Boss Byproducts: Calthemites Are Man-Made Cave Dwellers

November 20, 2024 by Kristina Panos 6 Comments

Some lovely orange calthemite flowstone colored so by iron oxide from rusting steel reinforcing. Image via Wikipedia

At this point, we’ve learned about man-made byproducts and nature-made byproducts. But how about one that’s a little of both? I’m talking about calthemites, which are secondary deposits that form in those man-made caves such as parking garages, mines, and tunnels.

Calthemites grow both on and under these structures in forms that mimic natural cave speleothems like stalactites, stalagmites, flowstone, and so on. They are often the result of an hyperalkalinic solution of pH 9-14 seeping through a concrete structure to the point of coming into contact with the air on the underside. Here, carbon dioxide in the air facilitates the necessary reactions to secondarily deposit calcium carbonate.

These calcium carbonate deposits are usually white, but can be colored red, orange, or yellow thanks to iron oxide. If copper pipes are around, copper oxide can cause calthemites to be blue or green. As pretty as all that sounds, I didn’t find any evidence of these parking garage growths having been turned into jewelry. So there’s your million-dollar idea.

Continue reading “Boss Byproducts: Calthemites Are Man-Made Cave Dwellers” →

Homebrew PH Meter Uses Antimony Electrode

November 15, 2024 by Dan Maloney 11 Comments

Understanding the nature of pH has bedeviled beginning (and not-so-beginning) chemistry students for nearly as long as chemistry has had students. It all seems so arbitrary, being the base-10 log of the inverse of hydrogen ion concentration and with a measurement range of 0 to 14. Add to that the electrochemical reactions needed to measure pH electronically, and it’s enough to make your head spin.

Difficulties aside, [Markus Bindhammer] decided to tackle the topic and came up with this interesting digital pH meter as a result. Measuring pH electronically is all about the electrode, or rather a pair of electrodes, one of which is a reference electrode. The potential difference between the electrodes when dipped into the solution under test correlates to the pH of the solution. [Markus] created his electrode by drawing molten antimony into a length of borosilicate glass tubing containing a solid copper wire as a terminal. The reference electrode was made from another piece of glass tubing, also with a copper terminal but filled with a saturated solution of copper(II) sulfate and plugged with a wooden skewer soaked in potassium nitrate.

In theory, this electrode system should result in a linear correlation between the pH of the test solution and the potential difference between the electrodes, easily measured with a multimeter. [Marb]’s results were a little different, though, leading him to use a microcontroller to scale the electrode output and display the pH on an OLED.

The relaxing video below shows the build process and more detail on the electrochemistry involved. It might be worth getting your head around this, since liquid metal batteries based on antimony are becoming a thing.

Continue reading “Homebrew PH Meter Uses Antimony Electrode” →

Desert Island Acetylene From Seashells And Driftwood

November 15, 2024 by Dan Maloney 35 Comments

[MacGyver] would be proud of [Hyperspace Pirate]’s rough and ready method of producing acetylene gas from seashells and driftwood.

Acetylene, made by decomposing calcium carbide with water, is a vitally important industrial gas. Not only as a precursor in many chemical processes, but also as the fuel for the famous “blue wrench,” a tool without which auto mechanics working in the Rust Belt would be reduced to tears. To avoid this, [Hyperspace Pirate] started by beachcombing for the raw materials: shells to make calcium oxide and wood to make charcoal. Charcoal is pretty easy; you just cook chunks of wood in a reducing environment to drive off everything but the carbon. Making calcium oxide from the calcium carbonate in the shells isn’t much harder, with ground seashells heated in a propane-fired furnace to release carbon dioxide.

With the raw ingredients in hand, things get a little tricky. Making calcium carbide requires a lot of heat, far more than a simple propane burner can provide. [Hyperspace Pirate] decided to go with an electric arc furnace, to which end he cannibalized a 120 V to 240 V step-up converter for its toroidal transformer, which with a few extra windings provided the needed current to run an arc through carbon electrodes. This generated the needed heat, and then some, as the ceramic firebrick he was using to contain the inferno melted. After rewinding the melted secondary windings on his makeshift transformer and switching to a stainless steel crucible, he was able to make enough calcium carbide to generate an impressive amount of acetylene. The video below documents the process and the sooty results, as well as details a little of the excitement that metal acetylides offer.

For more about acetylene and its many uses, [This Old Tony] has you covered.

Continue reading “Desert Island Acetylene From Seashells And Driftwood” →

A Tiny Chemistry Lab

November 8, 2024 by Bryan Cockfield 12 Comments

While advances in modern technology have allowed average people access to tremendous computing power as well as novel tools like 3D printers and laser cutters for a bare minimum cost, around here we tend to overlook some of the areas that have taken advantage of these trends as well. Specifically in the area of chemistry, the accessibility of these things have opened up a wide range of possibilities for those immersed in this world, and [Marb’s Lab] shows us how to build a glucose-detection lab in an incredibly small form factor.

The key to the build is a set of three laser-cut acrylic sheets, which when sandwiched together provide a path for the fluid to flow as well as a chamber that will be monitored by electronic optical sensors. The fluid is pumped through the circuit by a custom-built syringe pump driven by a linear actuator, and when the chamber is filled the reaction can begin. In this case, if the fluid contains glucose it will turn blue, which is detected by the microcontroller’s sensors. The color value is then displayed on a small screen mounted to the PCB, allowing the experimenter to take quick readings.

Chemistry labs like this aren’t limited to one specific reaction, though. The acrylic plates are straightforward to laser cut, so other forms can be made quickly. [Marb’s Lab] also made the syringe pump a standalone system, so it can be quickly moved or duplicated for use in other experiments as well. If you want to take your chemistry lab to the extreme, you can even build your own mass spectrometer.

Continue reading “A Tiny Chemistry Lab” →

Boss Byproducts: Fulgurites Are Fossilized Lightning

October 29, 2024 by Kristina Panos 28 Comments

So far in this series, we’ve talked about man-made byproducts — Fordite, which is built-up layers of cured car enamel, and Trinitite, which was created during the first nuclear bomb test.

A fulgurite pendant. — A lovely fulgurite pendant. Image via Etsy

But not all byproducts are man-made, and not all of them are basically untouchable. Some are created by Mother Nature, but are nonetheless dangerous. I’m talking about fulgurites, which can form whenever lightning discharges into the Earth.

It’s likely that even if you’ve seen a fulgurite, you likely had no idea what it was. So what are they, exactly? Basically, they are natural tubes of glass that are formed by a fusion of silica sand or rock during a lightning strike.

Much like Lichtenberg figures appear across wood, the resulting shape mimics the path of the lightning bolt as it discharged into the ground. And yes, people make jewelry out of fulgurites.

Continue reading “Boss Byproducts: Fulgurites Are Fossilized Lightning” →

A Homebrew Gas Chromatograph That Won’t Bust Your Budget

October 13, 2024 by Dan Maloney 19 Comments

Chances are good that most of us will go through life without ever having to perform gas chromatography, and if we do have the occasion to do so, it’ll likely be on a professional basis using a somewhat expensive commercial instrument. That doesn’t mean you can’t roll your own gas chromatograph, though, and if you make a few compromises, it’s not even all that expensive.

At its heart, gas chromatography is pretty simple; it’s just selectively retarding the movement of a gas phase using a solid matrix and measuring the physical or chemical properties of the separated components of the gas as they pass through the system. That’s exactly what [Markus Bindhammer] has accomplished here, in about the simplest way possible. Gas chromatographs generally use a carrier gas such as helium to move the sample through the system. However, since that’s expensive stuff, [Markus] decided to use room air as the carrier.

The column itself is just a meter or so of silicone tubing packed with chromatography-grade silica gel, which is probably the most expensive thing on the BOM. It also includes an injection port homebrewed from brass compression fittings and some machined acrylic blocks. Those hold the detectors, an MQ-2 gas sensor module, and a thermal conductivity sensor fashioned from the filament of a grain-of-wheat incandescent lamp. To read the sensors and control the air pump, [Markus] employs an Arduino Uno, which unfortunately doesn’t have great resolution on its analog-to-digital converter. To fix that, he used the ubiquitous HX7111 load cell amplifier to read the output from the thermal conductivity sensor.

After purging the column and warming up the sensors, [Markus] injected a sample of lighter fuel and exported the data to Excel. The MQ-2 clearly shows two fractions coming off the column, which makes sense for the mix of propane and butane in the lighter fuel. You can also see two peaks in the thermal conductivity data from a different fuel containing only butane, corresponding to the two different isomers of the four-carbon alkane.

[Markus] has been on a bit of a tear lately; just last week, we featured his photochromic memristor and, before that, his all-in-one electrochemistry lab.

Continue reading “A Homebrew Gas Chromatograph That Won’t Bust Your Budget” →

Memristors Are Cool, Radiation-resistant Memristors Even Moreso

October 5, 2024 by Donald Papp 9 Comments

Space is a challenging environment for semiconductors, but researchers have shown that a specific type of memristor (the hafnium oxide memristor, to be exact) actually reacts quite usefully when exposed to gamma radiation. In fact, it’s even able to leverage this behavior as a way to measure radiation exposure. In essence, it’s able to act as both memory and a sensor.

Being able to resist radiation exposure is highly desirable for space applications. Efficient ways to measure radiation exposure are just as valuable. The hafnium oxide memristor looks like it might be able to do both, but before going into how that works, let’s take a moment for a memristor refresher.

A memristor is essentially two conductive plates between which bridges can be made by applying a voltage to “write” to the device, by which one sets it to a particular resistance. A positive voltage causes bridging to occur between the two ends, lowering the device’s resistance, and a negative voltage reverses the process, increasing the resistance. The exact formulation of a memristor can vary. The memristor was conceived in the 1970s by Leon Chua, and HP Labs created a working one in 2008. An (expensive) 16-pin DIP was first made available in 2015.

A hafnium oxide memristor is a bit different. Normally it would be write-once, meaning a negative voltage does not reset the device, but researchers discovered that exposing it to gamma radiation appears to weaken the bridging, allowing a negative voltage to reset the device as expected. Exposure to radiation also caused a higher voltage to be required to set the memristor; a behavior researchers were able to leverage into using the memristor to measure radiation exposure. Given time, a hafnium oxide memristor exposed to radiation, causing it to require higher-than-normal voltages to be “set”, eventually lost this attribute. After 30 days, the exposed memristors appeared to recover completely from the effects of radiation exposure and no longer required an elevated voltage for writing. This is the behavior the article refers to as “self-healing”.

The research paper has all the details, and it’s interesting to see new things relating to memristors. After all, when it comes to electronic components it’s been quite a long time since we’ve seen something genuinely new.