Supercapacitors rely mostly on double-layer capacitance to bridge the divide between chemical batteries and traditional capacitors, but they come with a number of weaknesses. Paramount among these are their relatively low voltage of around 2.7 V before their electrolyte begins to decompose, as well as their relatively high rates of self-discharge. Here a new design using lignin-derived porous carbon electrodes and a fluorinated diluent was demonstrated by [Shichao Zhang] et al., as published in Carbon Research, that seems to address these issues.
Most notable are the relatively high voltage of 4 V, an energy density of 77 Wh/kg and a self-discharge rate that’s much slower than that of conventional supercapacitors. In comparison with these supercapacitors, these demonstrated versions are also superior in terms of recharge cycles with 90% of capacity remaining after 10,000 cycles, which together with their much higher energy density should prove to be quite useful.
This feat is accomplished by using lignin as the base for the carbon electrodes to make a highly porous surface, along with the new electrolyte formulation consisting of alithium salt (LiBF4) dissolved in sulfolane with TTE as a non-solvating diluent. The idea of using lignin-derived carbon for such a purpose has previously been pitched by [Jia Liu] et al. in 2022 and [Zhihao Ding] in 2025, with this seemingly one of the first major applications we may be seeing.
Although the path towards commercialization from a lab-assembled prototype is a rough one, we may be seeing some of these improvements come to supercapacitors near you sooner rather than later.
