The Worst Greenhouse Gasses You Haven’t Heard Of

Carbon dioxide has long drawn the ire of an environmentally-conscious humanity. Released from combustion of fossil fuels, levels of CO2 in the atmosphere are higher now than at any point in the past 400,000 years. With the warming effects this has on the global environment, bringing these numbers down is a primary goal of scientists and policy makers worldwide.

However, this only tells part of the story. Carbon dioxide is not alone in its role as a greenhouse gas, with many others contributing significantly to global temperature rises. As humanity struggles to keep warming below 2 degrees C over the century, strategies will be needed to tackle the problem on all fronts.

There’s A Bad Smell Around Methane

Ruminant animals are a major source of greenhouse gas emissions, which is probably no surprise to some.
Source: Wikimedia Commons

Methane is a remarkably potent greenhouse gas, having 28 times the warming potential of CO2 by weight over a 100-year period. Historically, it’s mostly been released from natural sources, like bacteria processing organic material in stagnant watercourses, or from thawing permafrost. However, scientists now consider around 60% of methane in the atmosphere to be a direct result of human activity.

Agriculture is a major contributor in this area. Ruminant animals raised for human consumption are major methane emitters, as the microbes in their digestive systems release the gas when breaking down plant material. With the demand for meat and dairy showing no signs of slowing down, this could prove difficult to tackle. There are a variety of other diffuse sources of the gas, too. Landfills and sewage plants have significant methane emissions of their own, and it’s also often released from oil and gas drilling operations, too.

Oil and gas operations release significant quantities of methane into the atmosphere, often due to leaks or plant malfunctions.

Levels of methane in the atmosphere have been low compared to carbon dioxide. Methane also tends to have a short life in the atmosphere, of around 9 years. These factors have meant that methane has historically been of lower concern to environmental organisations. However, after levels plateaued from the 1990s to the mid-2000s, they have once again begun to climb precipitously. Scientists have yet to identify the cause of this rise, and it has the potential to undo hard-fought gains in the fight against global warming on the CO2 front. Theories range from a reduced level of chemicals that break down methane in the atmosphere, to increased livestock production or the rise of the hydraulic fracturing industry.

Whatever the cause of the recent rise, stemming the increase will require significant work. The Environmental Defence Fund is launching MethaneSAT in an attempt to better locate and quantify releases to the atmosphere, aiming to stem easily-fixed leaks in fossil fuel operations. Other ideas include using antibiotics to reduce animal’s methane output, or to capture the emissions from landfills and use them as an energy source. It’s likely a rigorous approach to both monitoring and emissions reduction will be required to keep methane levels in check.

Nitrous Oxide

Fertilizer use is a major contributor to nitrous oxide emissions.

Nitrous oxide isn’t just the favorite gas of the Fast and the Furious. It’s also a potent greenhouse gas, with 300 times the warming potential of carbon dioxide, pound for pound. With plenty of staying power, it sticks around in the atmosphere for 114 years on average. With 40 percent of NOx emissions coming from human activity, it’s a significant player as far as greenhouse gases go.

Fertilizer use in agriculture is the major contributor to nitrous oxide releases into the atmosphere. As farms push for ever-greater yields, there has been a corresponding increase in the use of nitrogen-containing fertilizers. Other lesser sources include fossil fuel combustion and various chemical production processes.

Reducing nitrous oxide emissions to any major degree is a difficult problem. Reducing farm yields is impractical if we wish to continue feeding as many people as possible. Increasing the efficiency of fertiliizer application is instead a more viable way to go. By applying fertilizers in the right way, in the right quantities at the right time, has the benefit of both reducing nitrous oxide emissions as well as cutting costs for farming operations. Other gains in this space can be made by reducing fossil fuel use by switching to renewable energy production, or cleaner burning technologies. The famous catalytic converter, introduced to gasoline-powered vehicles in the 1970s, plays a major role in reducing these emissions, and urea injection does much the same for diesel engines, which we’ve talked about before.

Sulfur Hexa-what now?

Sulfur hexafluoride is used heavily in high-voltage switchgear, as seen here in this hydroelectric installation. This circuit breaker is rated to run at 115 kV, 1200 A.

Recently, sulfur hexafluoride has come under scrutiny. Also known by its chemical formula, SF6, it’s a highly potent greenhouse gas, with a warming potential of over 23,000 times that of CO2. Prized for its performance as a gaseous dielectric medium, it’s used heavily in high-voltage circuit breakers in modern electricity grids. It enables the construction of much more compact switchgear, while remaining safe and reliable in operation.

Concentrations of SFhave begun to tick up in recent times, raising alarm bells. Speculation is that this is down to leaks of the gas from electrical equipment. As the world’s energy mix changes, grids have come to rely on more distributed generation, from sources like wind farms and solar. This mode of generation necessitates many more connections to the grid, which means more switchgear, and thus more SF6 out in the wild.

This graph shows the lifetime equivalent emissions of AirPlus versus SF6 technology. There are major gains to be had, thanks to the low global warming potential of AirPlus.

Work is afoot to slow this trend before things get out of hand. A replacement has been developed in a collaboration between ABB and 3M, by the name of AirPlus. While the production process releases more CO2, over the lifecycle of an installation, AirPlus-based switchgear should have far lower impact on warming. This is due to the fact that when released into the atmosphere, AirPlus degrades under UV light exposure in just 15 days, versus 3200 years for SF6. Its global warming potential is less than 1, meaning it has less of a warming effect than even CO2, while delivering comparable dielectric performance to SF6. Variants are available for both medium and high voltage applications.

Over time, as goverments work to reduce the prevalance of SFin new installations, its likely that we’ll see AirPlus and other alternatives gain steam. The gas has already been banned in the EU for all non-electrical purposes, since 2014. Industry is typically slow to act unless there’s a strong business case, so government intervention is likely to be the game changer that pushes adoption of newer, cleaner technology in this space.

Other Fluorinated Gases

SF6 is just one of a series of fluorinated gases that have significant global warming potential. Many of these were introduced as replacements for chlorofluorocarbons (CFCs), which tend to eat a hole in the ozone layer. Thankfully, that problem was largely solved when production of CFCs was tailed off in 1996, but their replacements can still cause further troubles.

With lifetimes in the hundreds to thousands of years in the upper atmosphere, gases like hydrofluorocarbons and perfluorocarbons have an outsized effect on atmospheric warming, thousands of times that of CO2 on a per-molecule basis. They have applications as aerosol propellants, solvents, and fire retardants, but their primary use is as refrigerants in cooling systems. HFC-134a is the most well-known, used widely in air conditioning systems worldwide, and particularly in motor vehicles. This has led to its position as the most abundant HFC in the atmosphere.

Efforts are in place to limit the impact of these chemicals, through precautionary measures. This involves taking more care during the repair and disposal of HVAC systems, as well as designing systems to be more resilient of leaks in the first place. Recycling methods are also beneficial to ensure that where possible, these gases are captured rather then simply vented to the atmosphere. Enforcement on a broad scale remains a challenge.

Automakers are already planning to switch air conditioning systems to use gases that have less global warming potential.
Source: Mercedes Benz

Sometimes, it’s better to avoid the problem entirely. A transition away from using refrigerants like HFC-134a is in progress. The EPA has legislated that all light vehicles manufactured or sold in the USA by model year 2021 must no longer use HFC-134a. Instead, alternatives like HFO-1234yf, HFC-152a, and R-744 will be legal. The first two are mildly flammable, while the latter is simply another name for good old CO2. These refrigerants will require different technology to existing air conditioners. CO2-based systems in particular needing to operate at up to 10 times the pressure of traditional systems. However, progress in technology should allow these gases to take over, reducing the impact these refrigeration gases have on global warming.

The Fight Continues

CO2 is still the primary greenhouse gas, but it’s not the whole story. We’ve looked at a wide variety of chemicals, each with their own important roles and impact on the Earth’s atmosphere. This highlights the fact that there’s no single panacea to heading off global warming; instead, a broad spectrum approach across all aspects of human endeavour is required.

Halting the impacts of these chemicals is difficult, and will require decisive action by both government bodies, as well as cooperation from relevant industries. In some cases, there are additional gains to be had, while in others, the solution comes with high costs and painful changes. We engineered ourselves into this situation, so we can probably engineer ourselves out. Regardless, if humanity is to flourish in the next century, there remains much work to be done.

A Trillion Trees – How Hard Can It Be?

Data from 2016 pegs it as the hottest year since recording began way back in 1880. Carbon dioxide levels continue to sit at historical highs, and last year the UN Intergovernmental Panel on Climate Change warned that humanity has just 12 years to limit warming to 1.5 C.

Reducing emissions is the gold standard, but it’s not the only way to go about solving the problem. There has been much research into the field of carbon sequestration — the practice of capturing atmospheric carbon and locking it away. Often times, this consists of grand plans of pumping old oil wells and aquifers full of captured CO2, but there’s another method of carbon capture that’s as old as nature itself.

As is taught in most primary school science courses, the trees around us are responsible for capturing carbon dioxide, in the process releasing breathable oxygen. The carbon becomes part of the biomass of the tree, no longer out in the atmosphere trapping heat on our precious Earth. It follows that planting more trees could help manage carbon levels and stave off global temperature rises. But just how many trees are we talking? The figure recently floated was 1,000,000,000,000 trees, which boggles the mind and has us wondering what it would take to succeed in such an ambitious program.

Continue reading “A Trillion Trees – How Hard Can It Be?”

Friday Hack Chat: Climate Change

This Friday, we’re talking climate change. Is it possible to remove carbon from the atmosphere before most cities are underwater? What role can hackers play in alleviating climate change? It’s all going down this Friday on the Hack Chat on Hackaday.io

We’ve invited [Tito Jankowski] and [Matthew Eshed] to talk about climate change this Friday over on hackaday.io. [Tito] and [Matthew] are the founders of Impossible Labs, and they’re looking for ways to find, test, and build technology that will remove carbon from Earth’s atmosphere. Their goal is to return the earth’s atmosphere to 300 parts per million of carbon dioxide by 2050. Will they succeed? If someone doesn’t, you can kiss every coastal city goodbye.

Their first job is getting everyone to care. [Jankowski] thinks it can be done through better access to information and snazzy graphics — if people knew what was going on, maybe they’d give a darn. So whether you’d like to talk graphics and data or the engineering of carbon sequestration devices, this is a Hack Chat of global importance. Join us!

Here’s How To Take Part:

join-hack-chatOur Hack Chats are live community events on the Hackaday.io Hack Chat group messaging. This Hack Chat will take place at noon Pacific time on Friday, June 30th. Confused about where and when ‘noon’ is? Here’s a time and date converter!

Log into Hackaday.io, visit that page, and look for the ‘Join this Project’ Button. Once you’re part of the project, the button will change to ‘Team Messaging’, which takes you directly to the Hack Chat.

You don’t have to wait until Friday; join whenever you want and you can see what the community is talking about.

Earth Day: Terraforming The Earth

In 300 years, New York, London, Tokyo, and just about every major city on the planet will be underwater. Sub-Saharan Africa will extend to the equator. Arizona will get hurricanes. These are huge problems, but luckily there are a few very creative people working to terraform the Earth for this year’s Hackaday Prize.

[Danny] is working to stop desertification, and stop blowing drifts of sand from encroaching on valuable farm land. How does his project aim to do this? There are a few techniques that can mitigate or even stop the expanding deserts, including reforestation, proper water management, and using woodlots and windbreaks just like in the 1930s dust bowl.

With the right tools, these techniques are fairly simple to implement. For that, [Danny] is working on a biodegradable lattice framework that will hold soil in place just like plant roots would. It’s an interesting concept, and we can’t wait to see what kind of prototypes [Danny comes up with.

The Terra Spider takes a different tack. In true post-apocalyptic fashion, the Terra Spider will deploy thousands of robots capable of moving and removing biomatter from the environment. Each of the Terra Spiders is able to monitor the local environment, and a few dozen of these bots connected by a wireless network will be able to address a specific site’s needs to make a landscape the way it should be.