The Possibility Of Reverting Time On The Ageing Of Materials

September 23, 2024 by Maya Posch 7 Comments

Everyone knows that time’s arrow only goes in one direction, regardless of the system or material involved. In the case of material time, i.e. the ageing of materials such as amorphous materials resulting from glass transition, this material time is determined after the initial solidification by the relaxation of localized stresses and medium-scale reordering. These changes are induced by the out-of-equilibrium state of the amorphous material, and result in changes to the material’s properties, such as a change from ductile to a brittle state in metallic glasses. It is this material time which the authors of a recent paper (preprint) in Nature Physics postulates to be reversible.

Whether or not this is possible is said to be dependent on the stationarity of the stochastic processes involved in the physical ageing. Determining this stationarity through the investigation of the material time in a number of metallic glass materials (1-phenyl-1-propanol, laponite and polymerizing epoxy) was the goal of this investigation by [Till Böhmer] and colleagues, and found that at least in these three materials to be the case, suggesting that this process is in fact reversible.

Naturally, the primary use of this research is to validate theories regarding the ageing of materials, other aspects of which have been investigated over the years, such as the atomic dynamics by [V.M Giordano] and colleagues in a 2016 paper in Nature Communications, and a 2022 study by [Birte Riechers] and colleagues in Science Advances on predicting the nonlinear physical ageing process of glasses.

While none of these studies will give us time-travel powers, it does give us a better understanding of how materials age over time, including biological systems like our bodies. This would definitely seem to be a cause worthy of our time.

Header image: Rosino on Flickr, CC BY-SA 2.0.

Liquid (Reversibly) Solidifies At Room Temperature, Gets Used For 3D Prints

August 9, 2024 by Donald Papp 8 Comments

Researchers demonstrate sustainable 3D printing by using poly(N-isopropylacrylamide) solutions (PNIPAM), which speedily and reliably turn solid by undergoing a rapid phase change when in a salt solution.

This property has been used to 3D print objects by using a syringe tip as if it were a nozzle in a filament-based printer. As long as the liquid is being printed into contact with a salt solution, the result is a polymer that solidifies upon leaving the syringe.

What’s also interesting is that the process by which the PNIPAM-based solutions solidify is entirely reversible. Researchers demonstrate printing, breaking down, then re-printing, which is an awfully neat trick. Finally, by mixing different additives in with PNIPAM, one can obtain different properties in the final product. For example, researchers demonstrate making conductive prints by adding carbon nanotubes.

While we’ve seen the concept of printing with liquids by extruding them into a gel bath or similar approach, we haven’t seen a process that prides itself on being so reversible before. The research paper with all the details is available here, so check it out for all the details.

Team members Madeleine Laitz, left, and lead author Dane deQuilettes stand in front of a tidy lab bench equipped with oscilloscopes and computers. Laitz has a snazzy yellow jacket that pops compared to the neutrals and blues of the rest of the picture.

More Progress On Perovskite Solar Cells

March 8, 2024 by Navarre Bartz 20 Comments

Perovskites hold enormous promise for generating solar energy, with the potential to provide lighter and cheaper cells than those made from silicon. Unfortunately, the material breaks down too rapidly to be practical for most applications. But thanks to some recent research, we now have a better understanding of the nanoscale changes that happen during this breakdown, and how to combat it.

The research is focused on the topic of passivation, which seeks to increase the useful lifespan of perovskites by studying the surface interface where they meet other materials. Most of the perovskite material is a perfect latticework of atoms, but this structure is broken at the surface. This atomically “jagged” interface introduces losses which only get worse over time. Currently, the best way to address this issue is to essentially seal the surface with a very thin layer of hexylammonium bromide.

While this technique significantly simplified the passivation process when it was discovered, the effect had yet to be adequately characterized to further advance the field. According to lead author, [Dane deQuilettes], “This is the first paper that demonstrates how to systematically control and engineer surface fields in perovskites.”

Prefer to roll your own cells? How about a DIY dye sensitized cell or this thermionic converter model?

Top left of image shows a picture of a purplish-grey sea cucumber. Above the cucumber is the word "bio-inspiration." Arrows come from the cucumber to anthropomorphized cartoons of it saying "rigid" at the top with a cartoon sea cucumber standing straight up with spikes and the arrow captioned "soft" pointing down showing a crawling sea cucumber that looks more like a slug. To the right of the cucumber images is a set of three images stacked top to bottom. The top image is of a silver sphere with a zoomed-in atomic diagram with aligned magnetic poles next to it saying "solid state." The middle image shows arrows going up and down next to a snowflake and an artistic rendering of magnetic fields labeled "transition." The bottom image of this section shows a reddish sphere next to a zoomed-in atomic diagram where the magnetic poles are not aligned labeled "liquid state."

Phase Change Materials For Flexible And Strong Robots

February 19, 2023 by Navarre Bartz 21 Comments

Shape shifters have long been the stuff of speculative fiction, but researchers in China have developed a magnetoactive phase transitional matter (MPTM) that makes Odo slipping through an air vent that much more believable.

Soft robots can squeeze into small spaces or change shape as needed, but many of these systems aren’t as strong as their more mechanically rigid siblings. Inspired by the sea cucumber’s ability to manipulate its rigidity, this new MPTM can be inductively heated to a molten state to change shape as well as encapsulate or release materials. The neodymium-iron-boron (NdFeB) microparticles suspended in gallium will then return to solid form once cooled.

Applications in drug delivery, foreign object removal, and smart soldering (video after the break) probably have more real world impact than the LEGO minifig T1000 impersonation, despite how cool that looks. While a pick-and-place can do better soldering work on a factory line, there might be repair situations where a magnetically-controlled solder system could come in handy.

We’ve seen earlier work with liquid robots using gallium and bio-electronic hybrids also portending the squishy future of robotics.

Continue reading “Phase Change Materials For Flexible And Strong Robots” →

Two-Dimensional Polymer Is A New Ultra-Strong Material

March 23, 2022 by Lewin Day 26 Comments

Plastics, by and large, are well-understood materials. Not as strong as most metals, but often much lighter, these man-made polymers have found innumerable applications that have revolutionized the way we live. The properties of plastics have been improved in many ways over the years, with composite materials like fiberglass and carbon fiber proving to have strength and lightness far beyond the simple properties of basic polymers alone.

However, a group of engineers at MIT have been working on a revolutionary type of polymer that promises greater strength then ever before while remaining remarkably light weight. It’s all down to the material’s two-dimensional molecular structure, something once thought to be prohibitively difficult in the world of polymer science.

Continue reading “Two-Dimensional Polymer Is A New Ultra-Strong Material” →

Magnesium: Where It Comes From And Why We’re Running Out

November 1, 2021 by Adam Zeloof 94 Comments

Okay, we’re not running out. We actually have tons of the stuff. But there is a global supply chain crisis. Most of the world’s magnesium is processed in China and several months ago, they just… stopped. In an effort to hit energy consumption quotas, the government of the city of Yulin (where most of the country’s magnesium production takes place) ordered 70% of the smelters to shut down entirely, and the remainder to slash their output by 50%. So, while magnesium remains one of the most abundant elements on the planet, we’re readily running out of processed metal that we can use in manufacturing.

Nikon camera body — The magnesium-alloy body of a Nikon d850. Courtesy of Nikon

But, how do we actually use magnesium in manufacturing anyway? Well, some things are just made from it. It can be mixed with other elements to be made into strong, lightweight alloys that are readily machined and cast. These alloys make up all manner of stuff from race car wheels to camera bodies (and the chassis of the laptop I’m typing this article on). These more direct uses aside, there’s another, larger draw for magnesium that isn’t immediately apparent: aluminum production.

But wait, aluminum, like magnesium is an element. So why would we need magnesium to make it? Rest assured, there’s no alchemy involved- just alloying. Much like magnesium, aluminum is rarely used in its raw form — it’s mixed with other elements to give it desirable properties such as high strength, ductility, toughness, etc. And, as you may have already guessed, most of these alloys require magnesium. Now we’re beginning to paint a larger, scarier picture (and we just missed Halloween!) — a disruption to the world’s aluminum supply.

Continue reading “Magnesium: Where It Comes From And Why We’re Running Out” →

A Single-Digit-Micrometer Thickness Wood Speaker

November 27, 2019 by Sharon Lin 22 Comments

Researchers have created an audio speaker using ultra-thin wood film. The new material demonstrates high tensile strength and increased Young’s modulus, as well as acoustic properties contributing to higher resonance frequency and greater displacement amplitude compared to a commercial polypropylene diaphragm in an audio speaker.

Typically, acoustic membranes have to remain very thin (on the micron scale) and robust in order to allow for a highly sensitive frequency response and vibrational amplitude. Materials made from plastic, metal, ceramic, and carbon have been used by engineers and physicists in an attempt to enhance the quality of sound. While plastic thin films are most commonly manufactured, they have a pretty bad impact on the environment. Meanwhile, metal, ceramic, and carbon-based materials are more expensive and less attractive to manufacturers as a result.

Cellulose-based materials have been making an entrance in acoustics research with their environmentally friendly nature and natural wooden structure. Materials like bagasse, wood fibers, chitin, cotton, bacterial cellulose, and lignocellulose are all contenders for effective alternatives to parts currently produced from plastics.

The process for building the ultra-thin film involved removing lignin and hemicellulose from balsa wood, resulting in a highly porous material. The result is hot pressed for a thickness reduction of 97%. The cellulose nano-fibers remain oriented but more densely packed compared to natural wood. In addition, the fibers required higher energy to be pulled apart while remaining flexible and foldable.

At one point in time, plastics seemed to be the hottest new material, but perhaps wood is making a comeback?

[Thanks Qes for the tip!]