what it was. So what are they, exactly? Basically, they are natural tubes of glass that are formed by a fusion of silica sand or rock during a lightning strike.

Much like Lichtenberg figures appear across wood, the resulting shape mimics the path of the lightning bolt as it discharged into the ground. And yes, people make jewelry out of fulgurites.

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