Hot Resistors Used For Color-changing Clock Face

[Sprite_TM] built a full clock display using thermochromic paint. This picks up where he left off with his paint-based 7-segment display prototype. He never really saw that design through to a finished project, but he recently came across the leftover paint and decided to do something with it. Instead of making thin traces on a PCB he’s heating up resistors mounted on protoboard. Each resistor has been coated with the black/light grey paint after getting a rough sanding on the tops of the packages. Run around 500mW through a segment and they heat up enough to change the paint to light grey. Once shut off, the segments gradually fade over the next 60 seconds.

Power All Over Your Body

We know that you can transform the mechanical motions of your body into electrical energy, like when you turn the crank or shake a mechanically-powered flashlight. These types of mechanical motions are quite large compared to many of the day-to-day (and minute-to-minute) actions you perform–for example walking, breathing, and thumb wrestling.

What if we could harvest energy from these tiny movements? Researchers at the Korea Advanced Institute of Science and Technology are seeking the answer to this question with piezoelectric barium titanate. The electrical output of their devices is very small (in the nanoAmps) but over a long period and over many repetitions it would be possible to run a small electric device–even a biologically-embedded one. An alternative to blood power?

There is clearly a lot of potential in this technology, and we’ll be interested to see if and when we can start messing around with this stuff. Heck, it’s already been used to power a small LED and you all know just how much everyone would jump at the chance to cover themselves in self-powered LEDs…

DIY OLEDs

[Jeri Ellsworth] has put together a couple of videos that cover how she made her own organic light emitting diodes, or OLEDs. In the first video, after the break, it discusses the difference between regular, rigid semiconductor LEDs and organic LEDs. The video then goes on to show how to make an OLED as successive layers of materials. Indium tin oxide (ITO) on glass forms a transparent anode. That is then coated with PEDOT:PSS, a conductive polymer mix that is used as a hole transport layer. Then a red diamond ruthenium complex is added to create the emissive layer. The cathode layer is a low work function metal, initially, gallium indium eutectic alloy then later other metals were shown to work. The second video, shows how to juice a glowstick and make OLEDs with the liquid. The dye in blue glowsticks, 9,10-Diphenylanthracene, is an organic semiconductor and will emit light as an electric current is passed through it. The glow stick method seems to have some problems as the ITO coated glass plate is degraded by the glowstick chemicals. It would be interesting to see if using the porous aluminum or similar technique from [Jeri]’s flexible electroluminescent displays could be used as an electrode.

Continue reading “DIY OLEDs”

Mix Your Own Photo Developing Emulsions

If you’re into developing your own photographs you might try mixing your own emulsion. [Jimmy Hartnett] worked out the chemical reaction necessary to make a photosensitive medium using Silver Chloride. His process lets him manufacture canvas that can be use like photo paper. The gist of it involves coating the back of a canvas with Gesso to prevent the emulsion from passing all the way through. He then floats the canvas face-down to apply the emulsion and skims it with a straight edge before it has time to set. You can see the results of some contact print testing in the image above. If anything, this makes a great piece of art to hang on the wall as it’s visually interesting and [Jimmy] has a personal connection because he not only made it himself, but came up with the process.

Jeri Makes Flexible EL Displays

A failed chemistry experiment led [Jeri Ellsworth] to discover a flexible substrate for electroluminescent displays. We’re familiar with EL displays on the back of a glass panel like you would find in an audio receiver, but after making a mesh from aluminum foil [Jeri] looked at using the porous metal to host phosphors. She starts by cleaning foil and using a vinyl sticker to resist etching portions of the aluminum. It then goes into a bath of boric acid, electrified with the foil as the anode. As the foil etches she tests the progress by shining a laser through the foil. After this the phosphors are applied to the back surface of the foil, covered in a dielectric, and topped off with a conductive ink that will carry the AC necessary to excite the phosphors. This is layering materials in reverse compared to her EL PCB experiments. See [Jeri] explain this herself in the clip after the break.

You can see above that this produces a pretty well-defined display area. It reminds us of that color changing paint display. We think it would be worth a try to build a few 7-segment displays using this method.

Continue reading “Jeri Makes Flexible EL Displays”

LEGO Ball Mill

This is a ball mill used for refining materials into a fine powder. [Jpoopdog] built it in two parts, a base and the tumbler chamber. The base itself is build using LEGO wheels as rollers. The motor and controller from an NXT kit is used to drive the rotation, with programming to stop the mill every so often so that the raw material can cool down. That’s important because this can be used to make substances like aluminum powder, an explosive substance sometimes used in pyrotechnics. We don’t recommend producing your own explosives (or making your own propellant) but if that’s what you’re after [Jpoopdog] did build in a safety feature. The chamber,which is constructed from PVC, has a fail safe to prevent an explosion. A hole has been drilled in the end cap and plugged with hot glue. In the event the milling material starts to overheat the glue will melt and alleviate the built up pressure.

More EL Chemistry: Luminescent Ink

[Jeri Ellsworth] continues her experiments with electroluminescence, this time she’s making EL ink. The ink she’s looking for is Zinc Sulfate in a solution. The process she chose is to re-dope some glow powder so that it can be excited by the field around an AC current. In her video (embedded after the break) she talks about the chemical properties she’s after by detailing a cubic lattice of zinc and sulfur atoms with an added copper atom (adding that atom is a process called doping).

The quick and dirty synopsis of the experiment starts by washing the glow powder with dish soap to acquire zinc sulfide crystals. Then she combined copper sulfate and zinc shavings from the inside of a modern penny to yield copper metal and zinc sulfate suspended in solution. That was mixed with the zinc sulfide from the glow powder washing and doped with a little more copper sulfate. The excess liquid is poured off, the test tube is capped with glass frit, and the whole thing hits the kiln to start the reaction. The result glows when excited by alternating current, but could have been improved by adding chlorine atoms into the mix.

We’re excited every time we see one of [Jeri’s] new chemistry hacks. We’d love to see more so if you’ve come across interesting chemistry experiments during your Internet travels, please let us know about them. Just make sure you have some idea of what you’re doing when working with chemicals… safety first.

Continue reading “More EL Chemistry: Luminescent Ink”