Chemistry

115 Articles

Lithium: What Is It And Do We Have Enough?

November 30, 2020 by 138 Comments

Lithium (from Greek lithos or stone) is a silvery-white alkali metal that is the lightest solid element. Just one atomic step up from Helium, this magic metal seems to be in everything these days. In addition to forming the backbone of many kinds of batteries, it also is used in lubricants, mood-stabilizing drugs, and serves as an important additive in iron, steel, and aluminum production. Increasingly, the world is looking to store more and more power as phones, solar grids, and electric cars continue to rise in popularity, each equipped with lithium-based batteries. This translates to an ever-growing need for more lithium. So far production has struggled to keep pace with demand. This leads to the question, do we have enough lithium for everyone?

It takes around 138 lbs (63 kg) of 99.5% pure lithium to make a 70 kWh Tesla Model S battery pack. In 2016, OICA estimated that the world had 1.3 billion cars in use. If we replace every car with an electric version, we would need 179 billion pounds or 89.5 million tons (81 million tonnes) of lithium. That’s just the cars. That doesn’t include smartphones, laptops, home power systems, massive grid storage projects, and thousands of other products that use lithium batteries.

In 2019 the US Geological Survey estimated the world reserves of identified lithium was 17 million tonnes. Including the unidentified, the estimated total worldwide lithium was 62 million tonnes. While neither of these estimates is at that 89 million ton mark, why is there such a large gap between the identified and estimated total? And given the general rule of thumb that the lighter a nucleus is, the more abundant the element is, shouldn’t there be more lithium reserves? After all, the US Geological Survey estimates there are around 2.1 billion tonnes of identified copper and an additional 3.5 billion tonnes that have yet to be discovered. Why is there a factor of 100x separating these two elements?

Continue reading “Lithium: What Is It And Do We Have Enough?” →

A 3D Printed Magnetic Stirrer For Your DIY Chemistry Projects

September 3, 2020 by 20 Comments

When mixing or agitating delicate solutions in the chemistry lab, a magnetic stirrer is often the tool of choice. They’re able to be easily sterilized and cleaned, while maintaining isolation between the mechanical parts and the solutions in question. While they can be purchased off the shelf, [Max Siebenschläfer] whipped up a design that can easily be built at home.

The build consists of a 3D printed base, containing a simple brushed motor. This is hooked up to a motor controller fitted with a simple potentiometer for adjusting the speed of rotation. The motor is then fitted with a small 3D printed spinner containing two magnets. A similar 3D printed part acts as a stirrer, and is fitted with a matching pair of magnets, and dropped into the solution. The magnets in the stirrer are attracted to the ones on the end of the motor, and so when the motor spins, the stirrer spins in the solution, with no physical contact required.

It’s a simple way to build a magnetic stirrer at home without having to shell out big money for a laboratory grade unit. We imagine this could be put to fun use for stirring coffee or cocktails, too – if built with a food-grade spinner. More advanced designs are also possible for the eager home scientist. Video after the break.

Continue reading “A 3D Printed Magnetic Stirrer For Your DIY Chemistry Projects” →

Jan Czochralski And The Silicon Revolution

July 22, 2020 by 39 Comments

If you were to travel back in time to the turn of the previous century and try to convince the average person that the grains of sand on just about any beach would be the basis of an industry worth hundreds of billions of dollars within 100 years, they’d probably have thought you were crazy. Aside from being coarse, rough, and irritating, sand is everywhere, and convincing anyone of its value would be a hard sell, unless your interlocutor was a real estate visionary with an appreciation of the future value of seaside property and a lot of patience.

Fast forward to our time, and we all know the value of the material that comes from common quartz sand: silicon, specifically the ultra-purified crystals of silicon that end up as the wafers we depend on to build the circuitry of life. The trip from beach to chip foundry is a long and non-obvious one which would not have been possible without the insights of an undistinguished Polish student and one-time druggist who discovered the process that made the Information Age possible: Jan Czochralski.

Continue reading “Jan Czochralski And The Silicon Revolution” →

Compile A Hydroponics System From Source

June 16, 2020 by 18 Comments

Tending to a garden is usually a rewarding endeavor, as long as there is good soil to work with. If there isn’t, it can either get frustrating quickly having to deal with soils like sand or hard clay, or it can get expensive by having to truck in compost each year. Alternatively, it’s possible to set up systems of growing plants that don’t need any soil at all, although this requires an automated system otherwise known as hydroponics to manage water and nutrients sent to the plants.

This setup by [Kyle] is unique in that it uses his own open-source software which he calls Mycodo to control the hydroponic system. It is loaded onto a Raspberry Pi 4 (which he notes can now be booted from a USB drive instead of an SD card) which controls all of the peripherals needed for making sure that the water has the correct amount of nutrients and chemical composition.

The build is much more than just a software control panel, though. [Kyle] walks through every part of setting up a small hydroponic system capable of effectively growing 15-20 plants indoors. He grows varieties of lettuce and basil, but this system can work for many more types of plants as well. With just slight variations, a similar system can not only grow plants like these, but fish as well.

Continue reading “Compile A Hydroponics System From Source” →

DIY Closed-Cell Silicone Foam

April 5, 2020 by 9 Comments

Most of us have a junk drawer, full of spare parts yanked from various places, but also likely stocked with materials we bought for a project but didn’t use completely. Half a gallon of wood glue, a pile of random, scattered resistors, or in [Ken]’s case, closed-cell silicone foam. Wanting to avoid this situation he set about trying to make his own silicone foam and had a great degree of success.

Commercial systems typically rely on a compressed gas of some sort to generate the foam. Ken also wanted to avoid this and kept his process simple by using basic (pun intended) chemistry to generate the bubbles. A mixture of vinegar and baking soda created the gas. After a healthy amount of trial and error using silicone caulk and some thinner to get the mixture correct, he was able to generate a small amount of silicone foam. While there only was a bit of foam, it was plenty for his needs. All without having a stockpile of extra foam or needing to buy any specialized equipment.

We appreciate this project for the ingenuity of taking something relatively simple (an acid-base reaction) and putting it to use in a way we’ve never seen before. While [Ken] doesn’t say directly on the project page what he uses the foam for, perhaps it or a similar type of foam could be used for building walk-along gliders.

Photo via Wikimedia Commons

Making Aerogel, It’s Not For The Faint-Hearted

April 3, 2020 by 12 Comments

Aerogel — that mixture of air and silica — is one of those materials that seems like a miracle. It is almost not there since the material is 99% air. [NileRed] wanted to make his own and he documented his work in a recent video you can see below.

If you decide to replicate his result, be careful with the tetramethyl orthosilicate. Here’s what he says about it:

And the best part is, that when it’s in your eyes, it gets under the surface, and the particles are way too small to remove. For this reason, you could go permanently blind.

It can also mess up your lungs, so you probably need a vent hood to really work with this. It isn’t cheap, either. The other things you need are easier to handle: methanol, distilled water, and ammonia.

Continue reading “Making Aerogel, It’s Not For The Faint-Hearted” →

Using Additives For Better Performing Epoxy

March 17, 2020 by 13 Comments

Epoxy resins are an important material in many fields. Used on their own as an adhesive, used as a coating, or used in concert with fiber materials to make composites, their high strength and light weight makes them useful in many applications. [Tech Ingredients] decided to explore how combining basic epoxy resin with various additives can make it perform better in different roles.

The video primarily concerns itself with explaining different common additives to epoxy resin mixtures, and how they impact its performance. Adding wood flour is a great way to thicken epoxy, allowing it to form a bead when joining two surfaces. Microbeads are great to add if you’re looking to create a sandable filler. Other additive like metal powders lend the mixture resistance to degradation from UV light, while adding dendritic copper creates a final product with high thermal conductivity.

The video does a great job of not only explaining the additives and their applications, but also shares a few handy tips on best workshop practices. Things like triple-gloving and observing proper mixing order can make a big difference to your workflow and lead to better results.

We’ve seen practical applications of epoxy mixes before – with epoxy granite being a particularly popular material. Video after the break.

Continue reading “Using Additives For Better Performing Epoxy” →