Rare-Earth-Free Magnets With High Entropy Borides

Map of the calculated magnetic anisotropy. (Credit: Beeson et al., Adv. Mat., 2025)
Map of the calculated magnetic anisotropy. (Credit: Beeson et al., Adv. Mat., 2025)

Although most of us simultaneously accept the premise that magnets are quite literally everywhere and that few people know how they work, a major problem with magnets today is that they tend to rely on so-called rare-earth elements.

Although firmly in the top 5 of misnomers, these abundant elements are hard to mine and isolate, which means that finding alternatives to their use is much desired. Fortunately the field of high entropy alloys (HEAs) offers hope here, with [Beeson] and colleagues recently demonstrating a rare-earth-free material that could be used for magnets.

Although many materials can be magnetic, to make a good magnet you need the material in question to be both magnetically anisotropic and posses a clear easy axis. This basically means a material that has strong preferential magnetic directions, with the easy axis being the orientation which is the most energetically favorable.

Through experimental validation with magnetic coercion it was determined that of the tested boride films, the (FeCoNiMn)2B variant with a specific deposition order showed the strongest anisotropy. What is interesting in this study is how much the way that the elements are added and in which way determines the final properties of the boride, which is one of the reasons why HEAs are such a hot topic of research currently.

Of course, this is just an early proof-of-concept, but it shows the promise of HEAs when it comes to replacing other types of anisotropic materials, in particular where – as noted in the paper – normally rare-earths are added to gain the properties that these researchers achieved without these elements being required.

Illustrative models of collinear ferromagnetism, antiferromagnetism, and altermagnetism in crystal-structure real space and nonrelativistic electronic-structure momentum space. (Credit: Libor Šmejkal et al., Phys. Rev. X, 2022)

Nanoscale Imaging And Control Of Altermagnetism In MnTe

Altermagnetism is effectively a hybrid form of ferromagnetism and antiferromagnetism that might become very useful in magnetic storage as well as spintronics in general. In order to practically use it, we first need to be able to control the creation of these altermagnets, which is what researchers have now taken the first steps towards. The research paper by [O. J. Amin] et al. was published earlier this month in Nature. It builds upon the team’s earlier research, including the detection of altermagnetism in manganese telluride (MnTe). This new study uses the same material but uses a photoemission electron microscope (PEEM) with X-rays to image these nanoscale altermagnetic structures.

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Illustrative models of collinear ferromagnetism, antiferromagnetism, and altermagnetism in crystal-structure real space and nonrelativistic electronic-structure momentum space. (Credit: Libor Šmejkal et al., Phys. Rev. X, 2022)

Altermagnetism In Manganese Telluride And Others: The Future Of Spintronics?

Magnetic materials are typically divided into ferromagnetic and antiferromagnetic types, depending on their magnetic moments (electron spins), resulting in either macroscopic (net) magnetism or not. Altermagnetism is however a recently experimentally confirmed third type that as the name suggests alternates effectively between these two states, demonstrating a splitting of the spin energy levels (spin-split band structure). Like antiferromagnets, altermagnets possess a net zero magnetic state due to alternating electron spin, but they differ in that the electronic band structure are not Kramers degenerate, which is the feature that can be tested to confirm altermagnetism. This is the crux of the February 2024 research paper in Nature by [J. Krempaský] and colleagues.

Specifically they were looking for the antiferromagnetic-like vanishing magnetization and ferromagnetic-like strong lifted Kramers spin degeneracy (LKSD) in manganese telluride (MnTe) samples, using photoemission spectroscopy in the UV and soft X-ray spectra. A similar confirmation in RuO2 samples was published in Science Advances by [Olena Fedchenko] and colleagues.

What this discovery and confirmation of altermagnetism means has been covered previously in a range of papers ever since altermagnetism was first proposed in 2019 by [Tomas Jungwirth] et al.. A 2022 paper published in Physical Review X by [Libor Šmejkal] and colleagues details a range of potential applications (section IV), which includes spintronics. Specific applications here include things like memory storage (e.g. GMR), where both ferromagnetic and antiferromagnetics have limitations that altermagnetism could overcome.

Naturally, as a fairly new discovery there is a lot of fundamental research and development left to be done, but there is a good chance that within the near future we will see altermagnetism begin to make a difference in daily life, simply due to how much of a fundamental shift this entails within our fundamental understanding of magnetics.

Heading image: Illustrative models of collinear ferromagnetism, antiferromagnetism, and altermagnetism in crystal-structure real space and nonrelativistic electronic-structure momentum space. (Credit: Libor Šmejkal et al., Phys. Rev. X, 2022)

Tool Demagnetizers And The Magnetic Stray Field

If you’ve ever found yourself wondering how those tool magnetizer/demagnetizer gadgets worked, [Electromagnetic Videos] has produced a pretty succinct and informative video on the subject.

The magnetizer/demagnetizer gadget after meeting its demise at a cutting disc. (Credit: Electromagnetic Videos, YouTube)
The magnetizer/demagnetizer gadget after meeting its demise at a cutting disc. (Credit: Electromagnetic Videos, YouTube)

While the magnetizing step is quite straightforward and can be demonstrated even by just putting any old magnet against the screwdriver’s metal, it is the demagnetization step that doesn’t make intuitively sense, as the field lines of the magnets are supposed to align the (usually ferromagnetic) material’s magnetic dipole moments and thus create an ordered magnetic field within the screwdriver.

This is only part of the story, however, as the magnetic field outside of a magnet is termed the demagnetizing field (also ‘stray field’). A property of this field is that it acts upon the magnetization of e.g. ferromagnetic material in a way that reduces its magnetic moment, effectively ‘scrambling’ any existing magnetization.

By repeatedly moving a metal tool through this stray field, each time further and further away from the magnet, the magnetic moment reduces until any magnetization has effectively vanished. It is the kind of simple demonstration of magnetism that really should be part of any physics class thanks to its myriad of real-world uses, as this one toolbox gadget shows.

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Electrical Steel: The Material At The Heart Of The Grid

When thoughts turn to the modernization and decarbonization of our transportation infrastructure, one imagines it to be dominated by exotic materials. EV motors and wind turbine generators need magnets made with rare earth metals (which turn out to be not all that rare), batteries for cars and grid storage need lithium and cobalt, and of course an abundance of extremely pure silicon is needed to provide the computational power that makes everything work. Throw in healthy pinches of graphene, carbon fiber composites and ceramics, and minerals like molybdenum, and the recipe starts looking pretty exotic.

As necessary as they are, all these exotic materials are worthless without a foundation of more familiar materials, ones that humans have been extracting and exploiting for eons. Mine all the neodymium you want, but without materials like copper for motor and generator windings, your EV is going nowhere and wind turbines are just big lawn ornaments. But just as important is iron, specifically as the alloy steel, which not only forms the structural elements of nearly everything mechanical but also appears in the stators and rotors of motors and generators, as well as the cores of the giant transformers that the electrical grid is built from.

Not just any steel will do for electrical use, though; special formulations, collectively known as electrical steel, are needed to build these electromagnetic devices. Electrical steel is simple in concept but complex in detail, and has become absolutely vital to the functioning of modern society. So it pays to take a look at what electrical steel is and how it works, and why we’re going nowhere without it.

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Moving Iron-Coated Polymer Particles Uphill Using External Magnetic Field

Microscopy of PMMA ferromagnetic Janus particle as used in the study (Credit: Wilson-Whitford et al., 2023)
Microscopy of PMMA ferromagnetic Janus particle as used in the study (Credit: Wilson-Whitford et al., 2023)

Granular media such as sand have a range of interesting properties that make it extremely useful, but they still will obey gravity and make their way downhill. That is, until you coat such particles with a ferromagnetic material like iron, make them spin using an external magnetic field and watch them make their way against gravity. This recent study by researchers has an accompanying video (also embedded below) that is probably best watched first before reading the study by Samuel R. Wilson-Whitford and colleagues in Nature Communications.

In the supplemental material the experimental setup is shown (see top image), which is designed to make the individual iron-coated polymer particles rotate. The particles are called Janus particles because only one hemisphere is coated using physical vapor deposition, leaving the other as uncovered PMMA (polymethyl methacrylate).

While one might expect that the rotating magnetic field would just make these particles spin in place, instead the researchers observed them forming temporary chains of particles, which were able to gradually churn their way upwards. Not only did this motion look like the inverse of granular media flowing downhill, the researchers also made a staircase obstacle that the Janus particles managed to traverse. Although no immediate practical application is apparent, these so-called ‘microrollers’ display an interesting method of locomotion in what’d otherwise be rather passive granular media.

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Close-up of a magnetic tentacle robot next to a phantom bronchiole (Credit: University of Leeds)

The Healing Touch Of Magnetic Tentacles In Photothermal Lung Cancer Therapy

Of the body’s organs, the lungs are among the trickiest to take a biopsy and treat cancer in, both due to how important they are, as well as due to their inaccessibility. The total respiratory surface within the average human lungs is about 50 to 75 square meters. Maneuvering any kind of instrument down the endless passages to reach a suspicious area, or a cancerous region to treat is nearly impossible. This has so far left much of the lungs inaccessible.

The standard of care for lung cancer is generally surgical: remove parts of the lung tissue. However, a proposed new method using magnetic tentacles may soon provide a more gentle approach, as described in Nature Engineering Communications by Giovanni Pittiglio and colleagues (press release).

The tentacles are made out of a silicone substrate with embedded magnets that allow for it to be steered using external magnetic sources. With an embedded laser fiber, the head of the tentacle can be guided to the target area, and the cancerous tissue sublimated using an external laser source. In experiments on cadavers with this system, the researchers found that they could enter 37% deeper into the lungs than with standard equipment. The procedure was also completed with less tissue displacement.

Considering the high fatality rate of lung cancers, the researchers hope that this approach could soon be turned into a viable therapy, as well as for other medical conditions where a gentle tentacle slithering into the patient’s body could effect treatments previously considered to be impossible.

Heading image: Close-up of a magnetic tentacle robot next to a phantom bronchiole (Credit: University of Leeds)