pierced puffed exposed leads lithium ion battery

Lessons In Li-Ion Safety

If you came here from an internet search because your battery just blew up and you don’t know how to put out the fire, then use a regular fire extinguisher if it’s plugged in to an outlet, or a fire extinguisher or water if it is not plugged in. Get out if there is a lot of smoke. For everyone else, keep reading.

I recently developed a product that used three 18650 cells. This battery pack had its own overvoltage, undervoltage, and overcurrent protection circuitry. On top of that my design incorporated a PTC fuse, and on top of that I had a current sensing circuit monitored by the microcontroller that controlled the board. When it comes to Li-Ion batteries, you don’t want to mess around. They pack a lot of energy, and if something goes wrong, they can experience thermal runaway, which is another word for blowing up and spreading fire and toxic gasses all over. So how do you take care of them, and what do you do when things go poorly?

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Better Battery Management Through Chemistry

The lead-acid rechargeable battery is a not-quite-modern marvel. Super reliable and easy to use, charging it is just a matter of applying a fixed voltage to it and waiting a while; eventually the battery is charged and stays topped off, and that’s it. Their ease is countered by their size, weight, energy density, and toxic materials.

The lithium battery is the new hotness, but their high energy density means a pretty small package that can get very angry and dangerous when mishandled. Academics have been searching for safer batteries, better charge management systems, and longer lasting battery formulations that can be recharged thousands of times, and a recent publication is generating a lot of excitement about it.

Consider the requirements for a battery cell in an electric car:

  • High energy density (Lots of power stored in a small size)
  • Quick charge ability
  • High discharge ability
  • MANY recharge cycles
  • Low self-discharge
  • Safe

Lithium ion batteries are the best option we have right now, but there are a variety of Li-ion chemistries, and depending on the expected use and balancing and charging, different chemistries can be optimized for different performance characteristics. There’s no perfect battery yet, and conflicting requirements mean that the battery market will likely always have some options.

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Rescuing A Proprietary Battery Pack With A Cell From A Camera

If you have an older handheld battery-powered device, you may be fighting a diminishing battery capacity as its lithium-ion cells reach the end of their life. And if you are like [Foxx D’Gamma], whose device is an Alinco DJ-C7 handheld transceiver, you face the complete lack of availability of replacement battery packs. All is not lost though, because as he explains in the video below the break, he noticed that a digital camera battery uses a very similar-sized cell, and was able to graft the camera battery into the shell of the Alinco pack.

Cracking open the Alinco pack, he was rewarded with the rectangular Li-Ion cell and two PCBs, one for the connector and another for the battery management circuitry. By comparison the camera battery had a much smaller battery management PCB, and it fit neatly into the space vacated by the Alinco cell once those covers had been removed. A fiddly soldering job to attach the connector PCB, and he was rewarded with a working Alinco pack and an unexpected bonus when he found out that the transceiver was a dual band model.

Along the way he’s at pains to point out the safety aspects of handling Li-Ion cells, and to ensure that the polarity of the cell is correct. It’s also worth our reminding readers that these packs must always be accompanied by their battery management circuitry. The result though is pleasing: a redundant piece of equipment made obsolete by a proprietary battery, given a new lease on life.

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Solid State Battery From The Man Who Brought Us Lithium Ion

Who is [John Goodenough]? He’s 94, so he’s been around long enough that you ought to know him. He was one of the co-inventors of the lithium-ion battery. Think about how much that battery has changed electronics. [Goodenough] along with [Maria Helena Braga] may have come up with that battery’s successor: the solid state battery. There’s a paper available that is free, but requires registration. If you don’t want to register, you can read the news release from the University of Texas with no trouble.

Keywords used to describe the new battery are low-cost, noncombustible, long cycle life, high energy density, and fast charge and discharge rates. The pair is also claiming three times the energy density of a current lithium-ion battery. They also claim that the batteries recharge in minutes instead of hours. You can see a video from [Transport Evolved] that discusses the invention, below.

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Reverse Engineering A Nissan Leaf Battery Pack

Batteries wear out. If you are an electric vehicle enthusiast, it’s a certainty that at some time in your not-too-distant future there will be a point at which your vehicle’s batteries have reached the end of their lives and will need to be replaced. If you have bought a new electric vehicle the chances are that you will be signed up to a leasing deal with the manufacturer which will take care of this replacement, but if you have an older vehicle this is likely to be an expensive moment.

Fortunately there is a tempting solution. As an increasing number of electric vehicles from large manufacturers appear on our roads, a corresponding number of them have become available on the scrap market from accident damage. It is thus not impossible to secure a fairly new lithium-ion battery pack from a modern electric car, and for a significantly lower price than you would pay for new cells. As always though, there is a snag. Such packs are designed only for the cars they came with, and have proprietary connectors and protocols with which they communicate with their host vehicle. Fitting them to another car is thus not a task for the faint hearted.

Hackaday reader [Wolf] has an electric truck, a Solectria E10. It has a set of elderly lead-acid batteries and would benefit hugely from an upgrade to lithium-ion. He secured a battery pack from a 2013 Nissan Leaf electric car, and he set about reverse engineering its battery management system (BMS). The Solectria will use a different battery configuration from the Leaf, so while he would like to use the Leaf’s BMS, he has had to reverse engineer its protocols so that he can replace its Nissan microcontroller with one of his own.

His description of the reverse engineering process is lengthy and detailed, and with its many photos and videos is well worth a read. He employs some clever techniques, such as making his own hardware simulation of a Li-ion cell so that he can supply the BMS known values that he can then sniff from the serial data stream.

We’ve covered quite a few EV batteries here at Hackaday. Quite recently we even covered another truck conversion using Leaf batteries, and last year we featured a Leaf battery teardown. We’ve not restricted ourselves to Nissan though, for example here’s a similar process with a Tesla Model S pack.

Faucet Add-On Attempts To Save Water By Changing Colors

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This augmented water device was rapidly developed during an H2O hackathon in Lausanne, Switzerland. It was built by a software engineer code-named [tamberg]. His creation contained an Arduino Uno, a strip of NeoPixels, a liquid flow sensor, and a tiny lithium-ion battery attached to a cut medical tube that was re-purposed for monitoring water use.

From the looks of it, this project addressed a specific problem and went on to solve it. The initial prototype showed a quick and dirty way to monitor precious water that is literally being flushed down the drain.

To see how the device was made, click the first link posted above for a set of Instructables. Code for the device can be found on [tamberg]’s bitbucket account. A demo video of the device being tested on a sink can be seen after the break.

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3D Printing Lithium Ion Cells

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[Jennifer Lewis] is a Harvard Materials Scientist, and she’s recently come up with a type of Lithium Ion “Ink” that allows her to 3D print battery cells.

You might remember our recent 3D Printering article on Pastestruders, but this research certainly takes it up a few notches. The ink is made up of nano-particles of Lithium Titanium in a solution of de-ionized water and ethylene glycol. When producing the ink, small ceramic balls are added to the mixture to help break up microscopic clumps of said particles. The mixture is then spun for 24 hours, after which the larger particles and ceramic balls are removed using a series of filters. The resulting ink is a solid when unperturbed, but flows under extreme pressures!

This means a conventional 3D printer can be used, with only the addition of a high pressure dispenser unit. We guess we can’t call it a hot-end any more…  The ink is forced out of a syringe tip as small as 1 micrometer across, allowing for extremely precise patterning. In her applications she uses a set up with many nozzles, allowing for the mass printing of the anodes and cathodes in a huge array. While still in the research phase, her micro-scale battery architectures can be as small as a square millimeter, but apparently compete with industry batteries that are much larger.

And here’s the exciting part:

Although she says the initial plan is to provide tools for manufacturers, she may eventually produce a low-end printer for hobbyists.

3D Printable electronics. The future is coming!

[Thanks Keith!]