Chemistry

120 Articles

Different Etching Strokes For Different PCBs, Folks

August 8, 2023 by 44 Comments

[Sebastian] probably didn’t think he was wading into controversial waters when he posted on his experimental method for etching PCBs (in German). It’s not like etching with hydrochloric acid and peroxide is anything new, really; it was just something new to him. But is it even possible these days to post something and not find out just how wrong you are about it?

Sadly, no, or at least so it appears from a scan of [Sebastian]’s tweet on the subject (Nitter). There are a bunch of ways to etch copper off boards, including the messy old standby etchant ferric chloride, or even [Sebastian]’s preferred sodium persulfate method. Being out of that etchant, he decided to give the acid-peroxide method a go and was much pleased by the results. The traces were nice and sharp, the total etching time was low, and the etchant seemed pretty gentle when it accidentally got on his skin. Sounds like a win all around.

But Twitter wouldn’t stand for this chemical heresy, with comments suggesting that the etching process would release chlorine gas, or that ferric chloride is far safer and cleaner. It seems to us that most of the naysayers are somewhat overwrought in their criticism, especially since [Sebastian]’s method used very dilute solutions: a 30% hydrochloric acid solution added to water — like you oughta — to bring it down to 8%, and a 12% peroxide solution. Yes, that’s four times more concentrated than the drug store stuff, but it’s not likely to get you put on a terrorism watch list, as some wag suggested — a hair stylist watchlist, perhaps. And 8% HCl is about the same concentration as vinegar; true, HCl dissociates almost completely, which makes it a strong acid compared to acetic acid, but at that dilution it seems unlikely that World War I-levels of chlorine gas will be sweeping across your bench.

As with all things, one must employ caution and common sense. PPE is essential, good chemical hygiene is a must, and safe disposal of spent solutions is critical. But taking someone to task for using what he had on hand to etch a quick PCB seems foolish — we all have our ways, but that doesn’t mean everyone else is wrong if they don’t do the same.

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Old Film Camera Modified For Different Chemistry

August 3, 2023 by 12 Comments

While most photographers have moved on to digital cameras with their numerous benefits, there are a few artists out there still taking pictures with film. While film is among the more well-known analog photographic methods available, there are chemically simpler ways of taking pictures available for those willing to experiment a little bit. Cyanotype photography is one of these methods, and as [JGJMatt] shows, it only takes a few commonly available chemicals, some paper, and a slightly modified box camera to get started.

Cyanotype photography works by adding UV-reactive chemicals to paper and exposing the paper similarly to how film would be exposed. The photographs come out blue wherever the paper wasn’t exposed and white where it was. Before mixing up chemicals and taking photos, though, [JGJMatt] needed to restore an old Kodak Brownie camera, designed to use a now expensive type of film. Once the camera is cleaned up, only a few modifications are needed to adapt it to the cyanotype method, one of which involves placing a magnet on the shutter to keep it open for the longer exposure times needed for this type of photography. There is some development to do on these pictures, but it’s relatively simple to do in comparison to more traditional chemical film development.

For anyone looking for a different way of taking photographs, or even those looking for a method of taking analog pictures without the hassle of developing film or creating a darkroom, cyanotype offers a much easier entry point and plenty of artists creating images with this method don’t use a camera at all. There are plenty of other photographic chemistries to explore as well; one of our favorites uses platinum to create striking black-and-white photos.

No Fish Left Behind

July 25, 2023 by 25 Comments

For hundreds of years, Icelanders have relied on the ocean for survival. This is perhaps not surprising as it’s an isolated island surrounded by ocean near the Arctic circle. But as the oceans warm and fisheries continue to be harvested unsustainably, Iceland has been looking for a way to make sure that the fish they do catch are put to the fullest use, for obvious things like food and for plenty of other novel uses as well as they work towards using 100% of their catch.

After harvesting fish for food, most amateur fishers will discard around 60% of the fish by weight. Some might use a portion of this waste for fertilizer in a garden, but otherwise it is simply thrown out. But as the 100% Fish Project is learning, there are plenty of uses for these parts of the fish as well. Famously, cod skin has been recently found to work as skin grafts for humans, while the skin from salmon has been made into a leather-type product and the shells of crustaceans like shrimp can be made into medicine. The heads and bones of fish can be dried and made into soups, and other parts of fish can be turned into things like Omega-3 capsules and dog treats.

While we don’t often feature biology-related hacks like this, out-of-the-box thinking like this is an important way to continue to challenge old ideas, leave less of a footprint, improve human lives, and potentially create a profitable enterprise on top of all of that. You might even find that life in the seas can be used for things you never thought possible before, like building logic gates out of crabs.

Thanks to [Ben] for the tip!

Stirring Up 3D-Printed Lab Equipment

July 9, 2023 by 18 Comments

Magnetic stirrers are a core part of many chemistry labs. They offer many advantages for ensuring the effective mixing of solutions compared to other methods of stirring, including consistency, precise control, operation within closed systems, and of course, hands-free automatic operation. With so many reasons for employing a magnetic stirrer, it’s not too surprising that [Joey] would want one. He built his using 3D-printed parts rather than purchasing it.

The magnetic stirrer uses a 3D-printed enclosure for the base. Inside is a PWM controller which sends power to a small DC motor. A 3D-printed arm is attached to the motor, which hosts a pair of magnets. As the arm spins inside the enclosure, the magnetic fields from the magnet couple with the stir bar inside the mixture, allowing it to spin without any mechanical link to the stirring device and without any input from the user. [Joey] has also made all the 3D-printed parts for this build available on Printables.

While magnetic stirrers aren’t the most complicated of devices (or the most expensive), building tools like this anyway often has other advantages, such as using parts already on hand, the ability to add in features and customizations that commercial offerings don’t have, or acting as a teaching aid during construction and use. It’s also a great way to put the 3D printer to work, along with this other piece of 3D-printed lab equipment designed for agitating cell cultures instead.

Cooling Paint You Can Actually Make

July 3, 2023 by 57 Comments

[NightHawkInLight] has been working on radiative sky paint. (Video, embedded below.) That’s a coating that radiates heat in the infrared spectrum at a wavelength that isn’t readily absorbed or reflected by the atmosphere. The result is a passive system that keeps materials a few degrees cooler in direct sunlight than an untreated piece in the shade. That sounds a bit like magic, but apparently the math checks out.

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Forgotten Chemical Photography

June 22, 2023 by 14 Comments

Much to the chagrin of Eastman Kodak, the world has moved on from chemical photography into the realm of digital, thanks to the ease of use and high quality of modern digital cameras. There are a few photographers here and there still using darkrooms and various chemical processes to develop film, and the most common of these use some type of chemistry based on silver to transfer images to paper. There are plenty of alternatives to silver, though, each with their unique style and benefits, like this rarely-used process that develops film using platinum.

This process, notable for its wide tonal range, delicate highlights, and rich blacks, produces only black and white photographs. But unlike its silver analog, it actually embeds the image into the paper itself rather than holding the image above the paper. This means that photographs developed in this manner are much more resilient and can last for much longer. There are some downsides to this method though, namely that it requires a large format camera and the negatives can’t be modified to produce various sized images in the same ways that other methods allow for. Still, the results of the method are striking for anyone who has seen one of these images in person.

As to why this method isn’t more common, [Matt Locke] describes a somewhat complicated history involving the use of platinum to create commercial fertilizers, which is an identical process to that of the creation of explosives, which were needed in great numbers at the same time this photographic method was gaining in popularity. While the amount of research and development that goes into creating weapons arguably generates some ancillary benefit for society, the effects of war can also serve to divert resources away from things like this.

Anodizing Titanium In Multiple Colors

May 14, 2023 by 12 Comments

[Titans of CNC Machining] wanted to anodize some titanium parts. They weren’t looking for a way to make the part harder or less prone to corrosion. They just wanted some color. As you can see in the video below, the resulting setup is much simpler than you might think.

The first attempt, however, didn’t work out very well. The distilled water and baking soda was fine, as was the power supply made of many 9V batteries. But a copper wire contaminated the results. The lesson was that you need electrodes of the same material as your workpiece.

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