Reinforcing Plastic Polymers With Cellulose And Other Natural Fibers

September 9, 2024 by Maya Posch 10 Comments

While plastics are very useful on their own, they can be much stronger when reinforced and mixed with a range of fibers. Not surprisingly, this includes the thermoplastic polymers which are commonly used with FDM 3D printing, such as polylactic acid (PLA) and polyamide (PA, also known as nylon). Although the most well-known fibers used for this purpose are probably glass fiber (GF) and carbon fiber (CF), these come with a range of issues, including their high abrasiveness when printing and potential carcinogenic properties in the case of carbon fiber.

So what other reinforcing fiber options are there? As it turns out, cellulose is one of these, along with basalt. The former has received a lot of attention currently, as the addition of cellulose and similar elements to thermopolymers such as PLA can create so-called biocomposites that create plastics without the brittleness of PLA, while also being made fully out of plant-based materials.

Regardless of the chosen composite, the goal is to enhance the properties of the base polymer matrix with the reinforcement material. Is cellulose the best material here?

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3D Printing Real Wood With Just Cellulose And Lignin

March 27, 2024 by Maya Posch 23 Comments

Although the components of wood – cellulose and lignin – are exceedingly cheap and plentiful, combining these into a wood-like structure is not straightforward, despite many attempts to make these components somehow self-assemble. A recent attempt by [MD Shajedul Hoque Thakur] and colleagues as published in Science Advances now may have come closest to 3D printing literal wood using cellulose and lignin ink, using direct ink writing (DIW) as additive manufacturing method.

Microstructures of 3D-printed wood after printing and post-printing operations. (Credit: Thakur et al., 2024) — Microstructures of 3D printed wood after printing and post-printing operations. (Credit: Thakur et al., 2024)

This water-based ink was created by mixing TOCN (tempo-oxidized cellulose nanofiber), a 10.6 wt % aqueous CNC (cellulose nanocrystals) and lignin in a 15:142:10 ratio, giving it roughly the viscosity of clay. The purpose of having both TOCNs and CNCs is to replicate the crystalline and amorphous cellulose elements of wood-based cellulose.

This ink was printed from a syringe head (SDS-60) installed in a Hyrel 3D Engine HR 3D printer. This printer is much like your average FDM printer, just targeting bioprinting and a wide range of heads to print and handle various attachments in a laboratory setting. The ink was extruded into specific shapes that were either freeze dried to get rid of the liquid component, or additionally also heated (at 180°C), with a third set of samples put into a hot press. These additional steps seem to promote the binding of the lignin and create a more durable result.

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Transistors That Grow On Trees

April 28, 2023 by Bryan Cockfield 16 Comments

Modern technology is riddled with innovations that were initially inspired by the natural world. Velcro, bullet trains, airplanes, solar panels, and many other technologies took inspiration from nature to become what they are today. While some of these examples might seem like obvious places to look, scientists are peering into more unconventional locations for this transistor design which is both inspired by and made out of wood.

The first obvious hurdle to overcome with any electronics made out of wood is that wood isn’t particularly conductive, but then again a block of silicon needs some work before it reliably conducts electricity too. First, the lignin is removed from the wood by dissolving it in acetate, leaving behind mostly the cellulose structure. Then a conductive polymer is added to create a lattice structure of sorts using the wood cellulose as the structure. Within this structure, transistors can be constructed that function mostly the same as a conventional transistor might.

It might seem counterintuitive to use wood to build electronics like transistors, but this method might offer a number of advantages including sustainability, lower cost, recyclability, and physical flexibility. Wood can be worked in a number of ways once the lignin is removed, most notably when making paper, but removing the lignin can also make the wood relatively transparent as well which has a number of other potential uses.

Thanks to [Adrian] for the tip!

Coffee Makes 3D Printing Better

October 14, 2019 by Al Williams 29 Comments

While we know some 3D printer operators who need coffee, Washington State University is showing an improved PLA material that incorporates used coffee waste. Regular PLA is not known for being especially strong, though It isn’t uncommon for vendors to add things to their PLA to change its characteristics.

The new material containing about 20% coffee waste showed an over 400% increase in toughness (25.24 MJ/m³) versus standard PLA. Why coffee waste? We aren’t sure. They didn’t add grounds, but rather a dry and odorless material left over after coffee grounds are processed for biodiesel production.

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3D-Printer Extrudes Paper Pulp Instead Of Plastic

November 11, 2018 by Dan Maloney 33 Comments

We’ve seen all sorts of 3D-printers on these pages before. From the small to the large, Cartesians and deltas, and printers that can squeeze out plastic, metal, and even concrete. But this appears to be the first time we’ve ever featured a paper-pulp extruding 3D-printer.

It’s fair to ask why the world would need such a thing, and its creator, [Beer Holthuis], has an obvious answer: the world has a lot of waste paper. Like 80 kg per person per year. Thankfully at least some of that is recycled, but that still leaves a lot of raw material that [Beer] wanted to put to work. Build details on the printer are sparse, but from the photos and the video below it seems clear how it all went together. A simple X-Y-Z gantry moves a nozzle over the build platform. The nozzle, an order of magnitude or two larger than the nozzles most of us are used to, is connected to an extruder by a plastic hose. The extruder appears to be tube with a stepper-driven screw that lowers a ram down onto the pulp, squeezing it into the hose. [Beer] notes that the pulp is mixed with a bit of “natural binder” to allow the extruded pulp to keep its shape. We found the extrusion process to be just a wee bit repulsive to watch, but fascinating nonetheless, and the items he’s creating are certainly striking in appearance.

This may be the first pulp printer to grace our pages, but it’s not the first pulp hack we’ve featured. Pulp turns out to be a great material to keep your neighbors happy and even makes a dandy fuel.

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Need Strength? It’s Modified Wood You Want!

February 12, 2018 by Jenny List 29 Comments

Wood is surely one of the most versatile materials available. It can be found in a huge variety of colours and physical properties depending on the variety of the tree that grew it, and it has been fashioned into all conceivable devices, products, and structures over millenia. It’s not without shortcomings though, and one of the most obvious is that it can’t match the strength of some other materials. To carry large forces with a piece of wood that piece has to be made much larger than a corresponding piece of steel, something which is not a problem in a roof truss, but significantly difficult in a car body.

There have been a variety of attempts to strengthen the structure of wood in the past, and the latest has recently been published as a Nature paper. In it is described a process of first treating natural wood in a chemical bath to remove lignin and leave only the cellulose structure, followed by sustained compression at high temperature. This causes the cellulose fibres to interlock, and leaves a much denser wooden board with an equivalent strength that is described as near that of steel. They’ve posted a video which we’ve placed below the break, showing some ballistic tests on their material.

All new materials are of interest, but assuming that this one can be commercialised it makes for a particularly exciting set of possibilities. Wooden motor vehicles for example, new techniques for wooden aircraft or boats, or as an alternative in some applications where carbon fibre might currently find an application.

We’ve looked at a very similar process in the past for producing transparent wood. The good news for Hackaday readers that takes this from esoteric scientific paper to fascinating possibility though is that it can be done at home. Can any of you replicate the pressing step to take it to the next level?

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Take Your 3D Printing To The Next Dimension

February 10, 2016 by Bryan Cockfield 20 Comments

In what is being hailed as the next great advancement in 3D printing, scientists have been able to get a 3D printed shape to change form when it is exposed to water, bringing 3D printing squarely into the realm of the fourth dimension. Although the only examples we’ve seen so far are with relatively flat prints (which arguably subtracts one “D” from the claim) the new procedure is one which is groundbreaking for the technology.

The process uses cellulose fibers which, when aligned in a particular way and exposed to water, swell in order to change shape. This is similar to how a bimetallic strip in a thermostat works, but they really took their inspiration from biological processes in plants that allow them to change shape according to environmental conditions. It’s hard to tell if this new method of printing will forever alter the landscape of 3D printing but, for now, it’s an interesting endeavor that will be worth watching. The video after the break shows a fast-motion print using the technique, followed by a demo of the print submersed in water.

We often see new technological advancements that use biology as a springboard for new ideas, and this one is no different. There have been building structures inspired by pinecones and this Processing hack inspired by squid. Biology is all around us, and any of it could be used for inspiration for your next project!

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