Big Chemistry: Cement And Concrete

Not too long ago, I was searching for ideas for the next installment of the “Big Chemistry” series when I found an article that discussed the world’s most-produced chemicals. It was an interesting article, right up my alley, and helpfully contained a top-ten list that I could use as a crib sheet for future articles, at least for the ones I hadn’t covered already, like the Haber-Bosch process for ammonia.

Number one on the list surprised me, though: sulfuric acid. The article stated that it was far and away the most produced chemical in the world, with 36 million tons produced every year in the United States alone, out of something like 265 million tons a year globally. It’s used in a vast number of industrial processes, and pretty much everywhere you need something cleaned or dissolved or oxidized, you’ll find sulfuric acid.

Staggering numbers, to be sure, but is it really the most produced chemical on Earth? I’d argue not by a long shot, when there’s a chemical that we make 4.4 billion tons of every year: Portland cement. It might not seem like a chemical in the traditional sense of the word, but once you get a look at what it takes to make the stuff, how finely tuned it can be for specific uses, and how when mixed with sand, gravel, and water it becomes the stuff that holds our world together, you might agree that cement and concrete fit the bill of “Big Chemistry.”

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Optical Contact Bonding: Where The Macro Meets The Molecular

If you take two objects with fairly smooth surfaces, and put these together, you would not expect them to stick together. At least not without a liberal amount of adhesive, water or some other substance to facilitate a temporary or more permanent bond. This assumption gets tossed out of the window when it comes to optical contact bonding, which is a process whereby two surfaces are joined together without glue.

The fascinating aspect of this process is that it uses the intermolecular forces in each surface, which normally don’t play a major role, due to the relatively rough surfaces. Before intermolecular forces like Van der Waals forces and hydrogen bonds become relevant, the two surfaces should not have imperfections or contaminants on the order of more than a few nanometers. Assuming that this is the case, both surfaces will bond together in a way that is permanent enough that breaking it is likely to cause damage.

Although more labor-intensive than using adhesives, the advantages are massive when considering that it creates an effectively uninterrupted optical interface. This makes it a perfect choice for especially high-precision optics, but with absolutely zero room for error.

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What Happened To WWW.?

Once upon a time, typing “www” at the start of a URL was as automatic as breathing. And yet, these days, most of us go straight to “hackaday.com” without bothering with those three letters that once defined the internet.

Have you ever wondered why those letters were there in the first place, and when exactly they became optional? Let’s dig into the archaeology of the early web and trace how this ubiquitous prefix went from essential to obsolete.

Where Did You Go?

The first website didn’t bother with any of that www. nonsense! Credit: author screenshot

It may shock you to find out that the “www.” prefix was actually never really a key feature or necessity at all. To understand why, we need only contemplate the very first website, created by Tim Berners-Lee at CERN in 1990. Running on a NeXT workstation employed as a server, the site could be accessed at a simple URL: “http//info.cern.ch/”—no WWW needed. Berners-Lee had invented the World Wide Web, and called it as such, but he hadn’t included the prefix in his URL at all. So where did it come from? Continue reading “What Happened To WWW.?”

Libogc Allegations Rock Wii Homebrew Community

Historically, efforts to create original games and tools, port over open source emulators, and explore a game console’s hardware and software have been generally lumped together under the banner of “homebrew.” While not the intended outcome, it’s often the case that exploring a console in this manner unlocks methods to run pirated games. For example, if a bug is found in the system’s firmware that enables a clever developer to run “Hello World”, you can bet that the next thing somebody tries to write is a loader that exploits that same bug to play a ripped commercial game.

But for those who are passionate about being able to develop software for their favorite game consoles, and the developers who create the libraries and toolchains that make that possible, the line between homebrew and piracy is a critical boundary. The general belief has always been that keeping piracy at arm’s length made it less likely that the homebrew community would draw the ire of the console manufacturers.

As such, homebrew libraries and tools are held to a particularly high standard. Homebrew can only thrive if developed transparently, and every effort must be taken to avoid tainting the code with proprietary information or code. Any deviation could be the justification a company like Nintendo or Sony needs to swoop in.

Unfortunately, there are fears that covenant has been broken in light of multiple allegations of impropriety against the developers of libogc, the C library used by nearly all homebrew software for the Wii and GameCube. From potential license violations to uncomfortable questions about the origins of the project, there’s mounting evidence that calls the viability of the library into question. Some of these allegations, if true, would effectively mean the distribution and use of the vast majority of community-developed software for both consoles is now illegal.

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Why Physical Media Deserved To Die

Over the course of more than a decade, physical media has gradually vanished from public view. Once computers had an optical drive except for ultrabooks, but these days computer cases that even support an internal optical drive are rare. Rather than manuals and drivers included on a data CD you now get a QR code for an online download. In the home, DVD and Blu-ray (BD) players have given way to smart TVs with integrated content streaming apps for various services. Music and kin are enjoyed via smart speakers and smart phones that stream audio content from online services. Even books are now commonly read on screens rather than printed on paper.

With these changes, stores selling physical media have mostly shuttered, with much audiovisual and software content no longer pressed on discs or printed. This situation might lead one to believe that the end of physical media is nigh, but the contradiction here comes in the form of a strong revival of primarily what used to be considered firmly obsolete physical media formats. While CD, DVD and BD sales are plummeting off a cliff, vinyl records, cassette tapes and even media like 8-track tapes are undergoing a resurgence, in a process that feels hard to explain.

How big is this revival, truly? Are people tired of digital restrictions management (DRM), high service fees and/or content in their playlists getting vanished or altered? Perhaps it is out of a sense of (faux) nostalgia?

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Which Browser Should I Use In 2025?

Over the history of the Web, we have seen several major shifts in browsing software. If you’re old enough to have used NCSA Mosaic or any of the other early browsers, you probably welcomed the arrival of Netscape Navigator, and rued its decline in the face of Internet Explorer. As Mozilla and then Firefox rose from Netscape’s corpse the domination by Microsoft seemed inevitable, but then along came Safari and then Chrome.

For a glorious while there was genuine competition between browser heavyweights, but over the last decade we’ve arrived at a point where Chrome and its associated Google domination is the only game in town. Other players are small, and the people behind Firefox seem hell-bent on fleeing to the Dark Side, so where should we turn? Is there a privacy-centric open source browser that follows web standards and doesn’t come with any unfortunate baggage in the room? It’s time to find out. Continue reading “Which Browser Should I Use In 2025?”

Australia’s Steady March Towards Space

The list of countries to achieve their own successful orbital space launch is a short one, almost as small as the exclusive club of states that possess nuclear weapons. The Soviet Union was first off the rank in 1957, with the United States close behind in 1958, and a gaggle of other aerospace-adept states followed in the 1960s, 1970s, and 1980s. Italy, Iran, North Korea and South Korea have all joined the list since the dawn of the new millennium.

Absent from the list stands Australia. The proud island nation has never stood out as a player in the field of space exploration, despite offering ground station assistance to many missions from other nations over the years. However, the country has continued to inch its way to the top of the atmosphere, establishing its own space agency in 2018. Since then, development has continued apace, and the country’s first orbital launch appears to be just around the corner.

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