a–d, Crystal structures of the 1CzTrz-F (a,b) and 3CzTrz-F (c,d) compounds, determined by XRD. a,c, Diagrams of the two dimers of both crystallographic unit cells to show the molecular packing. b,d, Spatial arrangement of the acceptor–donor contacts in the 3D crystal structure. The triazine acceptor and the carbazole donor units are coloured orange and blue, respectively. The green features in d indicate co-crystallized chloroform molecules. (Credit: Oskar Sachnik et al., 2023)

Eliminating Charge-Carrier Trapping In Organic Semiconductors

August 13, 2023 by Maya Posch 4 Comments

For organic semiconductors like the very common organic light-emitting diode (OLED), the issue of degradation due to contaminants that act as charge traps is a major problem. During the development of OLEDs, this was very pronounced in the difference between the different colors and the bandgap which they operated in. Due to blue OLEDs especially being sensitive to these charge traps, it still is the OLED type that degrades the quickest as contaminants like oxygen affect it the strongest. Recent research published in Nature Materials from researchers at the Max Planck Institute for Polymer Research by Oskar Sachnik and colleagues (press release) may however have found a way to shield the electron-carrying parts of organic semiconductors from such contaminants.

Current density (J)–voltage (V) characteristics of electron- and hole-only devices of 3CzTrz and TPBi. (Credit: Oskar Sachnik et al., 2023)

In current organic semiconductors TPBi is used for electron transport, whereas for this research triazine (Trz, as electron acceptor) and carbozole (Cz, as donor) were used and compared with the properties of leading-edge TPBi. While a few other formulations in the study did not show remarkable results, one compound (3CzTrz) was found using X-ray diffraction (XRD) to have a structure as shown on the right in the heading image, with the carbozole (in blue) forming essentially channels along which electrons can move, while shielded from contaminants by the triazine.

Using this research it might be possible to create organic semiconductors in the future which are free of charge-traps, and both efficiency and longevity of this type of semiconductor (including OLEDs and perovskites) can be improved immensely.

Using JTAG To Dump The Xbox’s Secret Boot ROM

August 11, 2023 by Maya Posch 13 Comments

When Microsoft released its first entry into the video game console market with the Xbox, a lot of the discussions at the time revolved around the fact that it used a nearly off-the-shelf Intel CPU and NVIDIA GPU solution. This made it quite different from the very custom consoles from Nintendo and Sony, and invited thoughts on running custom code on the x86 console. Although the security in the console was hacked before long, there were still some open questions, such as whether the secret boot ROM could have been dumped via the CPU’s JTAG interface. This is the question which [Markus Gaasedelen] sought to answer.

The reason why this secret code was originally dumped by intercepting it as it made its merry way from the South to the North Bridge (containing the GPU) of the Xbox was because Microsoft had foolishly left this path unencrypted, and because the JTAG interface on the CPU was left disabled via the TRST# pin which was tied to ground. This meant that without removing the CPU and adding some kind of interposer, the JTAG interface would not be active.

A small issue after the harrowing task of desoldering the CPU and reinstalling it with the custom interposer in place was to keep the system integrity check (enforced by an onboard PIC16 MCU) intact. With the CPU hooked up to the JTAG debugger this check failed, requiring an external injection of the signal on the I2C bus to keep the PIC16 from resetting the system. Yet even after all of this, and getting the secret bootrom code dumped via JTAG, there was one final system reset that was tied to the detection of an abnormal CPU start-up.

The original Xbox ended up being hacked pretty thoroughly, famously giving rise to projects like Xbox Media Center (XBMC), which today is known as Kodi. Microsoft learned their lesson though, as each of their new consoles has been more secure than the last. Barring some colossal screw-up in Redmond, the glory days of Xbox hacking are sadly well behind us.

The World ID Orb And The Question Of What Defines A Person

August 10, 2023 by Maya Posch 68 Comments

Among the daily churn of ‘Web 3.0’, blockchains and cryptocurrency messaging, there is generally very little that feels genuinely interesting or unique enough to pay attention to. The same was true for OpenAI CEO Sam Altman’s Ethereum blockchain-based Worldcoin when it was launched in 2021 while promising many of the same things as Bitcoin and others have for years. However, with the recent introduction of the World ID protocol by Tools for Humanity (TfH) – the company founded for Worldcoin by Mr. Altman – suddenly the interest of the general public was piqued.

Defined by TfH as a ‘privacy-first decentralized identity protocol’ World ID is supposed to be the end-all, be-all of authentication protocols. Part of it is an ominous-looking orb contraption that performs iris scans to enroll new participants. Not only do participants get ‘free’ Worldcoins if they sign up for a World ID enrollment this way, TfH also promises that this authentication protocol can uniquely identify any person without requiring them to submit any personal data, only requiring a scan of your irises.

Essentially, this would make World ID a unique ID for every person alive today and in the future, providing much more security while preventing identity theft. This naturally raises many questions about the feasibility of using iris recognition, as well as the potential for abuse and the impact of ocular surgery and diseases. Basically, can you reduce proof of personhood to an individual’s eyes, and should you?

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Humanity’s Return To The Moon And The Prospect Of South Pole Moon Bases

August 9, 2023 by Maya Posch 31 Comments

The last time that a human set foot on the Moon, it was December 1972 — when the crew of the Apollo 17 mission spent a few days on the surface before returning to Earth. Since then only unmanned probes have either touched down on the lunar surface or entered orbit to take snapshots and perform measurements.

But after years of false starts, there are finally new plans on the table which would see humans return to the Moon. Not just to visit, but with the goal of establishing a permanent presence on the lunar surface. What exactly has changed that the world went from space fever in the 1960s to tepid interest in anything beyond LEO for the past fifty years, to the renewed interest today?

Part of the reason at least appears to be an increasing interest in mineable resources on the Moon, along with the potential of manufacturing in a low gravity environment, and as a jumping-off point for missions to planets beyond Earth, such as Mars and Venus. Even with 1960s technology, the Moon is after all only a few days away from launch to landing, and we know that the lunar surface is rich in silicon dioxide, aluminium oxide as well as other metals and significant amounts of helium-3, enabling in-situ resource utilization.

Current and upcoming Moon missions focus on exploring the lunar south pole in particular, with frozen water presumed to exist in deep craters at both poles. All of which raises the question of we may truly see lunar-based colonies and factories pop up on the Moon this time, or are we merely seeing a repeat of last century?

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Reviving An 8-Inch Hard Drive From The 1980s

August 8, 2023 by Maya Posch 17 Comments

As part of the eternal quest within the realm of retrocomputing, storage devices can be one of the most challenging, especially when it comes to firmly obsolete hard drives, such as the CDC Finch drive. This compact 8″ HDD replaced the previous 14″ models with a form factor that was decidedly more portable. These Finch drives being 1980s technology that got run pretty hard before their retirement, it’s little wonder that they’d end up on the repair bench over at [Usagi Electric]

A CDC Finch hard disk drive, available in 8 to 32 MB for all your data storage needs. (Credit: Usage Electric)

Introduced in the early 1980s, the CDC Model 9410 Finch drive was unlike its 14″ predecessors in that it is a sealed unit, with maintenance-free air filtration. With the 14″ models you’d have both fixed and swappable platters, with far less consideration for dust exposure. This makes these Finch drives more touchy to work on, not unlike HDDs today, and adds to the excitement when repairing one of these old drives.

In this video, two differently broken Finch drives are discussed. Both appear to have an issue on the controller board, with one not responding to communications on the interface, while the other featuring a dead short on the interface pins. The first drive was brought back to life by replacing a dead SN75110 line driver IC, as well as a dead 7818 voltage regulator that was only outputting a sad 0.3 V.

Unfortunately, after half an hour of uptime and in the process of dumping data the drive errored out with a Not Ready, indicating that there are further issues on the controller board to fix. The good news here is that the platters appear to be pretty robust, but the controller boards on these old drives tend to develop issues over the years, something which will be further explored in upcoming videos.

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When The Sojourner Mars Rover Nearly Ran LISP

August 7, 2023 by Maya Posch 12 Comments

During the late 1980s NASA’s Jet Propulsion Laboratory (JPL) was busy developing the first ever wheeled robot that would roam the surface of Mars. Due to the long round-trip times of any signals between Mars and Earth, development of the firmware that would control the rover was a major point, with the two teams occupied with the task each picking different levels of autonomy for the rover. In a retrospective, [Ron Garrett] who worked at JPL on the ‘more autonomy’ team describes his recollections.

Whereas [Ron]’s team focused on creating a rover that could be provided with high-level instructions which the sophisticated LISP-based firmware would use as guidelines to navigate and operate by, the other team pursued a more limited autonomy approach whereby a human driver would use explicitly plan out the route which the rover would follow before awaiting new instructions.

Perhaps unsurprisingly, the system requirements for running LISP and the additional uncertainties and complexities with the autonomous approach, as well as testing and validating the firmware, resulted in the Sojourner Mars rover featuring the latter approach, with straightforward C-based firmware. Most of Sojourner’s autonomy was limited to a home return function if communication with the lander was lost, which limited both its range and operations during its 85-day extended mission.

As [Ron] covers with examples from later missions, one advantage of LISP is that it allows you to send instructions which can be interpreted (e.g. to debug the system) without having to program in such functionality explicitly. With later Mars rover missions much more of this autonomy that [Ron]’s team pioneered was implemented, although C remained the language of choice for these later rovers.

Heading image: Ron Garrett standing in front of the Robbie prototype. Rocky III can be see in the lower left, and above him are Rajiv Desai and Robert Ivlev, two other members of the team. (Credit: Ron Garret)

Repairing A Home Injection Molding Machine

August 5, 2023 by Maya Posch 10 Comments

When [Michael] over at the Teaching Tech YouTube channel bought a hobby injection molding machine a long time ago, one of the plans he had with it was to use it for grinding up waste bits of PLA filament for injection molding. Since the machine was bought from a US shop and [Michael] is based in Australia it required some modifications to adapt it to the local 220+ VAC mains, followed by adding a PID temperature controller and a small compressor to provide the compressed air rather than from a large shop compressor.

Although [Michael] had discussed using the machine for PLA with the seller to confirm that this would work, a user error meant that the now defective unit had been sitting idly for many years, until recently.

Since the machine had been gathering dust and rust in the garage, fixing the machine up took a complete teardown to remove corrosion and resolve other issues. After this the original fault was identified, which turned out to be a shorted wire near the heater which had been turned up to a too high temperature, leading to the release of magic smoke and banishment of the machine to the Pit of Despair, AKA the shadowy depths of one’s garage.

In this first installment, [Michael] cleaned up the machine and restored it to a working state. In the next part injection molding will be attempted again, which should give some idea of the feasibility of turning scraps of PLA and failed 3D prints into smooth injection molded parts, assuming you have the CNC machine or patience to carve out the requisite molds, of course.

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