Rubber! It starts out as a goopy material harvested from special trees, and is then processed into a resilient, flexible material used for innumerable important purposes. In the vast majority of applications, rubber is prized for its elasticity, which eventually goes away with repeated stress cycles, exposure to heat, and time. When a rubber part starts to show cracks, it’s generally time to replace it.
Researchers at Harvard have now found a way to potentially increase rubber’s ability to withstand cracking. The paper, published in Nature Sustainability, outlines how the material can be treated to provide far greater durability and toughness.
As you might remember from chemistry class, crystals are made up of blocks of atoms (usually called ‘unit cells’) that fit together in perfect repetition — baring dislocations, cracks, impurities, or anything else that might throw off a theoretically perfect crystal structure. There are only so many ways to tessellate atoms in 3D space; 230 of them, to be precise. A quasicrystal isn’t any of them. Rather than repeat endlessly in 3D space, a quasicrystal never repeats perfectly, like a 3D dimensional Penrose tile. The discovery of quasicrystals dates back to the 1980s, and was awarded a noble prize in 2011.
Penrose tiling– the pattern never repeats perfectly. Quasicrystals do this in 3D. (Image by Inductiveload, Public Domain)
Quasicrystals aren’t exactly common in nature, so how does 3D printing come into this? Well, it turns out that, quite accidentally, a particular Aluminum-Zirconium alloy was forming small zones of quasicrystals (the black spots in the image above) when used in powder bed fusion printing. Other high strength-alloys tended to be very prone to cracking, to the point of unusability, and this Al-Zr alloy, discovered in 2017, was the first of its class.
You might imagine that the non-regular structure of a quasicrystal wouldn’t propagate cracks as easily as a regular crystal structure, and you would be right! The NIST researchers obviously wanted to investigate why the printable alloy had the properties it does. When their crystallographic analysis showed not only five-fold, but also three-fold and two-fold rotational symmetry when examined from different angles, the researchers realized they had a quasicrystal on their hands. The unit cell is in the form of a 20-sided icosahedron, providing the penrose-style tiling that keeps the alloy from cracking.
You might say the original team that developed the alloy rolled a nat-20 on their crafting skill. Now that we understand why it works, this research opens up the doors for other metallic quasi-crystals to be developed on purpose, in aluminum and perhaps other alloys.
Nanostructured metamaterials have shown a lot of promise in what they can do in the lab, but often have fatal stress concentration factors that limit their applications. Researchers have now found a strong, lightweight nanostructured carbon. [via BGR]
Using a multi-objective Bayesian optimization (MBO) algorithm trained on finite element analysis (FEA) datasets to identify the best candidate nanostructures, the researchers then brought the theoretical material to life with 2 photon polymerization (2PP) photolithography. The resulting “carbon nanolattices achieve the compressive strength of carbon steels (180–360 MPa) with the density of Styrofoam (125–215 kg m−3) which exceeds the specific strengths of equivalent low-density materials by over an order of magnitude.”
While you probably shouldn’t start getting investors for your space elevator startup just yet, lighter materials like this are promising for a lot of applications, most notably more conventional aviation where fuel (or energy) prices are a big constraint on operations. As with any lab results, more work is needed until we see this in the real world, but it is nice to know that superalloys and composites aren’t the end of the road for strong and lightweight materials.
Everyone knows that time’s arrow only goes in one direction, regardless of the system or material involved. In the case of material time, i.e. the ageing of materials such as amorphous materials resulting from glass transition, this material time is determined after the initial solidification by the relaxation of localized stresses and medium-scale reordering. These changes are induced by the out-of-equilibrium state of the amorphous material, and result in changes to the material’s properties, such as a change from ductile to a brittle state in metallic glasses. It is this material time which the authors of a recent paper (preprint) in Nature Physics postulates to be reversible.
Whether or not this is possible is said to be dependent on the stationarity of the stochastic processes involved in the physical ageing. Determining this stationarity through the investigation of the material time in a number of metallic glass materials (1-phenyl-1-propanol, laponite and polymerizing epoxy) was the goal of this investigation by [Till Böhmer] and colleagues, and found that at least in these three materials to be the case, suggesting that this process is in fact reversible.
Naturally, the primary use of this research is to validate theories regarding the ageing of materials, other aspects of which have been investigated over the years, such as the atomic dynamics by [V.M Giordano] and colleagues in a 2016 paper in Nature Communications, and a 2022 study by [Birte Riechers] and colleagues in Science Advances on predicting the nonlinear physical ageing process of glasses.
While none of these studies will give us time-travel powers, it does give us a better understanding of how materials age over time, including biological systems like our bodies. This would definitely seem to be a cause worthy of our time.
This property has been used to 3D print objects by using a syringe tip as if it were a nozzle in a filament-based printer. As long as the liquid is being printed into contact with a salt solution, the result is a polymer that solidifies upon leaving the syringe.
What’s also interesting is that the process by which the PNIPAM-based solutions solidify is entirely reversible. Researchers demonstrate printing, breaking down, then re-printing, which is an awfully neat trick. Finally, by mixing different additives in with PNIPAM, one can obtain different properties in the final product. For example, researchers demonstrate making conductive prints by adding carbon nanotubes.
While we’ve seen the concept of printing with liquids by extruding them into a gel bath or similar approach, we haven’t seen a process that prides itself on being so reversible before. The research paper with all the details is available here, so check it out for all the details.
Perovskites hold enormous promise for generating solar energy, with the potential to provide lighter and cheaper cells than those made from silicon. Unfortunately, the material breaks down too rapidly to be practical for most applications. But thanks to some recent research, we now have a better understanding of the nanoscale changes that happen during this breakdown, and how to combat it.
The research is focused on the topic of passivation, which seeks to increase the useful lifespan of perovskites by studying the surface interface where they meet other materials. Most of the perovskite material is a perfect latticework of atoms, but this structure is broken at the surface. This atomically “jagged” interface introduces losses which only get worse over time. Currently, the best way to address this issue is to essentially seal the surface with a very thin layer of hexylammonium bromide.
While this technique significantly simplified the passivation process when it was discovered, the effect had yet to be adequately characterized to further advance the field. According to lead author, [Dane deQuilettes], “This is the first paper that demonstrates how to systematically control and engineer surface fields in perovskites.”
Shape shifters have long been the stuff of speculative fiction, but researchers in China have developed a magnetoactive phase transitional matter (MPTM) that makes Odo slipping through an air vent that much more believable.
Soft robots can squeeze into small spaces or change shape as needed, but many of these systems aren’t as strong as their more mechanically rigid siblings. Inspired by the sea cucumber’s ability to manipulate its rigidity, this new MPTM can be inductively heated to a molten state to change shape as well as encapsulate or release materials. The neodymium-iron-boron (NdFeB) microparticles suspended in gallium will then return to solid form once cooled.
Applications in drug delivery, foreign object removal, and smart soldering (video after the break) probably have more real world impact than the LEGO minifig T1000 impersonation, despite how cool that looks. While a pick-and-place can do better soldering work on a factory line, there might be repair situations where a magnetically-controlled solder system could come in handy.
