Hydrogen Generation With Seawater, Aluminum, And… Coffee?

August 12, 2024 by Alexander Rowsell 56 Comments

A team at MIT led by [Professor Douglas Hart] has discovered a new, potentially revelatory method for the generation of hydrogen. Using seawater, pure aluminum, and components from coffee grounds, the team was able to generate hydrogen at a not insignificant rate, getting the vast majority of the theoretical yield of hydrogen from the seawater/aluminum mixture. Though the process does use indium and gallium, rare and expensive materials, the process is so far able to recover 90% of the indium-gallium used which can then be recycled into the next batch. Aluminum holds twice as much energy as diesel, and 40x that of Li-Ion batteries. So finding a way to harness that energy could have a huge impact on the amount of fossil fuels burned by humans!

Pure, unoxidized aluminum reacts directly with water to create hydrogen, as well as aluminum oxyhydroxide and aluminum hydroxide. However, any aluminum that has had contact with atmospheric air immediately gets a coating of hard, unreactive aluminum oxide, which does not react in the same way. Another issue is that seawater significantly slows the reaction with pure aluminum. The researchers found that the indium-gallium mix was able to not only allow the reaction to proceed by creating an interface for the water and pure aluminum to react but also coating the aluminum pellets to prevent further oxidization. This worked well, but the resulting reaction was very slow.

Apparently “on a lark” they added coffee grounds. Caffeine had already been known to act as a chelating agent for both aluminum and gallium, and the addition of coffee grounds increased the reaction rate by a huge margin, to the point where it matched the reaction rate of pure aluminum in deionized, pure water. Even with wildly varying concentrations of caffeine, the reaction rate stayed high, and the researchers wanted to find out specifically which part of the caffeine molecule was responsible. It turned out to be imidazole, which is a readily available organic compound. The issue was balancing the amount of caffeine or imidazole added versus the gallium-indium recovery rate — too much caffeine or imidazole would drastically reduce the recoverable amount of gallium-indium.

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Improved Hydrogen Fuel Cells Are Groovy

July 7, 2023 by Al Williams 13 Comments

According to [Charles Q. Choi], a new study indicates that grooves in the hydrogen fuel cells used to power vehicles can improve their performance by up to 50%. Fuel cells are like batteries because they use chemical reactions to create electricity. Where they are different is that a battery reacts a certain amount of material, and then it is done unless you recharge it somehow. A fuel cell will use as much fuel as you give it. That allows it to continue creating electricity until the fuel runs out.

Common hydrogen fuel cells use a proton exchange membrane — a polymer membrane that conducts protons to separate the fuel and the oxidizer. You can think of it as an electrolyte. Common fuel cells use an electrode design that hasn’t changed in decades. The new research has catalyst ridges separated by empty grooves. This enhances oxygen flow and proton transport.

Conventional electrodes use an ion-conducting polymer and a platinum catalyst. Adding more polymer improves proton transport but inhibits oxygen flow. The grooved design allows for dense polymer on the ridges but allows oxygen to flow in the grooves. In technical terms, the proton transport resistance goes down, and there is little change in the oxygen transport resistance.

The grooves are between one and two nanometers wide, so don’t pull out your CNC mill. The researchers admit they had the idea for this some time ago, but it has taken several years to figure out how to fabricate the special electrodes.

Drone Flies For Five Hours With Hydrogen Fuel Cell

May 18, 2023 by Lewin Day 82 Comments

Multirotor drones have become a regular part of daily life, serving as everything from camera platforms to inspection tools and weapons of war. The vast majority run on lithium rechargeable batteries, with corresponding limits on flight time. A company called Hylium hopes to change all that with a hydrogen-powered drone that can fly for up to five hours.

The drone uses a hydrogen fuel cell to provide electricity to run the drone’s motors and other electronic systems. Thanks to the energy density advantage of hydrogen versus lithium batteries, the flight time can be greatly extended compared to conventional battery-only drones. Details are scant, but the company has gone to some lengths to build out the product beyond a simple tech demonstrator, too. Hylium touts useful features like the short five-minute refueling time. The drone also reportedly features a night vision camera and the capability to transmit video over distances up to 10 kilometers, though some of the video of these features appears to be stock footage.

Hylium claims the liquid hydrogen canister used for the drone is drop-safe in the event of a problem. Notably, the video suggests the company tested this by dropping the canister concerningly close to an active motorway, but from what we see, nothing went awry.

A drone that can fly for five hours would be particularly useful for autonomous surveillance and inspection roles. The additional loiter time would be advantageous in these roles. We’ve seen other aero experimenters exploring the use of hydrogen fuel cells, too.

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Largest Ever Hydrogen Fuel Cell Plane Takes Flight

April 3, 2023 by Lewin Day 72 Comments

In the automotive world, batteries are quickly becoming the energy source of the future. For heavier-duty tasks, though, they simply don’t cut the mustard. Their energy density, being a small fraction of that of liquid fuels, just can’t get the job done. In areas like these, hydrogen holds some promise as a cleaner fuel of the future.

Universal Hydrogen hopes that hydrogen will do for aviation what batteries can’t. The company has been developing flight-ready fuel cells for this exact purpose, and has begun test flights towards that very goal.

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China’s New 100 MPH Train Runs On Hydrogen And Supercaps

February 2, 2023 by Lewin Day 83 Comments

Electric cars are very much en vogue right now, as the world tries to clean up on emissions and transition to a more sustainable future. However, these vehicles require huge batteries as it is. For heavier-duty applications like trucks and trains, batteries simply won’t cut the mustard.

Normally, the solution for electrifying railways is to simply string up some wires and call it a day. China is trying an alternative solution, though, in the form of a hydrogen-powered train full of supercapacitors.

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Fuel Cell Drone Aims For Extended Flight Times

October 31, 2020 by Lewin Day 15 Comments

The RC world was changed forever by the development of the lithium-polymer battery. No longer did models have to rely on expensive, complicated combustion engines for good performance. However, batteries still lack the energy density of other fuels, and so flying times can be limited. Aiming to build a drone with impressively long endurance, [Игорь Негода] instead turned to hydrogen power.

The team fitted a power meter to the plane, aiming a camera at it to measure power draw during flight.

With a wingspan of five meters, and similar length, the build is necessarily large in order to carry the hydrogen tank and fuel cell that will eventually propel the plane, which uses a conventional brushless motor for propulsion. Weighing in at 6 kilograms, plenty of wing is needed to carry the heavy components aloft. Capable of putting out a maximum of 200W for many hours at a time, the team plans to use a booster battery to supply extra power for short bursts, such as during takeoff. Thus far, the plane has flown successfully on battery power, with work ongoing to solve handling issues and determine whether the platform can successfully fly on such low power.

We’re eager to see how the project develops, particularly in regards to loiter time. We can imagine having a few pilots on hand may be necessary with such a long flight time planned — other drones of similar design have already surpassed the 60-minute mark. Video after the break.

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Hackaday Podcast 034: 15 Years Of Hackaday, ESP8266 Hacked, Hydrogen Seeps Into Cars, Giant Scara Drawbot, Really Remote RC Car Racing

September 6, 2019 by Mike Szczys 5 Comments

Elliot Williams and Mike Szczys wish Hackaday a happy fifteenth birthday! We also jump into a few vulns found (and fixed… ish) in the WiFi stack of ESP32/ESP8266 chips, try to get to the bottom of improved search for 3D printable CAD models, and drool over some really cool RC cars that add realism to head-to-head online racing. We look at the machining masterpiece that is a really huge SCARA arm drawbot, ask why Hydrogen cars haven’t been seeing the kind of sunlight that fully electric vehicles do, and give a big nod of approval to a guide on building your own custom USB cables.

Take a look at the links below if you want to follow along, and as always tell us what you think about this episode in the comments!

Take a look at the links below if you want to follow along, and as always, tell us what you think about this episode in the comments!

Direct download (60 MB or so.)