Big Chemistry: Fuel Ethanol

May 21, 2025 by Dan Maloney 65 Comments

If legend is to be believed, three disparate social forces in early 20th-century America – the temperance movement, the rise of car culture, and the Scots-Irish culture of the South – collided with unexpected results. The temperance movement managed to get Prohibition written into the Constitution, which rankled the rebellious spirit of the descendants of the Scots-Irish who settled the South. In response, some of them took to the backwoods with stills and sacks of corn, creating moonshine by the barrel for personal use and profit. And to avoid the consequences of this, they used their mechanical ingenuity to modify their Fords, Chevrolets, and Dodges to provide the speed needed to outrun the law.

Though that story may be somewhat apocryphal, at least one of those threads is still woven into the American story. The moonshiner’s hotrod morphed into NASCAR, one of the nation’s most-watched spectator sports, and informed much of the car culture of the 20th century in general. Unfortunately, that led in part to our current fossil fuel predicament and its attendant environmental consequences, which are now being addressed by replacing at least some of the gasoline we burn with the same “white lightning” those old moonshiners made. The cost-benefit analysis of ethanol as a fuel is open to debate, as is the wisdom of using food for motor fuel, but one thing’s for sure: turning corn into ethanol in industrially useful quantities isn’t easy, and it requires some Big Chemistry to get it done.
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Producing Syngas From CO2 And Sunlight With Direct Air Capture

March 21, 2025 by Maya Posch 17 Comments

The prototype DACCU device for producing syngas from air. (Credit: Sayan Kar, University of Cambridge)

There is more carbon dioxide (CO₂) in the atmosphere these days than ever before in human history, and while it would be marvelous to use these carbon atoms for something more useful, capturing CO₂ directly from the air isn’t that easy. After capturing it would also be great if you could do something more with it than stuff it into a big hole. Something like producing syngas (CO + H₂) for example, as demonstrated by researchers at the University of Cambridge.

Among the improvements claimed in the paper as published in Nature Energy for this direct air capture and utilization (DACCU) approach are that it does not require pure CO₂ feedstock, but will adsorb it directly from the air passing over a bed of solid silica-amine. After adsorption, the CO₂ can be released again by exposure to concentrated light. Following this the conversion to syngas is accomplished by passing it over a second bed consisting of silica/alumina-titania-cobalt bis(terpyridine), that acts as a photocatalyst.

The envisioned usage scenario would be CO2 adsorption during the night, with concentrated solar power releasing it the day with subsequent production of syngas. Inlet air would be passed only over the adsorption section before switching the inlet off during the syngas generating phase. As a lab proof-of-concept it seems to work well, with outlet air stripped from virtually all CO₂ and very high conversion ratio from CO₂ to syngas.

Syngas has historically been used as a replacement for gasoline, but is also used as a source of hydrogen (e.g. steam reformation (SMR) of natural gas) where it’s used for reduction of iron ore, as well as the production of methanol as a precursor to many industrial processes. Whether this DACCU approach provides a viable alternative to SMR and other existing technologies will become clear once this technology moves from the lab into the real world.

Thanks to [Dan] for the tip.

An artist's depiction of a lystrosaurus munching on a prehistoric plant. It looks kind of like a hippo with a beak. The main body of the animal is grey-ish green and it's beak is ivory with two tusks jutting out from its top jaw.

Mammalian Ancestors Shed Light On The Great Dying

November 22, 2024 by Navarre Bartz 31 Comments

As we move through the Sixth Extinction, it can be beneficial to examine what caused massive die-offs in the past. Lystrosaurus specimens from South Africa have been found that may help clarify what happened 250 million years ago. [via IFLScience]

The Permian-Triassic Extinction Event, or the Great Dying, takes the cake for the worst extinction we know about so far on our pale blue dot. The primary cause is thought to be intense volcanic activity which formed the Siberian Traps and sent global CO₂ levels soaring. In Karoo Basin of South Africa, 170 tetrapod fossils were found that lend credence to the theory. Several of the Lystrosaurus skeletons were preserved in a spread eagle position that “are interpreted as drought-stricken carcasses that collapsed and died of starvation in and alongside dried-up water sources.”

As Pangea dried from increased global temperatures, drought struck many different terrestrial ecosystems and changed them from what they were before. The scientists say this “likely had a profound and lasting influence on the evolution of tetrapods.” As we come up on the Thanksgiving holiday here in the United States, perhaps you should give thanks for the prehistoric volcanism that led to your birth?

If you want to explore more about how CO₂ can lead to life forms having a bad day, have a look at paleoclimatology and what it tells us about today. In more recent history, have a look at how we can detect volcanic eruptions from all around the world and how you can learn more about the Earth by dangling an antenna from a helicopter.

Pac-Man Ghost Helps With Air Quality Sensing

October 21, 2024 by Bryan Cockfield 13 Comments

In the past, building construction methods generally didn’t worry much about air quality. There were enough gaps around windows, doors, siding, and flooring that a house could naturally “breathe” and do a decent enough job of making sure the occupants didn’t suffocate. Modern buildings, on the other hand, are extremely concerned with efficiency and go to great lengths to ensure that no air leaks in or out. This can be a problem for occupants though and generally requires some sort of mechanical ventilation, but to be on the safe side and keep an eye on it a CO2 sensor like this unique Pac-Man-inspired monitor can be helpful.

Although there are some ways to approximate indoor air quality with inexpensive sensors, [Tobias] decided on a dedicated CO2 sensor for accuracy and effectiveness, despite its relatively large cost of around $30. An ESP32 handles the data from the sensor and then outputs the results to an array of LEDs hidden inside a ghost modeled after the ones from the classic arcade game Pac-Man. There are 17 WS2812B LEDs in total installed on a custom PCB, with everything held together in the custom 3D printed ghost-shaped case. The LEDs change from green to red as the air quality gets worse, although a few preserve the ghost’s white eyes even as the colors change.

For anyone looking to recreate this project and keep an eye on their own air quality, [Tobias] has made everything from the code, the PCB, and the 3D printer files open source, and has used accessible hardware in the build as well. Although the CO2 sensors can indeed be pricey, there are a few less expensive ways of keeping an eye on indoor air quality. Some of these methods attempt to approximate CO2 levels indirectly, but current consensus is that there’s no real substitute for taking this measurement directly if that’s the metric targeted for your own air quality.

An Earth-Bound Homage To A Martian Biochemistry Experiment

September 14, 2024 by Dan Maloney 5 Comments

With all the recent attention on Mars and the search for evidence of ancient life there, it’s easy to forget that not only has the Red Planet been under the figurative microscope since the early days of the Space Race, but we went to tremendous effort to send a pair of miniaturized biochemical laboratories there back in 1976. While the results were equivocal, it was still an amazing piece of engineering and spacefaring, one that [Marb] has recreated with this Earth-based version of the famed Viking “Labeled Release” experiment.

The Labeled Release experimental design was based on the fact that many metabolic processes result in the evolution of carbon dioxide gas, which should be detectable by inoculating a soil sample with a nutrient broth laced with radioactive carbon-14. For this homage to the LR experiment, [Marb] eschewed the radioactive tracer, instead looking for a relative increase in the much lower CO₂ concentration here on Earth. The test chamber is an electrical enclosure with a gasketed lid that holds a petri dish and a simple CO₂ sensor module. Glands in the lid allow an analog for Martian regolith — red terrarium sand — and a nutrient broth to be added to the petri dish. Once the chamber was sterilized, or at least sanitized, [Marb] established a baseline CO₂ level with a homebrew data logger and added his sample. Adding the nutrient broth — a solution of trypsinized milk protein, yeast extract, sugar, and salt — gives the bacteria in the “regolith” all the food they need, which increases the CO₂ level in the chamber.

More after the break…

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Dry Ice From Seashells, The Hard (But Cheap) Way

December 6, 2023 by Dan Maloney 11 Comments

[Hyperspace Pirate] wants to make his own dry ice, but he wants it to be really, really cheap. So naturally, his first stop is… the beach?

That’s right, the beach, because that’s where to find the buckets of free seashells that he turned into dry ice. Readers may recall previous efforts at DIY dry ice, which used baking soda and vinegar as a feedstock. We’d have thought those were pretty cheap materials for making carbon dioxide gas, but not cheap enough for [Hyperspace Pirate], as the dry ice he succeeded in making from them came out to almost ten bucks a pound. The low yield of the process probably had more to do with the high unit cost, in truth, so cheaper feedstocks and improved yield would attack the problem from both ends.

With a supply of zero-cost calcium carbonate from the beach and a homemade ZVS-powered induction heater tube furnace at the ready, [Hyperspace Pirate] was ready to make quicklime and capture the CO₂ liberated in the process. That proved to be a little more difficult than planned since the reaction needed not just heat but a partial vacuum to drive the CO₂ off. An oil-free vacuum pump helped, yielding a little CO₂, but eventually he knuckled under and just doused the shells in vinegar. This had the fun side effect of creating calcium acetate, which when distilled not only corrodes the copper still plumbing but also makes a lousy but still flammable grade of acetone. Once enough CO₂ was stored in a couple of beach balls, the process of cooling and condensing it into dry ice was pretty much the same as the previous method, except for taking advantage of the Joule-Thomson cryocooler he built a while back.

The result is a hundred or so grams of dry ice snow, which isn’t great but still shows promise. [Hyperspace Pirate] feels like the key to improving this process is more heat to really drive the calcination reaction. Might we suggest a DIY tube furnace for that job?

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Fuel Cell Turns PET And Carbon Dioxide Into Useful Chemicals

June 21, 2023 by Al Williams 17 Comments

The University of Cambridge has a novel fuel cell design that can grab CO₂ from the atmosphere or industrial processes and, combined with waste PET plastic, provides syngas and glycolic acid, a product used in some cosmetics. You can read about the device in a recent paper.

The strange juxtaposition of CO₂ and PET is no accident. The processes work together with solar energy. There is no external voltage required, but the cell operates as a photocell to produce electricity from the solar energy. Removing both CO₂ and waste plastic from the environment is a good thing.

Syngas is hydrogen and carbon monoxide and finds use in producing methanol and ammonia. It also will work as a fuel that can replace gasoline when gasoline isn’t available. It has a few other uses, like reducing iron ore to sponge iron and even converting methanol to gasoline.

The technology has a ways to go to operate at scale, and we doubt this will ever be a consumer item since you are unlikely to need syngas or glycolic acid in your home or vehicle. But it still is a promising technique to reduce both greenhouse gas and plastic waste in one swoop.

We’ve looked at other ways to grab carbon dioxide and make it useful. If you want to make your own syngas, there are other ways to do it.