Recycling Tough Plastics Into Precursors With Some Smart Catalyst Chemistry

October 8, 2024 by Lewin Day 33 Comments

Plastics are unfortunately so cheap useful that they’ve ended up everywhere. They’re filling our landfills, polluting our rivers, and even infiltrating our food chain as microplastics. As much as we think of plastic as recyclable, too, that’s often not the case—while some plastics like PET (polyethylene terephthalate) are easily reused, others just aren’t.

Indeed, the world currently produces an immense amount of polyethylene and polypropylene waste. These materials are used for everything from plastic bags to milk jugs and for microwavable containers—and it’s all really hard to recycle. However, a team at UC Berkeley might have just figured out how to deal with this problem.

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3D Printing On Top Of Laser Cut Acrylic

September 24, 2024 by Dave Rowntree 8 Comments

[Julius Curt] needed to mark acrylic panels with a bit more clarity than the usual way of rastering the surface, so they attempted to 3D print directly to an acrylic sheet, which worked perfectly. The obvious way to do this was to bond the acrylic sheet to the bed with glue temporarily, but another way was tried, and it’s much less messy and precarious.

The bond between a 3D print and acrylic is very strong

The first step was to create a 3D model which combined a constraining ‘fence’ to contain the acrylic panel with the required artwork floating above. It was easy enough to run the print long enough to build the fence, then pause the print mid-way to add the pristine panel and restart after a quick re-prime and wipe.

There were a few simple takeaways from the video below. First, to ensure sufficient tolerance between the fence and the panel, consider the layer width (plus associated tolerance when printed) and the laser kerf of your machines to ensure a not-too-sloppy fit. Secondly, that hot nozzle won’t do the acrylic surface any favours during travel moves, so enabling Z-hopping is essential!

Another use for this simple technique is to fully incorporate an acrylic sheet within a print by pausing at an appropriate height again, dropping the panel in, and continuing the print. A degree of overlap will lock the panel tight, with the plastic bonding very firmly to the acrylic, as [Julius] demonstrates in the video.

It’s always a delight to see how techniques can combine to create the desired effects. Here’s how to use a color laser printer and toner transfer paper to apply designs to a 3D printing front panel. Whilst we’re thinking about the multitude of uses for hacking with acrylic, what about not doing that and using corrugated plastic instead?

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Fighting The Scourge Of “Screwdriver Mange”

August 16, 2024 by Dan Maloney 45 Comments

We’ve all got our favorite hand tools, and while the selection criteria are usually pretty subjective, it usually boils down to a combination of looks and feel. In our opinion, the king of both these categories when it comes to screwdrivers is those clear, hard acetate plastic handles, which are a joy to use — at least until the plastic starts to degrade and exude a characteristically funky aroma.

But perhaps we can change that if these experiments on screwdriver “mange” hold up. That’s [357magdad]’s unappealing but accurate description of the chemical changes that eventually occur in the strong, hard, crystal-clear handles of your favorite screwdrivers. The polymer used for these handles is cellulose acetate butyrate, or CAB, which is mostly the same cellulose acetate that replaced the more explode-y cellulose nitrate in things like pool balls and movie film, except with some of the acetate groups replaced with a little butyric acid. The polymer is fine at first, but add a little UV light and over time the outer layer of CAB decomposes into a white flaky cellulose residue while the butyric acid volatilizes, creating the characteristic odor of vomitus. Lovely.

In the video below, [357magdad] takes a look at different concoctions that all allegedly cure the mange. TL, DW; it was a dunk in household ammonia that performed the best, well ahead of other common agents like vinegar and bleach. The ammonia — or more precisely, ammonium hydroxide — works very quickly on the cellulose residue, dissolving it readily and leaving the handle mange-free and looking nearly new after some light scrubbing. None of the other agents came close, although acetone did manage to clear up the mange a bit, at the cost of softening the underlying CAB in a process that’s probably similar to acetone smoothing ABS prints.

As for the funky smell, well, the results were less encouraging. Nothing really got rid of the pukey smell, even a roll in baking soda. We suspect there won’t be much for that, since humans can detect it down to 10 parts per million. Consider it the price to pay for a nice-looking screwdriver that feels so good in your hand. Continue reading “Fighting The Scourge Of “Screwdriver Mange”” →

Lasers Could Help Us Recycle Plastics Into Carbon Dots

July 18, 2024 by Lewin Day 17 Comments

As it turns out, a great deal of plastics are thrown away every year, a waste which feels ever growing. Still, as reported by Sci-Tech Daily, there may be help on the way from our good friend, the laser!

The research paper from the University of Texas outlines the use of lasers for breaking down tough plastics into their baser components. The method isn’t quite as simple as fire a laser off at the plastic, though. First, the material must be laid on a special two-dimensional transition metal dichalcogenide material — a type of atomically-thin semiconductor at the very forefront of current research. When the plastics are placed under the right laser light in this scenario, carbon-hydrogen bonds in the plastic are broken and transformed, creating new chemical bonds. Done right, and you can synthesize luminescent carbon dots from the plastic itself!

“By harnessing these unique reactions, we can explore new pathways for transforming environmental pollutants into valuable, reusable chemicals, contributing to the development of a more sustainable and circular economy,” says Yuebing Zheng, a leader on the project. “This discovery has significant implications for addressing environmental challenges and advancing the field of green chemistry.”

Sure it’s a bit trickier than turning old drink bottles into filament, but it could be very useful to researchers and those investigating high-tech materials solutions. Don’t forget to read up on the sheer immensity of the world’s plastic recycling problems, either. If you’ve got the solution, let us know!

A red hot crucible is held with metal tongs above a white plaster mold. The mold is held in a bright pink silicone sleve atop a metal pan on a wooden workbench. Red cheese wax holds the sleeve to a metal funnel connected to a vacuum cleaner.

Lost Print Vacuum Casting In A Microwave

March 2, 2024 by Navarre Bartz 16 Comments

Hacks are rough around the edges by their nature, so we love it when we get updates from makers about how they’ve improved their process. [Denny] from Shake the Future has just provided an update on his microwave casting process.

Sticking metal in a microwave certainly seems like it would be a bad idea at first, but with the right equipment it can work quite nicely to develop a compact foundry. [Denny] walks us through the process start to finish in this video, including how to build the kilns, what materials to use, and how he made several different investment castings using the process. The video might be worth watching just for all the 3D printed tools he’s built to aid in the process — it’s a great example of useful 3D prints to accompany your fleet of little plastic boats.

A lot of the magic happens with a one minute on and six minutes off cycle set by a simple plug timer. This allows a more gradual ramp to burn out the PLA or resin than running the microwave at full blast which can cause some issues with the kiln, although nothing catastrophic as demonstrated. Vacuum is applied to the mold with a silicone sleeve cut from a swimming cap while pouring the molten metal into the mold to draw the metal into the cavities and reduce imperfections.

We appreciate the shout out to respirators while casting or cutting the ceramic fiber mat. Given boric acid’s effects, [PDF] you might want to use safety equipment when handling it as well or just use water as that seems like a valid option.

If you want to see where he started check out this earlier version of the microwave kiln and how he used it to make an aluminum pencil.

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Common Enzyme Breaks Down PLA Fast

February 4, 2024 by Lewin Day 50 Comments

The global issue of plastic waste has prompted scientists to seek innovative solutions for recycling. Single-use plastics, notorious for their environmental impact, require new methods for efficient and sustainable management. For some common plastics, though, salvation could be at hand, with researchers identifying a common enzyme that can be used to break them down fast.

Researchers at King’s College London have discovered an enzyme used in laundry detergents that can break down PLA plastics within 24 hours, using a little heat as an aid. Normally, this is achieved via composting methods that take weeks or months. This method transforms the plastics back into their original chemical components, offering a rapid and eco-friendly recycling process. The monomers can then be reused for manufacturing new plastic items.

One wonders if this could also be used in another way – perhaps in a multimaterial printer, allowing PLA to be used for supports and then broken down. It’s probably not that necessary, given other degradable materials exist, but it’s something to think about.

This project is a significant leap forward in recycling technology, showcasing the potential for enzymes to revolutionize how we handle plastic waste. It could also be a great way to recycle all those errant deformed Pikachus that keep ending up in your hackerspace’s 3D-printing waste basket. In any case, plastic waste is a problem the world needs to solve, and quickly, because it’s not going anywhere any time soon. Video after the break.

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Diesel Station Wagon Runs On Plastic

November 15, 2023 by Bryan Cockfield 58 Comments

Old diesel engines from various car manufacturers like Mercedes and Volkswagen are highly prized even in modern times. Not only were these engines incredibly reliable and mechanically simple, but they can easily be modified to run on a wide variety of fuels. It’s common to see old Volkswagen Jettas or Mercedes 300Ds running on used vegetable oil or any other free flammable liquid that might otherwise end up in the garbage. [Gijs Schalkx] has an diesel Volvo 240 wagon, and rather than compete with all the other diesel owners looking for cooking oil, he modified this one to run on plastic waste instead. (Google Translate from Dutch)

While our Dutch language skills aren’t the best, what we gather about this project is that it uses standard solid plastic waste for fuel, but an intermediate step of cooking the plastic into a liquid is first needed. The apparatus on the roof is actually a plastic refinery which uses a small wood fire to break the plastic molecules into usable hydrocarbons, which are then sent to the engine for burning. The car is street legal and seems to operate like any other diesel of this vintage, although the fuel delivery system may not be able to provide it enough to get it going at very high speeds.

While it is possible to use wood to produce wood gas for fuel in an internal combustion engine like this wood gas-powered lawnmower, the hydrocarbon strings in plastic are essentially stabilized hydrocarbons from refining oil and have potentially much more available energy. Releasing this energy is generally difficult enough that used plastic is simply landfilled. [Gijs Schalkx] has made plenty of alternative fuel vehicles, too, like this moped that used locally-harvested swamp gas to ride around town.

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