chemistry hacks

644 Articles

holding up the flavor stone

An Infinity Gem That Didn’t Make The Cut, The Flavor Stone

March 5, 2022 by 26 Comments

MSG (Monosodium Glutamate) is a flavor enhancer used to add a meaty/savory (often called umami) flavor to a dish. You might even have some in your pantry (though more likely it is in something that is in your pantry). What you might not know is that you can grow it into a large crystal.

[Chase] does an excellent job walking through the details of the process. MSG is one of the many common household substances that can grow into a crystal such as table salt, alum, fertilizer, sugar, or Epsom salt to name a few. The idea is quite simple —  just create a supersaturated solution with your desired crystal material and then suspend a string in it; but the execution has some nuance. To create a medium that’s super saturated, heat some water and mix in equal parts of MSG. Then let it cool once it has all dissolved and split it into two parts, one big and one small. You need to create a seed crystal, so place the small solution in a shallow dish and let a crystal percolate out over the new few days. You attach one of the seed crystals that grow to a string and suspend it in your solution. There are several gotchas around how to properly harvest the crystals but [Chase] enumerates them for you.

We’ve covered [Chase’s] efforts before when he grew crystals out of Rust. He is on a quest to grow all five flavor stones: salty, sweet, sour, umami, and bitter and we wish him all the best. What we would also love to see is the whole process of MSG from start to finish, making your own MSG.

Neon, Ukraine, And The Global Semiconductor Industry

February 27, 2022 by 34 Comments

On our news feeds and TV channels at the moment are many stories concerning the war in Ukraine, and among them is one which may have an effect on the high-tech industries. It seems that a significant percentage of the world’s neon gas is produced in Ukrainian factories, and there is concern among pundits and electronics manufacturers that a disruption of this supply could be a further problem for an industry already reeling from the COVID-related chip shortage. It’s thus worth taking a quick look at the neon business from an engineering perspective to perhaps make sense of some of those concerns.

As most readers will know from their high school chemistry lessons, neon is one of the so-called inert gasses, sitting in the column at the extreme right of the Periodic table. It occurs in nature as a small percentage of the air we breathe and is extracted from the air by fractional distillation of the liquid phase. The important point from the above sentences is that the same neon is all around us in the air as there is in Ukraine, in other words, there is no strategic neon mine in the Ukrainian countryside about to be overrun by the Russian invaders.

So why do we source so much neon from Ukraine, if we’re constantly breathing the stuff in and out everywhere else in the world? Since the air separation industry is alive and well worldwide for the production of liquid nitrogen and oxygen as well as the slightly more numerous inert gasses, we’re guessing that the answer lies in economics. It’s a bit harder to extract neon from air than it is argon because there is less of it in the air. Since it can be brought for a reasonable cost from the Ukrainians who have made it their business to extract it, there is little benefit in American or Western European companies trying to compete. Our take is that if the supply of Ukrainian neon is interrupted there may be a short period of neon scarcity. After that, air extraction companies will quite speedily install whatever extra plant they need in order to service the demand. If that’s your area of expertise, we’d love to hear from you in the comments.

Here at Hackaday we are saddened beyond words at what has happened in Ukraine, and we hope our Ukrainian readers and those Ukrainian hackers whose work we’ve featured make it through safely. We sincerely hope that this madness can be ended and that we can mention the country in the context of cool hacks again rather than war.

If you are interested in the strategic value of inert gasses, have a read about the global helium supply.

Header image: Lestat (Jan Mehlich), CC BY-SA 3.0.

Grocery Store Rocket Fuel: Don’t Try This At Home!

February 25, 2022 by 29 Comments

It seems like whenever the topic of rocket science comes up, the conversation quickly shifts to that of rocket fuels. As discussed in the excellent [Scott Manley] video below the break, there are many rocket fuels that can be found in some way, state, or form at your local grocery or liquor store. The video itself is a reaction to some college students in Utah who caused an evacuation when the rocket fuel they were cooking up exploded.

[Scott] himself theorizes that the fuel they were cooking was Rocket Candy, a volatile mix of sugar and potassium nitrate that is known to go Kaboom on occasion. And as it turns out, the combination might not even be legal in your area because as much as it can be used as rocket fuel, it can also be used for other things that go boom.

So, what else at your local megamart can be used to get to orbit? [Scott] talks about different kinds of alcohols, gasses, cleaners- all things that can be used as rocket fuel. He also talks about all of the solid reasons you don’t want to do this at home.

If this type of things gets your molecules excited, you might enjoy a bit we posted recently about using another grocery store staple to save Martian colonists from being held back by gravity.

Big Chemistry: From Gasoline To Wintergreen

February 22, 2022 by 18 Comments

Most of us probably have some vivid memories of high school or college chemistry lab, where the principles of the science were demonstrated, and where we all got at least a little practice in experimental methods. Measuring, diluting, precipitating, titrating, all generally conducted under safe conditions using stuff that wasn’t likely to blow up or burn.

But dropwise additions and reaction volumes measured in milliliters are not the stuff upon which to build a global economy that feeds, clothes, and provides for eight billion people. For chemistry to go beyond the lab, it needs to be scaled up, often to a point that’s hard to conceptualize. Big chemistry and big engineering go hand in hand, delivering processes that transform the simplest, most abundant substances into the things that, for better or worse, make life possible.

To get a better idea of how big chemistry does that, we’re going to take a look at one simple molecule that we’ve probably all used at one time or another: the common artificial flavoring wintergreen. It’s an innocuous ingredient in a wide range of foods and medicines, but the infrastructure required to make it and all its precursors is a snapshot of just how important big chemistry really is.

Continue reading “Big Chemistry: From Gasoline To Wintergreen” →

Mining And Refining: Lithium, Powering The Future With Brine

February 9, 2022 by 28 Comments

Many years ago, I read an article about the new hotness: lithium batteries. The author opened with what he no doubt thought was a clever pop culture reference by saying that the mere mention of lithium would “strike fear in the hearts of Klingons.” It was a weak reference to the fictional “dilithium crystals” of Star Trek fame, and even then I found it a bit cheesy, but I guess he had to lead with something.

Decades later, a deeper understanding of the lore makes it clear that a Klingon’s only fear is death with dishonor, but there is a species here on earth that lives in dread of lithium: CEOs of electric vehicle manufacturing concerns. For them, it’s not the presence of lithium that strikes fear, but the relative absence of it; while it’s the 25th most abundant element in the Earth’s crust, and gigatons are dissolved into the oceans of the world, lithium is very reactive and thus tends to be diffuse, making it difficult to obtain concentrated in the quantities their businesses depend on.

As the electric vehicle and renewable energy markets continue to grow, the need for lithium to manufacture batteries will grow with it, potentially to the point where demand outstrips the mining industry’s production capability. To understand how that imbalance may be possible, we’ll take a look at how lithium is currently mined, as well as examine some new mining techniques that may help fill the coming lithium gap.

Continue reading “Mining And Refining: Lithium, Powering The Future With Brine” →

An snowy city street.

The Road Is Peppered With Rock Salt Alternatives

January 25, 2022 by 79 Comments

Every winter, millions of tons of rock salt is sprinkled across roads in the US, mostly in the Midwest and Northeast regions. It’s a cheap and effective way to prevent accidents. Rock salt is chemically the same as the stuff that sits next to the pepper, except it isn’t as finely ground, and it doesn’t have sodium or potassium iodine added to it to prevent goiters. Both table salt and rock salt melt ice by lowering the freezing point of water. So does sugar.

Much of what we salt the Earth with every winter comes from underground networks of salt crystal that formed when various ancient seas dried up. As natural as it may be, rock salt is bad for the environment. For one thing, chloride is forever, and can’t easily be decoupled from the soil and water it taints when it washes away. Rock salt also corrodes concrete, makes its way into the groundwater, and is bad for pets. Worst of all, its efficacy drops along with the temperature. At 15° F (-9° C), rock salt loses more than 86% of its melting power.

Disposable Detroit

All this salt is not great for cars, either — it’s bad for the paint and eats up the frame. In the saltiest parts of the US, aka The Salt Belt, cars only last a handful of years before they become Flintstones mobiles. Well, not really, but salt is terrible for the brake lines and most of the undercarriage. Consumer woes aside, there’s a real environmental impact to manufacturing all these disposable cars to meet the demand.

But the problem is that we need to use salt, or at something like it. Even though millions of people are staying home a whole lot more, the trucking industry still relies on salted highways and local roads. So if you like stocked grocery stores and stuff arriving from the Bezos Barn in a timely fashion, you can see the problem. So what are the alternatives? Are there any?

Continue reading “The Road Is Peppered With Rock Salt Alternatives” →

suspended carbon nanotube

Falling Down The Carbon Rabbit Hole

January 11, 2022 by 18 Comments

Research projects have a funny way of getting blown out of proportion by the non-experts, over-promising the often relatively small success that the dedicated folks doing the science have managed to eke out. Scaling-up cost-effectively is one of the biggest killers for commercializing research, which is why recent developments in creating carbon nanotube transistors have us hopeful.

Currently, most cutting-edge processes use FETs (Field Effect Transistors). As they’ve gotten smaller, we’ve added fins and other tricks to get around the fact that things get weird when they’re small. The industry is looking to move to GAAFETs (Gate All Around FET) as Intel and Samsung have declared their 3 nm processes (or equivalent) will use the new type of gate. As transistors have shrunk, the “off-state” leakage current has grown. GAAFETs are multi-gate devices, allowing better control of that leakage, among other things.

As usual, we’re already looking at what is past 3 nm towards 2 nm, and the concern is that GAAFET won’t scale past 3 nm. Carbon Nanotubes are an up-and-coming technology as they offer a few critical advantages. They conduct heat exceptionally well, exhibit higher transconductance, and conduct large amounts of power. In addition, they show higher electron mobility than conventional MOSFETs and often outperform them with less power even while being at larger sizes. This is all to say that they’re an awesome piece of tech with a few caveats. Continue reading “Falling Down The Carbon Rabbit Hole” →