Homebrew PH Meter Uses Antimony Electrode

Understanding the nature of pH has bedeviled beginning (and not-so-beginning) chemistry students for nearly as long as chemistry has had students. It all seems so arbitrary, being the base-10 log of the inverse of hydrogen ion concentration and with a measurement range of 0 to 14. Add to that the electrochemical reactions needed to measure pH electronically, and it’s enough to make your head spin.

Difficulties aside, [Markus Bindhammer] decided to tackle the topic and came up with this interesting digital pH meter as a result. Measuring pH electronically is all about the electrode, or rather a pair of electrodes, one of which is a reference electrode. The potential difference between the electrodes when dipped into the solution under test correlates to the pH of the solution. [Markus] created his electrode by drawing molten antimony into a length of borosilicate glass tubing containing a solid copper wire as a terminal. The reference electrode was made from another piece of glass tubing, also with a copper terminal but filled with a saturated solution of copper(II) sulfate and plugged with a wooden skewer soaked in potassium nitrate.

In theory, this electrode system should result in a linear correlation between the pH of the test solution and the potential difference between the electrodes, easily measured with a multimeter. [Marb]’s results were a little different, though, leading him to use a microcontroller to scale the electrode output and display the pH on an OLED.

The relaxing video below shows the build process and more detail on the electrochemistry involved. It might be worth getting your head around this, since liquid metal batteries based on antimony are becoming a thing.

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Op Amp Challenge: An Ultra-Cheap PH Sensor Amplifier

It’s rare in 2023 for an instrument to be entirely analog, instead it’s more normal for a front-end to feed the analog-to-digital converter (ADC) in a microcontroller. Typically the front-end will do the job of transforming whatever the output range of the sensor is, and present it to the microcontroller in whatever range it accepts. [David] had exactly this problem with a pH sensor, and rather than buy an expensive module to do the job he designed his own.

The sensor in question produces a relatively tiny voltage of -0.414 to +0.414 volts, and requires a very high input impedance. A FET input op-amp is selected, with the ground of the sensor shifted upwards into the positive range by a voltage divider. This then feeds a second op-amp that amplifies the resulting DC voltage for the microcontroller input.

This circuit is an especially simple op-amp application, and is a typical one for a sensor interface where a DC voltage needs to be brought into range of a microcontroller. If you’re not used to op-amp circuits then take a look, this type of analogue circuit is not difficult and might just save your butt some time.

Want to know more about simple op-amp circuits? Have we got the video for you!

Basic Toolkit For The Basement Biohacker

Laying hands on the supplies for most hacks we cover is getting easier by the day. A few pecks at the keyboard and half a dozen boards or chips are on an ePacket from China to your doorstep for next to nothing. But if hacking life is what you’re into, you’ll spend a lot of time and money gathering the necessary instrumentation. Unless you roll your own mini genetic engineering lab from scratch, that is.

arduino-based-biolab-data-logger-thumbTaking the form of an Arduino mega-shield that supports a pH meter, a spectrophotometer, and a PID-controlled hot plate, [M. Bindhammer]’s design has a nice cross-section of the instruments needed to start biohacking in your basement. Since the shield piggybacks on an Arduino, all the data can be logged, and decisions can be made based on the data as it is collected. One example is changing the temperature of the hot plate when a certain pH is reached. Not having to babysit your experiments could be a huge boon to the basement biohacker.

Biohacking is poised to be the next big thing in the hacking movement, and [M. Bindhammer]’s design is far from the only player in the space. From incubators to peristaltic pumps to complete labs in a box, the tools to tweak life are starting to reach critical mass. We can’t wait to see where these tools lead.