Stylized silver text with the the word: "arpa-e" over the further text: "Changing What's Possible"

Uncle Sam Wants You To Recover Energy Materials From Wastewater

The U.S. Department of Energy’s (DOE) Advanced Research Projects Agency-Energy (ARPA-E) was founded to support moonshot projects in the realm of energy, with a portfolio that ranges from the edge of current capabilities to some pretty far out stuff. We’re not sure exactly where their newest “Notice of Funding Opportunity (NOFO)” falls, but they’re looking for critical materials from the wastewater treatment process. [via CleanTechnica]

As a refresher, critical materials are those things that are bottlenecks in a supply chain that you don’t want to be sourcing from unfriendly regions. For the electrification of transportation and industrial processes required to lower carbon emissions, lithium, cobalt, and other rare earth elements are pretty high on the list.

ARPA-E also has an interest in ammonia-based products which is particularly interesting as industrial fertilizers can wreak havoc on natural ecosystems when they become run off instead of making it into the soil. As any farmer knows, inputs cost money, so finding an economical way to recover those products from wastewater would be a win-win. “For all categories, the final recovered products will need to include at least two targeted high energy-value materials, have greater than 90% recovery efficiency, and be commercially viable in the U.S. market.” If that sounds like the sort of thing you’d like to try hacking on, consider filling out an Applicant Profile.

If you’re curious about where we’re getting some of these materials from right now, checkout our series on Mining and Refining, including the lithium and cobalt ARPA-E wants more of.

Mining And Refining: Uranium And Plutonium

When I was a kid we used to go to a place we just called “The Book Barn.” It was pretty descriptive, as it was just a barn filled with old books. It smelled pretty much like you’d expect a barn filled with old books to smell, and it was a fantastic place to browse — all of the charm of an old library with none of the organization. On one visit I found a stack of old magazines, including a couple of Popular Mechanics from the late 1940s. The cover art always looked like pulp science fiction, with a pipe-smoking father coming home from work to his suburban home in a flying car.

But the issue that caught my eye had a cover showing a couple of rugged men in a Jeep, bouncing around the desert with a Geiger counter. “Build your own uranium detector,” the caption implored, suggesting that the next gold rush was underway and that anyone could get in on the action. The world was a much more optimistic place back then, looking forward as it was to a nuclear-powered future with electricity “too cheap to meter.” The fact that sudden death in an expanding ball of radioactive plasma was potentially the other side of that coin never seemed to matter that much; one tends to abstract away realities that are too big to comprehend.

Things are more complicated now, but uranium remains important. Not only is it needed to build new nuclear weapons and maintain the existing stockpile, it’s also an important part of the mix of non-fossil-fuel electricity options we’re going to need going forward. And getting it out of the ground and turned into useful materials, including its radioactive offspring plutonium, is anything but easy.

Continue reading “Mining And Refining: Uranium And Plutonium”

Mining And Refining: Graphite

In my teenage years I worked for a couple of summers at a small amusement park as a ride operator. Looking back on it, the whole experience was a lot of fun, although with the minimum wage at $3.37 an hour and being subjected to the fickle New England weather that ranged from freezing rains to heat stroke-inducing tropical swelter, it didn’t seem like it at the time.

One of my assignments, and the one I remember most fondly, was running the bumper cars. Like everything else in the park, the ride was old and worn out, and maintenance was a daily chore. To keep the sheet steel floor of the track from rusting, every morning we had to brush on a coat of graphite “paint”. It was an impossibly messy job — get the least bit of the greasy silver-black goop on your hands, and it was there for the day. And for the first few runs of the day, before the stuff worked into the floor, the excited guests were as likely as not to get their shoes loaded up with the stuff, and since everyone invariably stepped on the seat of the car before sitting on it… well, let’s just say it was easy to spot who just rode the bumper cars from behind, especially with white shorts on.

The properties that made graphite great for bumper cars — slippery, electrically conductive, tenacious, and cheap — are properties that make it a fit with innumerable industrial processes. The stuff turns up everywhere, and it’s becoming increasingly important as the decarbonization of transportation picks up pace. Graphite is amazingly useful stuff and fairly common, but not all that easy to extract and purify. So let’s take a look at what it takes to mine and refine graphite.

Continue reading “Mining And Refining: Graphite”

Mining And Refining: Quartz, Both Natural And Synthetic

So far in this series, pretty much every material we’ve covered has had to undergo a significant industrial process to transform it from its natural state to a more useful product. Whether it’s the transformation of bauxite from reddish-brown clay to lustrous aluminum ingots, or squeezing solid sulfur out of oil and natural gas, there haven’t been many examples of commercially useful materials that are taken from the Earth and used in their natural state.

Quartz, though, is at least a partial exception to this rule. Once its unusual electrical properties were understood, crystalline quartz was sent directly from quarries and mines to factories, where they were turned into piezoelectric devices with no chemical transformation whatsoever. The magic of crystal formation had already been done by natural processes; all that was needed was a little slicing and dicing.

As it turns out, though, quartz is so immensely useful for a technological society that there’s no way for the supply of naturally formed crystals to match demand. Like copper before it, which was first discovered in natural metallic deposits that could be fashioned into tools and decorations more or less directly, we would need to discover different sources for quartz and invent chemical transformations to create our own crystals, taking cues from Mother Nature’s recipe book on the way.

Continue reading “Mining And Refining: Quartz, Both Natural And Synthetic”

Tiny Bitcoin Miner Plays The Lottery

Usually when we think of Bitcoin miners, we imagine huge facilities of server racks doing nothing but essentially wasting energy, all for the chance that one of those computers amongst the rows will stumble upon the correct set of numbers to get rewarded with imaginary money. The idea being that the more computers, the more chances to win. But just buying one lottery ticket is the only thing technically required to win, at least in theory. And [Data Slayer] is putting this theory to the test with this Bitcoin miner built around a single Raspberry Pi.

This tiny Raspberry Pi Zero does get a little bit of support from an Ant Miner, a USB peripheral which is optimized to run the SHA256 hashing algorithm and solve the complex mathematical operations needed to “win” the round of Bitcoin mining. Typically a large number of these would be arrayed together to provide more chances at winning (or “earning”, to use the term generously) Bitcoin but there’s no reason other than extreme statistical improbability that a single one can’t work on its own. The only other thing needed to get this setup working is to give the Pi all of the configuration information it needs such as wallet information and pool information.

This type of miner isn’t novel by any means, and in fact it’s a style of mining cryptocurrency called “lottery mining” where contributing to a pool is omitted in favor of attempting to solve the entire block by pure random chance alone in the hopes that if it’s solved, the entire reward will be claimed by that device alone. In the case of this device, the current hash rate calculated when it was contributing to a pool means that when lottery mining, it has about a one-in-two-billion chance of winning. That’s essentially zero, which is basically the same chance of winning a lottery that pays out actual usable currency.

Continue reading “Tiny Bitcoin Miner Plays The Lottery”

We Can’t Switch To Electric Cars Until We Get More Copper

Reducing emissions from human activity requires a great deal of effort in many different sectors. When it comes to land transport, the idea is generally to eliminate vehicles powered by combustion engines and replace them with electric vehicles instead. At a glance, the job is simple enough. We know how to build EVs, and the technology is getting to the point where they’re capable of replacing traditional vehicles in many applications.

Of course, the reality is not so simple. To understand the problem of converting transportation to electric drive en masse, you have to take a look at the big numbers. Focus in on the metrics of copper, and you’ll find the story is a concerning one. 

Continue reading “We Can’t Switch To Electric Cars Until We Get More Copper”

Mining And Refining: Lithium, Powering The Future With Brine

Many years ago, I read an article about the new hotness: lithium batteries. The author opened with what he no doubt thought was a clever pop culture reference by saying that the mere mention of lithium would “strike fear in the hearts of Klingons.” It was a weak reference to the fictional “dilithium crystals” of Star Trek fame, and even then I found it a bit cheesy, but I guess he had to lead with something.

Decades later, a deeper understanding of the lore makes it clear that a Klingon’s only fear is death with dishonor, but there is a species here on earth that lives in dread of lithium: CEOs of electric vehicle manufacturing concerns. For them, it’s not the presence of lithium that strikes fear, but the relative absence of it; while it’s the 25th most abundant element in the Earth’s crust, and gigatons are dissolved into the oceans of the world, lithium is very reactive and thus tends to be diffuse, making it difficult to obtain concentrated in the quantities their businesses depend on.

As the electric vehicle and renewable energy markets continue to grow, the need for lithium to manufacture batteries will grow with it, potentially to the point where demand outstrips the mining industry’s production capability. To understand how that imbalance may be possible, we’ll take a look at how lithium is currently mined, as well as examine some new mining techniques that may help fill the coming lithium gap.

Continue reading “Mining And Refining: Lithium, Powering The Future With Brine”